Hydrogen atom transfer methodology for the synthesis of C-22, C-23, and C-25 stereoisomers of cephalostatin north 1 side chain from spirostan sapogenins

Tetrahedron

Volumn 61, Issue 11, 2005, Pages 2803-2814

  Betancor, Carmen ^b   Freire, Raimundo ^a   Pérez Martín, Inés ^a   Prangé, Thierry ^c   Suárez, Ernesto ^a  

^a INSTITUTO DE PRODUCTOS NATURALES Y AGROBIOLOGÍA   (Spain)

^b UNIVERSIDAD DE LA LAGUNA   (Spain)

^c UNIVERSITÉ PARIS SACLAY   (France)

Author keywords

Alkoxyl radical; Cephalostatin; Hydrogen abstraction; Radical reaction; Spirostan sapogenin; Steroid

Indexed keywords

1,6 DIOXASPIRO[4.4]NONANE; 1,6 DIOXASPIRO[4.5]DECANE; CEPHALOSTATIN; DECANE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; CROSS COUPLING REACTION; DIASTEREOISOMER; EQUILIBRIUM CONSTANT; HYDROXYLATION; ISOMERIZATION; KINETICS; MOLECULAR INTERACTION; PRIORITY JOURNAL; PROTEIN SYNTHESIS; PROTON TRANSPORT; REDUCTION; THERMODYNAMICS;

EID: 14244268192     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2005.01.077     Document Type: Article

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