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Volumn , Issue 22, 1999, Pages 2301-2302

Mononuclear tris(2-mercapto-1-arylimidazolyl)hydroborato complexes of zinc, [Tm(Ar)]ZnX: Structural evidence that a sulfur rich coordination environment promotes the formation of a tetrahedral alcohol complex in a synthetic analogue of LADH

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DEHYDROGENASE; BORIC ACID; COORDINATION COMPOUND; IMIDAZOLE DERIVATIVE; LIVER ENZYME; METHANOL; MONOMER; SULFUR; THIOL DERIVATIVE; ZINC COMPLEX;

EID: 0033592804     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a906561j     Document Type: Article
Times cited : (108)

References (37)
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    • See, for example: C. Bergquist and G. Parkin, Inorg. Chem., 1999, 38, 422; M. Ruf, F. A. Schell, R. Walz and H. Vahrenkamp, Chem. Ber./ Recueil, 1997, 130, 101; R. Alsfasser, M. Ruf, S. Trofimenko and H. Vahrenkamp, Chem. Ber., 1993, 126, 703.
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    • note
    • In this regard, it has been suggested that the two negative cysteine tlhiolate residues serve to reduce the tendency to form a zinc hydroxide species and thereby increase the propensity for a coordinated water molecule to be replaced by an alcohol. See ref. 1(a).


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