Methyl, hydrochalcogenido, and phenylchalcogenolate complexes of zinc in a sulfur rich coordination environment: Syntheses and structural characterization of the tris(2-mercapto-1-tert-butylimidazolyl)-hydroboratozinc complexes [TmBut]ZnMe, [TmBut]ZnEH (E = S, Se) and [TmBut]ZnEPh (E = O, S, Se, Te)

Chemical Communications

Volumn , Issue 24, 2004, Pages 2870-2871

  Melnick, Jonathan G ^a   Docrat, Arefa ^a   Parkin, Gerard ^a  

^a Och Spine at New York Presbyterian Hospitals   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BORIC ACID; CHALCOGEN; COORDINATION COMPOUND; IMIDAZOLE DERIVATIVE; METAL COMPLEX; METHYL GROUP; OXYGEN DERIVATIVE; PHENYL GROUP; SELENIUM DERIVATIVE; SULFUR; SULFUR DERIVATIVE; TELLURIUM DERIVATIVE; THIOL DERIVATIVE; TRIS(2 MERCAPTO 1 TERT BUTYLIMIDAZOLYL)HYDROBORATOZINC COMPLEX; UNCLASSIFIED DRUG; ZINC COMPLEX;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; COVALENT BOND; DISSOCIATION; HYDROGEN BOND; PROTON NUCLEAR MAGNETIC RESONANCE; STRUCTURE ANALYSIS; SYNTHESIS; X RAY DIFFRACTION;

EID: 11244337869     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b412218f     Document Type: Article

References (40)

1. (a) G. Parkin, Prog. Inorg. Chem., 1998, 47, 1;
2. (b) M. C. Kuchta and G. Parkin, Coord. Chem. Rev., 1998, 176, 323.
3. (a) M. Peruzzini, I. de los Rios and A. Romerosa, Prog. Inorg. Chem., 2001, 49, 169;
4. (b) S. Kuwata and M. Hidai, Coord. Chem. Rev., 2001, 213, 211.
5. (a) J. Arnold, Prog. Inorg. Chem., 1995, 43, 353, and references therein;
6. (b) U. Englich and K. Ruhlandt-Senge, Coord. Chem. Rev., 2000, 210, 135;
7. (c) D. C. Bradley, R. C. Mehrotra, I. P. Rothwell and A. Singh, Alkoxo and Aryloxo Derivatives of Metals, Academic Press, San Diego, CA, 2001.
8. (a) G. Parkin, Chem. Rev., 2004, 104, 699;
9. (b) G. Henkel and B. Krebs, Chem. Rev., 2004, 104, 801.
10. (a) M. Bochmann, Chem. Vapor Deposition, 1996, 2, 85;
11. (b) N. L. Pickett and P. O'Brien, Chem. Record, 2001, 6, 467.
12. For representative studies, see: (a) I. Cassidy, M. Garner, A. R. Kennedy, G. B. S. Potts, J. Reglinski, P. A. Slavin and M. D. Spicer, Eur. J. Inorg. Chem., 2002, 1235;
13. (b) S. Bakbak, V. K. Bhatia, C. D. Incarvito, A. L. Rheingold and D. Rabinovich, Polyhedron, 2001, 20, 3343;
14. (c) C. Kimblin, B. M. Bridge-water, D. G. Churchill and G. Parkin, Chem. Commun., 1999, 2301;
15. (d) B. M. Bridgewater and G. Parkin, J. Am. Chem. Soc., 2000, 122, 7140;
16. (e) B. M. Bridgewater and G. Parkin, Inorg. Chem. Commun., 2001, 4, 126;
17. (J) M. Tesmer, M. Shu and H. Vahrenkamp, Inorg. Chem., 2001, 40, 4022;
18. (g) J. L. White, J. M. Tanski and D. Rabinovich, J. Chem. Soc., Dalton Trans., 2002, 2987;
19. (h) B. M. Bridgewater, T. Fillebeen, R. A. Friesner and G. Parkin, J. Chem. Soc., Dalton Trans., 2000, 4494.
20. (a) I. B. Gorrell, A. Looney and G. Parkin, J. Chem. Soc., Chem. Commun., 1990, 220;
21. (b) R. Han, I. B. Gorrell, A. G. Looney and G. Parkin, J. Chem. Soc., Chem. Commun., 1991, 717;
22. (c) A. Looney, R. Han, I. B. Gorrell, M. Cornebise, K. Yoon, G. Parkin and A. L. Rheingold, Organometallics, 1995, 14, 274;
23. (d) C. Bergquist and G. Parkin, Inorg. Chem., 1999, 38, 422;
24. (e) C. Bergquist, H. Storrie, L. Koutcher, B. M. Bridgewater, R. A. Friesner and G. Parkin, J. Am. Chem. Soc., 2000, 122, 12651;
25. (f) R. Alsfasser, A. K. Powell, S. Trofimenko and H. Vahrenkamp, Chem. Ber./Recl., 1993, 126, 685.
26. D. J. Mihalcik, J. L. White, J. M. Tanski, L. N. Zakharov, G. P. A. Yap, C. D. Incarvito, A. L. Rheingold and D. Rabinovich, Dalton Trans., 2004, 1626.
27. CSD Version 5.25. F. H. Allen and O. Kennard, Chem. Des. Autom. News, 1993, 8(1), 1 & 31-37.
28. p-Tol]MgSeH have been prepared in an analogous manner. See: P. Ghosh and G. Parkin, Chem. Commun., 1996, 1239.
29. (a) M. Ruf and H. Vahrenkamp, Inorg. Chem., 1996, 35, 6571;
30. (b) M. Rombach and H. Vahrenkamp, Inorg. Chem., 2001, 40, 6144.
31. RR′]M chemistry, see: (a) P. Ghosh and G. Parkin, Polyhedron, 1997, 16, 1255;
32. (b) Ref. 7f 13 W. A. Howard, T. M. Trnka and G. Parkin, Inorg. Chem., 1995, 34, 5900.
33. A. C. Hillier, S. Y. Liu, A. Sella and M. R. J. Elsegood, Inorg. Chem., 2000, 39, 2635.
34. Covalent radii (Å): Zn (1.25), C (0.77). O (0.73), S (1.03), Se (1.19) and Te (1.40). Data taken from: S. S. Batsanov, Russ. Chem. Rev., 1995, 44, 2245.
35. M. R. Russo, N. Kaltsoyannis and A. Sella, Chem. Commun., 2002, 2458.
36. L. Pauling, The Nature of The Chemical Bond, Cornell University Press, Ithaca, NY, 3rd edn., 1960, p. 93.
37. See, for example: C. Bergquist, T. Fillebeen, M. M. Morlok and G. Parkin, J. Am. Chem Soc., 2003, 125, 6189, and references therein.
38. But]ZnOPh would not significantly lengthen the Zn-O bond to an extent that it does not afford a useful comparison with the other phenylchalcogenolate derivatives.
39. For related examples, see: (a) U. Brand, M. Rombach, J. Seebacher and H. Vahrenkamp, Inorg. Chem., 2001, 40, 6151;
40. (b) refs. 6h and 11b.