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For reviews, see: (a) Procter D.J. J. Chem. Soc. Perkin Trans. 1. 1999;641-667 (b) Simpkins N.S. Tetrahedron. 46:1990;6951-6984 (c) Patai S., Rappaport Z., Stirling C. The Chemistry of Sulphones and Sulphoxides. 1988;Wiley, New York. For representative recent applications, see e.g.: (d) Mauleón P., Alonso I., Carretero J.C. Angew. Chem. Int. Ed. 40:2001;1291-1293 (e) Bentley P.A., Bickley J.F., Roberts S.M., Steiner A. Tetrahedron Lett. 42:2001;3741-3743 (f) Lusinchi M., Stanbury T.V., Zard S.Z. Chem. Commun. 2002;1532-1533 (g) Fahrat S., Marek I. Angew. Chem. Int. Ed. 41:2002;1410-1412 (h) Teyssot M.L., Fayolle M., Philouze C., Dupuy C. Eur. J. Org. Chem. 2002;54-62.
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For reviews, see: (a) Procter D.J. J. Chem. Soc. Perkin Trans. 1. 1999;641-667 (b) Simpkins N.S. Tetrahedron. 46:1990;6951-6984 (c) Patai S., Rappaport Z., Stirling C. The Chemistry of Sulphones and Sulphoxides. 1988;Wiley, New York. For representative recent applications, see e.g.: (d) Mauleón P., Alonso I., Carretero J.C. Angew. Chem. Int. Ed. 40:2001;1291-1293 (e) Bentley P.A., Bickley J.F., Roberts S.M., Steiner A. Tetrahedron Lett. 42:2001;3741-3743 (f) Lusinchi M., Stanbury T.V., Zard S.Z. Chem. Commun. 2002;1532-1533 (g) Fahrat S., Marek I. Angew. Chem. Int. Ed. 41:2002;1410-1412 (h) Teyssot M.L., Fayolle M., Philouze C., Dupuy C. Eur. J. Org. Chem. 2002;54-62.
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For reviews, see: (a) Procter D.J. J. Chem. Soc. Perkin Trans. 1. 1999;641-667 (b) Simpkins N.S. Tetrahedron. 46:1990;6951-6984 (c) Patai S., Rappaport Z., Stirling C. The Chemistry of Sulphones and Sulphoxides. 1988;Wiley, New York. For representative recent applications, see e.g.: (d) Mauleón P., Alonso I., Carretero J.C. Angew. Chem. Int. Ed. 40:2001;1291-1293 (e) Bentley P.A., Bickley J.F., Roberts S.M., Steiner A. Tetrahedron Lett. 42:2001;3741-3743 (f) Lusinchi M., Stanbury T.V., Zard S.Z. Chem. Commun. 2002;1532-1533 (g) Fahrat S., Marek I. Angew. Chem. Int. Ed. 41:2002;1410-1412 (h) Teyssot M.L., Fayolle M., Philouze C., Dupuy C. Eur. J. Org. Chem. 2002;54-62.
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For reviews, see: (a) Procter D.J. J. Chem. Soc. Perkin Trans. 1. 1999;641-667 (b) Simpkins N.S. Tetrahedron. 46:1990;6951-6984 (c) Patai S., Rappaport Z., Stirling C. The Chemistry of Sulphones and Sulphoxides. 1988;Wiley, New York. For representative recent applications, see e.g.: (d) Mauleón P., Alonso I., Carretero J.C. Angew. Chem. Int. Ed. 40:2001;1291-1293 (e) Bentley P.A., Bickley J.F., Roberts S.M., Steiner A. Tetrahedron Lett. 42:2001;3741-3743 (f) Lusinchi M., Stanbury T.V., Zard S.Z. Chem. Commun. 2002;1532-1533 (g) Fahrat S., Marek I. Angew. Chem. Int. Ed. 41:2002;1410-1412 (h) Teyssot M.L., Fayolle M., Philouze C., Dupuy C. Eur. J. Org. Chem. 2002;54-62.
