A four-oxidation-state family of coordinated carbon: The first isolable and crystallographically characterized triradical [M]-C4-[M]3+

Organometallics

Volumn 17, Issue 10, 1998, Pages 1928-1930

  Guillemot, Maud ^a   Toupet, Loic ^b   Lapinte, Claude ^a  

^a UMR 6509 Organometalliques et Catalyse Chimie et Electrochimie Moleculaires   (France)

^b CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001229797     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (31)

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19. Complete spectroscopic data for new compounds are given in the Supporting Information.
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24. Thominot, P.; Lapinte, C. Unpublished results, 1997.
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28. -1)): 1318, 14 000.
29. 3 components.
30. s = 2 transition is too broad and might be reminiscent of a signal due to impurities in the quartz sample tube. This suggestion was not confirmed by blank ESR measurements.
31. s = 2 or 3 is also difficult to observe in high-spin organic molecules. See for example: Ishida, T.; Iwamura, H. J. Am. Chem. Soc. 1991, 113, 4238-4241.