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Volumn 9, Issue 7, 2003, Pages 1585-1593

Driving force dependence of intermolecular electron-transfer reactions of fullerenes

Author keywords

Electron transfer; Fullerenes; Marcus inverted region; Photochemistry; Time resolved spectroscopy

Indexed keywords

ELECTRON TRANSITIONS; FULLERENES; LASER APPLICATIONS; OXIDATION; PHOTOLYSIS; POSITIVE IONS;

EID: 0037419297     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200390182     Document Type: Article
Times cited : (165)

References (111)
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    • There have been considerable discussion on the reasons to explain the no observance of the Marcus inverted region in the bimolecular electron-transfer reactions, see: a) A. Weller, K. Zacharaasse, Chem. Phys. Lett. 1971, 10, 590; (b) P. Suppan, Top. Curr. Chem. 1992, 163, 95; (c) S. Efrima, M. Bixon, Chem. Phys. Lett. 1974, 25, 34; (d) B. S. Brunschwig, S. Ehrenson, N. Sutin, J. Am. Chem. Soc. 1984, 106, 6858; (e) A. V. Barzykin, P. A. Frantsuzov, K. Seki, M. Tachiya, Adv. Chem. Phys. 2002, 123, 511, and references cited therein.
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    • There have been considerable discussion on the reasons to explain the no observance of the Marcus inverted region in the bimolecular electron-transfer reactions, see: a) A. Weller, K. Zacharaasse, Chem. Phys. Lett. 1971, 10, 590; (b) P. Suppan, Top. Curr. Chem. 1992, 163, 95; (c) S. Efrima, M. Bixon, Chem. Phys. Lett. 1974, 25, 34; (d) B. S. Brunschwig, S. Ehrenson, N. Sutin, J. Am. Chem. Soc. 1984, 106, 6858; (e) A. V. Barzykin, P. A. Frantsuzov, K. Seki, M. Tachiya, Adv. Chem. Phys. 2002, 123, 511, and references cited therein.
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    • There have been considerable discussion on the reasons to explain the no observance of the Marcus inverted region in the bimolecular electron-transfer reactions, see: a) A. Weller, K. Zacharaasse, Chem. Phys. Lett. 1971, 10, 590; (b) P. Suppan, Top. Curr. Chem. 1992, 163, 95; (c) S. Efrima, M. Bixon, Chem. Phys. Lett. 1974, 25, 34; (d) B. S. Brunschwig, S. Ehrenson, N. Sutin, J. Am. Chem. Soc. 1984, 106, 6858; (e) A. V. Barzykin, P. A. Frantsuzov, K. Seki, M. Tachiya, Adv. Chem. Phys. 2002, 123, 511, and references cited therein.
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    • There have been considerable discussion on the reasons to explain the no observance of the Marcus inverted region in the bimolecular electron-transfer reactions, see: a) A. Weller, K. Zacharaasse, Chem. Phys. Lett. 1971, 10, 590; (b) P. Suppan, Top. Curr. Chem. 1992, 163, 95; (c) S. Efrima, M. Bixon, Chem. Phys. Lett. 1974, 25, 34; (d) B. S. Brunschwig, S. Ehrenson, N. Sutin, J. Am. Chem. Soc. 1984, 106, 6858; (e) A. V. Barzykin, P. A. Frantsuzov, K. Seki, M. Tachiya, Adv. Chem. Phys. 2002, 123, 511, and references cited therein.
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    • and references cited therein
    • There have been considerable discussion on the reasons to explain the no observance of the Marcus inverted region in the bimolecular electron-transfer reactions, see: a) A. Weller, K. Zacharaasse, Chem. Phys. Lett. 1971, 10, 590; (b) P. Suppan, Top. Curr. Chem. 1992, 163, 95; (c) S. Efrima, M. Bixon, Chem. Phys. Lett. 1974, 25, 34; (d) B. S. Brunschwig, S. Ehrenson, N. Sutin, J. Am. Chem. Soc. 1984, 106, 6858; (e) A. V. Barzykin, P. A. Frantsuzov, K. Seki, M. Tachiya, Adv. Chem. Phys. 2002, 123, 511, and references cited therein.
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    • note
    • Although the reorganization energies of various aromatic compounds vary depending on the compounds, the difference may be small enough to allow the fit of the curve with the averaged reorganization energy. See ref. [25].
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    • 60. This may be the reason why the bimolecular electron transfer rate is still diffusion-limited.
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    • note
    • 2 is rather limited.
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    • note
    • .-.
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    • 0 values of metalloporphyrin π-radical anions, see: a) F. D'Souza, M. E. Zandler, P. Tagliatesta, Z. Ou, J. Shao, E. Van Caemelbecke, K. M. Kadish, Inorg. Chem. 1998, 37, 4567; (b) K. M. Kadish, J.-L. Cornillon, A. Coutsolelos, R. Guilard, Inorg. Chem. 1987. 26, 4167; (c) K. M. Kadish, J.-L. Cornillon, P. Cocolios, A. Tabard, R. Guilard, Inorg. Chem. 1985, 24, 3645; (d) R. Guilard, J.-M. Barbe, A. Boukhris, C. Lecomte, J. E. Anderson, Q. Xu, K. M. Kadish, J. Chem. Soc. Dalton Trans. 1988, 1109.
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    • 0 values of metalloporphyrin π-radical anions, see: a) F. D'Souza, M. E. Zandler, P. Tagliatesta, Z. Ou, J. Shao, E. Van Caemelbecke, K. M. Kadish, Inorg. Chem. 1998, 37, 4567; (b) K. M. Kadish, J.-L. Cornillon, A. Coutsolelos, R. Guilard, Inorg. Chem. 1987. 26, 4167; (c) K. M. Kadish, J.-L. Cornillon, P. Cocolios, A. Tabard, R. Guilard, Inorg. Chem. 1985, 24, 3645; (d) R. Guilard, J.-M. Barbe, A. Boukhris, C. Lecomte, J. E. Anderson, Q. Xu, K. M. Kadish, J. Chem. Soc. Dalton Trans. 1988, 1109.
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    • 0 values of metalloporphyrin π-radical anions, see: a) F. D'Souza, M. E. Zandler, P. Tagliatesta, Z. Ou, J. Shao, E. Van Caemelbecke, K. M. Kadish, Inorg. Chem. 1998, 37, 4567; (b) K. M. Kadish, J.-L. Cornillon, A. Coutsolelos, R. Guilard, Inorg. Chem. 1987. 26, 4167; (c) K. M. Kadish, J.-L. Cornillon, P. Cocolios, A. Tabard, R. Guilard, Inorg. Chem. 1985, 24, 3645; (d) R. Guilard, J.-M. Barbe, A. Boukhris, C. Lecomte, J. E. Anderson, Q. Xu, K. M. Kadish, J. Chem. Soc. Dalton Trans. 1988, 1109.
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    • note
    • The diffusion-limited plateau region in Figure 8 gives only the limit of the λ value and the exact value of λ is determined by the values below the diffusion limit.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.