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For reviews, see: (a) Procter D.J. J. Chem. Soc. Perkin Trans. 1. 1999;641-667 (b) Simpkins N.S. Tetrahedron. 46:1990;6951-6984 (c) Patai S., Rappaport Z., Stirling C. The Chemistry of Sulphones and Sulphoxides. 1988;Wiley, New York. For representative recent applications, see e.g.: (d) Mauleón P., Alonso I., Carretero J.C. Angew. Chem. Int. Ed. 40:2001;1291-1293 (e) Bentley P.A., Bickley J.F., Roberts S.M., Steiner A. Tetrahedron Lett. 42:2001;3741-3743 (f) Lusinchi M., Stanbury T.V., Zard S.Z. Chem. Commun. 2002;1532-1533 (g) Fahrat S., Marek I. Angew. Chem. Int. Ed. 41:2002;1410-1412 (h) Teyssot M.L., Fayolle M., Philouze C., Dupuy C. Eur. J. Org. Chem. 2002;54-62.
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For reviews, see: (a) Procter D.J. J. Chem. Soc. Perkin Trans. 1. 1999;641-667 (b) Simpkins N.S. Tetrahedron. 46:1990;6951-6984 (c) Patai S., Rappaport Z., Stirling C. The Chemistry of Sulphones and Sulphoxides. 1988;Wiley, New York. For representative recent applications, see e.g.: (d) Mauleón P., Alonso I., Carretero J.C. Angew. Chem. Int. Ed. 40:2001;1291-1293 (e) Bentley P.A., Bickley J.F., Roberts S.M., Steiner A. Tetrahedron Lett. 42:2001;3741-3743 (f) Lusinchi M., Stanbury T.V., Zard S.Z. Chem. Commun. 2002;1532-1533 (g) Fahrat S., Marek I. Angew. Chem. Int. Ed. 41:2002;1410-1412 (h) Teyssot M.L., Fayolle M., Philouze C., Dupuy C. Eur. J. Org. Chem. 2002;54-62.
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For example: (a) Paquette L.A., Leit S.M. J. Am. Chem. Soc. 121:1999;8926-8927 (b) Paquette L.A., Fabris F., Tae J., Gallucci J.C., Hofferberth J.E. J. Am. Chem. Soc. 122:2000;3391-3398 (c) Fürstner A., Gastner T., Weintritt H. J. Org. Chem. 64:1999;2361-2366 (d) Fürstner A., Ackermann L. Chem. Commun. 1999;95-98.
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For example: (a) Paquette L.A., Leit S.M. J. Am. Chem. Soc. 121:1999;8926-8927 (b) Paquette L.A., Fabris F., Tae J., Gallucci J.C., Hofferberth J.E. J. Am. Chem. Soc. 122:2000;3391-3398 (c) Fürstner A., Gastner T., Weintritt H. J. Org. Chem. 64:1999;2361-2366 (d) Fürstner A., Ackermann L. Chem. Commun. 1999;95-98.
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For example: (a) Paquette L.A., Leit S.M. J. Am. Chem. Soc. 121:1999;8926-8927 (b) Paquette L.A., Fabris F., Tae J., Gallucci J.C., Hofferberth J.E. J. Am. Chem. Soc. 122:2000;3391-3398 (c) Fürstner A., Gastner T., Weintritt H. J. Org. Chem. 64:1999;2361-2366 (d) Fürstner A., Ackermann L. Chem. Commun. 1999;95-98.
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It should be noted, however, that the structurally very similar complex 1d was found to be not reactive in cross-metathesis of vinyl sulfones
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It should be noted, however, that the structurally very similar complex 1d was found to be not reactive in cross-metathesis of vinyl sulfones: Chatterjee A.K., Morgan J.P., Scholl M., Grubbs R.H. J. Am. Chem. Soc. 122:2000;3783-3784.
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0001039117
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4-(1-sulfinyldiene)-iron(0) tricarbonyl complexes (protected vinyl sulfoxides), see:
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4-(1-sulfinyldiene)-iron(0) tricarbonyl complexes (protected vinyl sulfoxides), see: Paley R.S., Estroff L.A., Gauguet J.-M., Hunt D.K., Newlin R.C. Org. Lett. 2:2000;365-368.
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For recent application, see:
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A referee suggested that the inability of vinyl sulfoxides to participate in the CM reaction can be also explained by a red-ox catalyst degradation, as it is known that sulfoxides can oxidise Fisher-type carbenes, cf: We gratefully acknowledge a referee for pointing out this possibility
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A referee suggested that the inability of vinyl sulfoxides to participate in the CM reaction can be also explained by a red-ox catalyst degradation, as it is known that sulfoxides can oxidise Fisher-type carbenes, cf: Wienand A., Reissig H.U. Organometallics. 9:1990;3133-3142. We gratefully acknowledge a referee for pointing out this possibility.
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