A new rhodium(I) hexapentaene complex prepared from a precursor containing a RhC5 chain

Organometallics

Volumn 16, Issue 26, 1997, Pages 5607-5609

  Kovacik, Ivan ^a   Laubender, Matthias ^a   Werner, Helmut ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001008514     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970734t     Document Type: Article

References (25)

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5. Roth, G.; Fischer, H. Organometallics 1996, 15, 1139-1145.
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7. (b) Werner, H. J. Chem. Soc., Chem. Commun. 1997, 903-910.
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10. Brandsma, L. Preparative Acetylenic Chemistry, 2nd ed.; Elsevier: Amsterdam, 1988; p 179.
11. Correct elemental analyses have been obtained for complexes 2, 4, 5 and 7.
12. Werner, H.; Gevert, O.; Steinert, P.; Wolf, J. Organometallics 1995, 14, 1786-1791.
13. P-Rh = 114.8 Hz).
14. P-Rh = 132.3 Hz).
15. P-Rh = 128.8 Hz).
16. Werner, H.; Laubender, M.; Wiedemann, R.; Windmüller, B. Angew. Chem. 1996, 108, 1330-1332; Angew. Chem., Int. Ed. Engl. 1996, 35, 1237-1239.
17. Werner, H.; Laubender, M.; Wiedemann, R.; Windmüller, B. Angew. Chem. 1996, 108, 1330-1332; Angew. Chem., Int. Ed. Engl. 1996, 35, 1237-1239.
18. +).
19. Principal bond lengths (Å) and interbond angles (deg) for isomer B of 7: Rh-Cl 2.348(1); Rh-P1, 2.367(1); Rh-P2, 2.369(1); Rh-C2, 1.992(5); Rh-C3, 2.040(4); C1-C2, 1.321(8); C2-C3, 1.357(6); C3-C4, 1.302(6); C4-C5, 1.261(6); C5-C6, 1.337(7); P1-Rh-P2, 171.25(5); P1-Rh-Cl, 87.75(5); P2-Rh-Cl, 87.09(5); Cl-Rh-C2, 151.0(2); Cl-Rh-C3, 169.6(1); C1-C2-C3, 149.2(6); C2-C3-C4, 152.6(5); C3-C4-C5, 177.1(5); C4-C5-C6, 175.3(5); C2-Rh-C3, 39.3(2); Rh-C2-C1, 138.5(5); Rh-C3-C4, 138.9(4).
20. Song, L.; Arif, A. M.; Stang. P. J. J. Organomet. Chem. 1990, 395, 219-226.
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23. (a) Hopf, H. In The Chemistry of Ketenes, Allenes and Related Compounds; Patai, S., Ed.; Wiley: Chichester, New York, Brisbane, Toronto, 1980; Chapter 20, p 867.
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