A supramolecular solution to a long-standing problem: The 1,6- polymerization of a triacetylene

Angewandte Chemie - International Edition

Volumn 39, Issue 12, 2000, Pages 2132-2135

  Xiao, Jun ^a   Yang, Meng ^a   Lauher, Joseph W ^a   Fowler, Frank W ^a  

^a STONY BROOK UNIVERSITY   (United States)

Author keywords

Crystal engineering; Polymers; Polytriacetylenes; Supramolecular chemistry; Topochemistry

Indexed keywords

ACETYLENE; TRIACETYLENE; UNCLASSIFIED DRUG;

ARTICLE; CRYSTAL STRUCTURE; DERIVATIZATION; DRUG SYNTHESIS; HYDROGEN BOND; POLYMERIZATION; STRUCTURE ANALYSIS; TRANSLATION REGULATION; X RAY CRYSTALLOGRAPHY;

EID: 0034674285     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20000616)39:12<2132::AID-ANIE2132>3.0.CO;2-8     Document Type: Article

References (18)

1. U. H. F. Bunz, Angew. Chem. 1994, 106, 1127-1130; Angew. Chem. Int. Ed. Engl. 1994, 33, 1073-1076.
2. U. H. F. Bunz, Angew. Chem. 1994, 106, 1127-1130; Angew. Chem. Int. Ed. Engl. 1994, 33, 1073-1076.
3. Although the poly(triacetylenes) have not been prepared by the direct polymerization of a triacetylene, they have been prepared by clever indirect means: R. E. Martin, T. Mäder, F. Diederich, Angew. Chem. 1999, 111, 834-838; Angew. Chem. Int. Ed. 1999, 38, 817-821.
4. Although the poly(triacetylenes) have not been prepared by the direct polymerization of a triacetylene, they have been prepared by clever indirect means: R. E. Martin, T. Mäder, F. Diederich, Angew. Chem. 1999, 111, 834-838; Angew. Chem. Int. Ed. 1999, 38, 817-821.
5. J. Kiji, J. Kaiser, G. Wegner, R. C. Schulz, Polymer 1973, 14, 433-439.
6. V. Enkelmann, Chem. Mater. 1994, 6, 1337-1340.
7. Macromodel version 6.2 using the MM2 force field was used in modeling calculations: F. Mohamadi, N. B. G. Richards, W. C. Guida, R. Liskamp, M. Lipton, C. Caufield, G. Chang, T. Hendrickson, W. C. Still, J. Comput. Chem. 1990, 11, 440-467.
8. P. Lue and J. V. Greenhill, Adv. Heterocycl. Chem. 1997, 67, 207-343.
9. This derivative (R = m-nitrophenyl) displayed a simple translational distance of 7.313 Å.
10. J. J. Kane, R.-F. Liao, J. W. Lauher, F. W. Fowler, J. Am. Chem. Soc. 1995, 117, 12003-12004.
11. C. M. Paleos, D. Tsiourvas, Angew. Chem. 1995, 107, 1839-1855; Angew. Chem. Int. Ed. Engl. 1995, 34, 1696-1711.
12. C. M. Paleos, D. Tsiourvas, Angew. Chem. 1995, 107, 1839-1855; Angew. Chem. Int. Ed. Engl. 1995, 34, 1696-1711.
13. 1 and was located at Brookhaven National Laboratories, Upton, NY.
14. H. R. Bhattacharjee, A. F. Preziosi, G. N. Patel, J. Polym. Sci. Polym. Symp. 1984, 71, 259-270.
15. Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure (Eds. W. R. Salaneck, I. Lundström, Rånby), Oxford University Press, Oxford, 1993.
16. R. E. Martin, F. Diederich, Angew. Chem. 1999, 111, 1440-1469; Angew. Chem. Int. Ed. 1999, 38, 1351-1377.
17. R. E. Martin, F. Diederich, Angew. Chem. 1999, 111, 1440-1469; Angew. Chem. Int. Ed. 1999, 38, 1351-1377.
18. G. A. Krafft, J. A. Katzenellenbogen, J. Am. Chem. Soc. 1981, 103, 5459-5466.