1,1-Insertion of substituted alkynes into the Ir-O bond of η2-carboxylato iridium complexes

Journal of Organometallic Chemistry

Volumn 690, Issue 5, 2005, Pages 1306-1313

  Chin, Chong Shik ^a   Lee, Hyungeui ^a   Lee, Myung Ki ^a   Noh, Soyoung ^a   Eum, Min Sik ^a   Hong, Seunggweon ^a  

^a Sogang University   (South Korea)

Author keywords

1,1 Insertion; Alkynes; Iridium; M C O bond formation; Vinylidenes

Indexed keywords

CARBONYLATION; IRIDIUM; OXYGEN; REACTION KINETICS;

ALKYNES; VINYL ACETATE LIGANDS;

ORGANOMETALLICS;

ALKYNE; CARBON; HYDROGEN; IRIDIUM; IRIDIUM COMPLEX; OXYGEN; PHOSPHORUS; VINYL ACETATE;

ANALYTIC METHOD; ARTICLE; CARBOXYLATION; CHEMICAL BOND; COMPLEX FORMATION; REACTION ANALYSIS; STRUCTURE ANALYSIS; SUBSTITUTION REACTION;

EID: 14144253166     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2004.11.040     Document Type: Article

References (36)

1. M.L. Waters, M.E. Bos, and W.D. Wulff J. Am. Chem. Soc. 121 1999 6403
2. Y. Ishii, K. Miyashita, K. Kamita, and M. Hidai J. Am. Chem. Soc. 119 1997 6448
3. T. Shibata, K. Yamashita, H. Ishida, and K. Takagi Org. Lett. 3 2001 1217
4. T. Ohmura, S. Yorozuya, Y. Yamamoto, and N. Miyaura Organometallics 19 2000 365
5. C. Slugovc, K. Mereiter, E. Zobetz, R. Schmid, and K. Kirchner Organometallics 15 1996 5275
6. Y. Kishimoto, P. Eckerle, T. Miyatake, M. Kainosho, A. Ono, T. Ikariya, and R. Noyori J. Am. Chem. Soc. 121 1999 12035
7. T. Yasukawa, T. Satoh, M. Miura, and M. Nomura J. Am. Chem. Soc. 124 2002 12680
8. T. Takahashi, F.-Y. Tsai, and M. Kotora J. Am. Chem. Soc. 122 2000 4994
9. T. Ohmura, Y. Yamamoto, and N. Miyaura J. Am. Chem. Soc. 122 2000 4990
10. M. Picquet, C. Bruneau, and P.H. Dixneuf Chem. Commun. 1998 2249
11. D. Amoroso, G.P.A. Yap, and D.E. Fogg Organometallics 21 2002 3335
12. S.M. Hansen, M.A.O. Volland, F. Rominger, F. Eisenträger, and P. Hofmann Angew. Chem., Int. Ed. 38 1999 1273
13. M.A. Esteruelas, F.J. Lahoz, E. Oñate, L.A. Oro, C. Valero, and B. Zeier J. Am. Chem. Soc. 117 1995 7935
14. M. Saoud, A. Romerosa, and M. Peruzzini Organometallics 19 2000 4005
15. D. Touchard, P. Haquette, S. Guesmi, L.L. Pichon, A. Daridor, L. Toupet, and P.H. Dixneuf Organometallics 16 1997 3640
16. C. Bianchini, P. Innocenti, M. Peruzzini, A. Romerosa, and F. Zanobini Organometallics 15 1996 272
17. I. Kovacik, M. Laubender, and H. Werner Organometallics 16 1997 5607
18. M.I. Bruce Chem. Rev. 91 1991 197
19. C.S. Chin, H. Lee, S. Noh, H. Park, and M. Kim Organometallics 22 2003 2119
20. C.S. Chin, M. Kim, and H. Lee Organometallics 21 2002 1679
21. C.S. Chin, H. Cho, G. Won, M. Oh, and K.M. Ok Organometallics 18 1999 4810
22. C.S. Chin, H. Lee, H. Park, and M. Kim Organometallics 21 2002 3889
23. C.S. Chin, M. Kim, H. Lee, S. Noh, and K.M. Ok Organometallics 21 2002 4785
24. C.S. Chin, G. Won, D. Chong, M. Kim, and H. Lee Acc. Chem. Res. 35 2002 218
25. C.S. Chin, M. Kim, G. Won, H. Chong, and H. Lee Dalton Trans. 2003 2325
26. C.S. Chin, W. Maeng, D. Chong, G. Won, B. Lee, Y.J. Park, and J.M. Shin Organometallics 18 1999 2210
27. C.S. Chin, M. Kim, M.K. Lee, and H. Lee Organometallics 22 2003 3239
28. 2 (5) have been also synthesized by other method in our laboratory (see [3c])
29. -
30. M.S. Sanford, M.R. Valdez, and R.H. Grubbs Organometallics 20 2001 5455
31. M.A. Esteruelas, F.J. Lahoz, A.M. López, E. Oñate, and L.A. Oro Organometallics 13 1994 1669
32. T. Daniel, N. Mahr, T. Braun, and H. Werner Organometallics 12 1993 1475
33. I. Ara, J.R. Berenguer, E. Eguizábal, J. Forniés, E. Lalinde, and F. Martínez Organometallics 18 1999 4344
34. I. Ara, J.R. Berenguer, E. Eguizábal, J. Forniés, E. Lalinde, A. Martín, and F. Martínez Organometallics 17 1998 4578
35. F.J. Fernández, M. Alfonso, H.W. Schmalle, and H. Berke Organometallics 20 2001 3122
36. C.S. Chin, Y. Park, J. Kim, and B. Lee J. Chem. Soc. Chem. Commun. 1995 1495