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Volumn 59, Issue 25, 2003, Pages 4525-4531

Cross-metathesis reaction of vinyl sulfones and sulfoxides

Author keywords

Carbene complex; Homogenous catalysis; Olefin metathesis; Ruthenium; Sulfone

Indexed keywords

ALKENE DERIVATIVE; MOLYBDENUM; RUTHENIUM; SULFONE DERIVATIVE; SULFOXIDE; UNCLASSIFIED DRUG; VINYL SULFONE;

EID: 0037498252     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(03)00682-3     Document Type: Article
Times cited : (68)

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    • It should be noted, however, that the structurally very similar complex 1d was found to be not reactive in cross-metathesis of vinyl sulfones
    • It should be noted, however, that the structurally very similar complex 1d was found to be not reactive in cross-metathesis of vinyl sulfones: Chatterjee A.K., Morgan J.P., Scholl M., Grubbs R.H. J. Am. Chem. Soc. 122:2000;3783-3784.
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    • A referee suggested that the inability of vinyl sulfoxides to participate in the CM reaction can be also explained by a red-ox catalyst degradation, as it is known that sulfoxides can oxidise Fisher-type carbenes, cf: We gratefully acknowledge a referee for pointing out this possibility
    • A referee suggested that the inability of vinyl sulfoxides to participate in the CM reaction can be also explained by a red-ox catalyst degradation, as it is known that sulfoxides can oxidise Fisher-type carbenes, cf: Wienand A., Reissig H.U. Organometallics. 9:1990;3133-3142. We gratefully acknowledge a referee for pointing out this possibility.
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