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0011420004
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note
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Carbon-13 NMR shifts between 350 and 300 ppm are typical of ruthenium vinylidenes (for examples see ref 2 and ref 3) and alkylidenes (for example ref 5).
-
-
-
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48
-
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0011481678
-
-
note
-
Proton NMR shifts between 18 and 21 ppm are typical of ruthenium alkylidenes. For examples see ref 5.
-
-
-
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49
-
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0011428528
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note
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After 2 days at 45°C both species decompose entirely. The identity of the multiple decomposition products is unknown at this time.
-
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-
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50
-
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0011472384
-
-
note
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1 geometry to generate an open coordination site for olefin binding. The latter result suggests that highly charged intermediates are not involved in the formation of 2. Further investigations on this topic are ongoing.
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51
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0011420005
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note
-
In solution, the chemical shift of the α-carbon of complex 2 is more consistent with its formulation as a ruthenium vinyl adduct than as the tautomeric alkylidene or vinylidene structures [ref 24].
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54
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For a review of the unique chemistry of the Tp ligand see: Trofimenko, S. Chem. Rev. 1993, 93, 943.
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0011420006
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note
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000 = 1609, T = 98 K. More information is provided in the Supporting Information.
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56
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0011417409
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note
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In solution, the chemical shift of the α-carbon of complex 8 is more consistent with its formulation as a ruthenium vinyl adduct than as the tautomeric alkylidene or vinylidene structures [ref 24].
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58
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0011481679
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note; unpublished results.
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2Ru=CHPh is an active catalyst for the ROMP of norbornene and cyclobutene, but is completely unreactive toward RCM substrates such as diethyl diallylmalonate. Dias, E. L.; Nguyen, S. T.; Grubbs, R. H. 1996, unpublished results.
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0011412298
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note
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2) (CCDC 164302). Copies of the data can be obtained, free of charge, on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax:+44 1223 336033 or e-mail: deposit@ccdc.cam.ac.uk). Structure factors are available from the authors via e-mail: xray@caltech.edu.
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67
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0011417410
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note
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000 = 2032, T = 293 K. More information is provided in the Supporting Information.
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