Regio- and enantioselective iridium-catalyzed intermolecular allylic etherification of achiral allylic carbonates with phenoxides

Journal of the American Chemical Society

Volumn 125, Issue 12, 2003, Pages 3426-3427

  López, Fernando ^a   Ohmura, Toshimichi ^a   Hartwig, John F ^a  

^a YALE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALIPHATIC COMPOUND; AROMATIC COMPOUND; CARBON; CARBONIC ACID DERIVATIVE; IRIDIUM; MOLYBDENUM; OXIDE; PALLADIUM; TRANSITION ELEMENT; TUNGSTEN;

ALKYLATION; AMINATION; ARTICLE; CATALYST; CHEMICAL BOND; CHEMICAL REACTION; CHIRALITY; COMPLEX FORMATION; ENANTIOSELECTIVITY; ETHERIFICATION; REACTION ANALYSIS; STEREOCHEMISTRY; SUBSTITUTION REACTION; SYNTHESIS; TECHNIQUE;

ALLYL COMPOUNDS; CARBONATES; CATALYSIS; ETHERS; IRIDIUM; OXIDES; STEREOISOMERISM;

EID: 0242500920     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja029790y     Document Type: Article

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24. 4/5 = 90/10 after 36 h, 80/20 after 76 h, and 70/30 after 240 h. ee = 90% after 36 h, 86% after 76 h, and 70% after 240 h.