Syntheses and structures of monoplatinum model complexes for diplatinum polyynediyl adducts LnPt(CC)zPtLn

Journal of Organometallic Chemistry

Volumn 641, Issue 1-2, 2002, Pages 53-61

  Peters, Thomas B ^a   Zheng, Qinglin ^b   Stahl, Jürgen ^b   Bohling, James C ^a   Arif, Atta M ^a   Hampel, Frank ^b   Gladysz, J A ^b  

^a UNIVERSITY OF UTAH   (United States)

^b UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

Alkynyl and butadiynyl complexes; Crystal structures; Hagihara coupling; Platinum

Indexed keywords

CRYSTAL STRUCTURE; PLATINUM;

ALKYNYLS; CATALYZED REACTIONS; MODEL COMPLEXES; THREE-STEP SYNTHESIS;

SYNTHESIS (CHEMICAL);

EID: 0002878112     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(01)01311-0     Document Type: Article

References (46)

1. J.A. Gladysz, B.J. Boone, Angew. Chem. 109 (1997) 566; Angew. Chem. Int. Ed. Engl. 36 (1997) 551.
2. Full papers from our laboratory: (a) W. Weng, T. Bartik, M. Brady, B. Bartik, J.A. Ramsden, A.M. Arif, J.A. Gladysz, J. Am. Chem. Soc. 117 (1995) 11922;(b) M. Brady, W. Weng, Y. Zhou, J.W. Seyler, A.J. Amoroso, A.M. Arif, M. Böhme, G. Frenking, J.A. Gladysz, J. Am. Chem. Soc. 119 (1997) 775;(c) S.B. Falloon, S. Szafert, A.M. Arif, J.A. Gladysz, Chem. Eur. J. 4 (1998) 1033;(d) T. Bartik, W. Weng, J.A. Ramsden, S. Szafert, S.B. Falloon, A.M. Arif, J.A. Gladysz, J. Am. Chem. Soc. 120 (1998) 11071;(e) R. Dembinski, T. Bartik, B. Bartik, M. Jaeger, J.A. Gladysz, J. Am. Chem. Soc. 122 (2000) 810;(f) W.E. Meyer, A.J. Amoroso, C.R. Horn, M. Jaeger, J.A. Gladysz, Organometallics 20 (2001) 1115.
3. See the following lead references and papers cited therein: (a) M.I. Bruce, Coord. Chem. Rev. 166 (1997) 91;(b) F. Paul, C. Lapinte, Coord. Chem. Rev. 178-180 (1998) 431;(c) A. Sakurai, M. Akita, Y. Moro-oka, Organometallics, 18 (1999) 3241;(d) F.J. Fernández, O. Blacque, M. Alfonso, H.J. Berke, Chem. Soc. Chem. Commun. (2001) 1266.
4. Paul F., Meyer W.E., Toupet L., Jiao H., Gladysz J.A., and Lapinte C. J. Am. Chem. Soc. 122 (2000) 9405
5. Jiao H., and Gladysz J.A. N. J. Chem. 25 (2001) 551
6. Peters T.B., Bohling J.C., Arif A.M., and Gladysz J.A. Organometallics 18 (1999) 3261
7. Mohr W., Stahl J., Hampel F., and Gladysz J.A. Inorg. Chem. 40 (2001) 3263
8. Bohling J.C., Peters T.B., Arif A.M., Hampel F., and Gladysz J.A. In: Ondrejoviç G., and Sirota A. (Eds). Coordination Chemistry at the Turn of the Century (1999), Slovak Technical University Press, Bratislava, Slovokia 47-52
9. Anderson G.K. In: Abel E.W., Stone F.G.A., and Wilkinson G. (Eds). Comprehensive Organometallic Chemistry II 9 (1995), Pergamon, Oxford 490-492
10. Ruwwe J., Marti{dotless}́n-Alvarez J.M., Horn C.R., Bauer E.B., Szafert S., Lis T., Hampel F., Cagle P.C., and Gladysz J.A. Chem. Eur. J. 7 (2001) 3931
11. Anderson G.K., Clark H.C., and Davies J.A. Inorg. Chem. 20 (1981) 3607
12. Pregosin P.S., and Venanzi L.M. Chem. Br. (1978) 276
13. The J values given represent the apparent coupling between adjacent peaks of the triplet.
14. Bartik B., Dembinski R., Bartik T., Arif A.M., and Gladysz J.A. N. J. Chem. 21 (1997) 739
15. Ertl J., Grafl D., and Brune H.A. Z. Naturforsch B: Anorg. Chem. Org. Chem. 37b (1982) 1082
16. Clark H.C., and Manzer L.E. J. Organomet. Chem. 59 (1973) 411
17. Eaborn C., Odell K.J., and Pidcock A. J. Chem. Soc. Dalton Trans. (1978) 357
