Synthesis and isolation of a fullerene carbocation (C76+)

Journal of the American Chemical Society

Volumn 118, Issue 51, 1996, Pages 13093-13094

  Bolskar, Robert D ^a   Mathur, Rajeev S ^a   Reed, Christopher A ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FULLERENE;

ARTICLE; DRUG PURIFICATION; DRUG SYNTHESIS; INFRARED SPECTROPHOTOMETRY; NUCLEAR MAGNETIC RESONANCE; TECHNIQUE;

EID: 0030450482     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja962294n     Document Type: Article

References (28)

1. Hirsch, A. The Chemistry of the Fullerenes; Georg Thieme Verlag: Stuttgart, 1994.
2. (a) Bausch, J. W.; Prakash, G. K. S.; Olah, G. A.; Tse, D. S.; Lorents, D. C.; Bae, Y. K.; Malhotra, R. J. Am. Chem. Soc. 1991, 113, 3205-3206.
3. (b) Kukolich, S. G.; Huffman, D. R. Chem. Phys. Lett. 1991, 182, 263-265.
4. (c) Thomann, H.; Bernardo, M.; Miller, G. P. J. Am. Chem. Soc. 1992, 114, 6593-6594.
5. (d) Miller, G. P.; Hsu, C. S.; Thomann, H.; Chiang, L. Y.: Bernardo, M. Mater. Res. Soc. Symp. Proc. 1992, 247, 293-300.
6. (e) Olah, G. A.; Bucsi, I.; Aniszfeld, R.; Prakash, G. K. S. Carbon 1992, 30, 1203-1211.
7. (f) Baumgarten, M.; Gherghel, L. Progress in Fullerene Research; World Scientific: Singapore, 1994; p 384-388.
8. (g) Cataldo, F. Spectrochim. Acta 1995, 51A. 405-414.
9. See: (a) Foote, C. S. Top. Curr. Chem. 1993, 169, 347-363. (b) Guldi, D. M.; Neta, P.; Asmus, K.-D. J. Phys. Chem. 1994, 98, 4617-4621 and earlier references therein.
10. See: (a) Foote, C. S. Top. Curr. Chem. 1993, 169, 347-363. (b) Guldi, D. M.; Neta, P.; Asmus, K.-D. J. Phys. Chem. 1994, 98, 4617-4621 and earlier references therein.
11. (a) Xie, Q.; Arias, F.; Echegoyen, L. J. Am. Chem. Soc. 1993, 115, 9818-9819.
12. (b) Meerholz, K.; Tschuncky, P.; Heinze, J. J. Electroanal. Chem. 1993, 347, 425-433.
13. Yang, Y.; Arias, F.; Echegoyen, L.; Chibante, L. P.; Flanagan, S.; Robertson, A.; Wilson L. J. J. Am. Chem. Soc. 1995, 117, 7801-7804.
14. Schmidt, W.; Steckhan, E. Chem. Ber. 1980, 113, 577-585.
15. Xie, Z.; Manning, J.; Reed, R. W.; Mathur, R.; Boyd, P. D. W.; Benesi, A.; Reed, C. A. J. Am. Chem. Soc. 1996, 118, 2922-2928.
16. Liston, D. J.; Lee, Y. J.; Scheldt, W. R.; Reed C. A. J. Am. Chem. Soc. 1989, 111, 6643-6647.
17. 76 (99.8%) was purchased from TechnoCarbo.
18. -]: found 7.6:1; calcd 1.83:1.
19. Michel, R. H.; Schreiber, H.; Gierden, R.; Hennrich, F.; Rockenberger, J.; Beck, R. D.; Kappes, M. M.; Lehner, C.; Adelmann, P.; Armbruster; J. F. Ber. Bunsen-Ges. Phys. Chem. 1994, 98, 975-978.
20. (a) Colt, J. R.; Scuseria, G. E. J. Phys. Chem. 1992, 96, 10265-10268.
21. (b) Haddon, R. Personal communication.
22. Madec, C.; Courtot-Coupez, J. J. Etectroanal. Chem. 1977, 84, 177-185.
23. Shida, T. Electronic Absorption Spectra of Radical Ions; Elsevier: Amsterdam, The Netherlands, 1988; p 159.
24. 76 is commercially available in milligram quantities at ca. $40 000 per gram.
25. 1
26. 1
27. 1
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