18. Brandsma L., and Verkruijsse H.D. Synth. Commun. 21 (1991) 657
19. Usón R., Forniés J., Espinet P., and Alfranca G. Synth. React. Inorg. Met.-Org. Chem. 10 (1980) 579
20. Usón R., Forniés J., Espinet P., Navarro R., and Fortuño C. J. Chem. Soc. Dalton Trans. (1987) 2077
21. Low P.J., and Bruce M.I. Adv. Organomet. Chem. 48 (2001) 71
22. Alqaisi S.M., Galat K.J., Chai M., Ray III D.G., Rinaldi P.L., Tessier C.A., and Youngs W.J. J. Am. Chem. Soc. 120 (1998) 12149
23. Manna J., John K.D., and Hopkins M.D. Adv. Organomet. Chem. 38 (1995) 79
24. Recent lead reference: R. D'Amato, A. Furlani, M. Colapietro, G. Portalone, M. Casalboni, M. Falconieri, M.V. Russo, J. Organomet. Chem. 627 (2001) 13.
25. Sünkel K., Birk U., and Robl C. Organometallics 13 (1994) 1679
26. Lichtenberger D.L., Renshaw S.K., and Bullock R.M. J. Am. Chem. Soc. 115 (1993) 3276
27. McGrady J.E., Lovell T., Stranger R., and Humphrey M.G. Organometallics 16 (1997) 4004
28. John K.D., Miskowski V.M., Vance M.A., Dallinger R.F., Wang L.C., Geib S.J., and Hopkins M.D. Inorg. Chem. 37 (1998) 6858
29. Vaid T.P., Veige A.S., Lobkovsky E.B., Glassey W.V., Wolczanski P.T., Liable-Sands L.M., Rheingold A.L., and Cundari T.R. J. Am. Chem. Soc. 120 (1998) 10067
30. Delfs C.D., Stranger R., Humphrey M.G., and McDonagh A.M. J. Organomet. Chem. 607 (2000) 208
31. Koentjoro O.F., Rousseau R., and Low P.J. Organometallics 20 (2001) 4476
32. Yam V.W.-W., Zhang L., Tao C.-H., Wong K.M.-C., and Cheung K.-K. J. Chem. Soc. Dalton Trans. (2001) 1111 (and references therein)
33. Whittle C.E., Kleinstein J.A., George M.W., and Schanze K.S. Inorg. Chem. 40 (2001) 4053
34. J. Stahl, W. Mohr, Universität Erlangen-Nürnberg, unpublished results.
35. For a recent list of references to this extensive literature, see. Osakada K., Hamada M., and Yamamoto T. Organometallics 19 (2000) 458
36. Watson S.C., and Eastham J.F. J. Organomet. Chem. 9 (1967) 165
37. This compound is easily synthesized:. Hsu C.-Y., Leshner B.T., and Orchin M. Inorg. Synth. 19 (1979) 114 (Alternatively, the cis isomer of 1 (or cis/trans mixtures) can also be used to prepare the trans complexes 2 and 3.)
38. 195Pt=33.8%), and is not reflected in the peak multiplicity given;(b) A satellite would be expected based upon other spectra in this paper, but could not be discerned above background noise.
39. 1H-NMR.
40. The HCCCCH concentration is calculated from the mass increase of the THF solution [16]. CAUTION: this compound is explosive and literature precautions should be followed.
41. 1H-undecoupled spectra were recorded [6].
42. Otwinowski Z., and Minor W. Methods Enzymol. A: Macromol. Crystallogr. 276 (1997) 307
43. G.M. Sheldrick, shelx-97, University of Göttingen, Göttingen, Germany, 1997.
44. Maslen E.N., Fox A.G., and O'Keefe M.A. In: Wilson A.J.C. (Ed). International Tables for Crystallography: Mathematical, Physical and Chemical Tables C (1992), Kluwer Academic, Dordrecht, The Netherlands 476-516 (chap. 6)
45. Creagh D.C., and McAuley W.J. In: Wilson A.J.C. (Ed). International Tables for Crystallography: Mathematical, Physical and Chemical Tables C (1992), Kluwer Academic, Dordrecht, The Netherlands 206-222 (chap. 4)
46. Cromer D.T., and Waber J.T. In: Ibers J.A., and Hamilton W.C. (Eds). International Tables for X-ray Crystallography. 2nd ed. (1974), Kynoch, Birmingham, England