Marcus inverted region in the photoinduced electron transfer reactions of ruthenium(II)-polypyridine complexes with phenolate ions

Journal of Physical Chemistry A

Volumn 101, Issue 44, 1997, Pages 8195-8199

  Thanasekaran, P ^a   Rajendran, T ^a   Rajagopal, S ^a   Srinivasan, C ^a   Ramaraj, R ^a   Ramamurthy, P ^b   Venkatachalapathy, B ^b  

^a MADURAI KAMARAJ UNIVERSITY   (India)

^b UNIVERSITY OF MADRAS   (India)

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE TRANSFER; ELECTRON TRANSITIONS; GIBBS FREE ENERGY; MATHEMATICAL MODELS; PHOTOCHEMICAL REACTIONS; RUTHENIUM COMPOUNDS;

MARCUS INVERTED REGION; RUTHENIUM POLYPYRIDYL;

METALLORGANIC POLYMERS;

EID: 0031248157     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp971746v     Document Type: Article

References (57)

1. Chanon, M.; Fox, M. A. Photoinduced Electron Transfer; Elsevier: New York, 1988; Vol. 1-4.
2. Kavarnos, G. J. Fundamentals of Photoinduced Electron Transfer; VCH: New York, 1993.
3. Bolton, J. R., Mataga, N., McLendon, G., Eds. Electron Transfer in Inorganic, Organic and Biological Systems; Advances in Chemistry Series 228; American Chemcial Society: Washington, DC, 1991.
4. Mattay, J., Ed. Photoinduced Electron Transfer; Topics in Current Chemistry 163; Springer-Verlag: Berlin, 1992.
5. Marcus, R. A.; Sutin, N. Biochim. Biophys. Acta 1985, 811, 265.
6. Eberson, L. Electron-Transfer Reactions in Organic Chemistry; Springer-Verlag: Berlin, 1987.
7. Astruc, D. Electron Transfer and Radical Processes in Transition Metal Chemistry; VCH: New York, 1995.
8. Suppan, P. Top. Curr. Chem. 1992, 163, 95.
9. Miller, J. R.; Calcaterra, L. T.; Closs, G. L. J. Am. Chem. Soc. 1984, 106, 3047. Closs, G. L.; Miller, J. R. Science 1988, 240, 440. Liang, N.; Miller, J. R.; Closs, G. L. J. Am. Chem. Soc. 1990, 112, 5353.
10. Miller, J. R.; Calcaterra, L. T.; Closs, G. L. J. Am. Chem. Soc. 1984, 106, 3047. Closs, G. L.; Miller, J. R. Science 1988, 240, 440. Liang, N.; Miller, J. R.; Closs, G. L. J. Am. Chem. Soc. 1990, 112, 5353.
11. Miller, J. R.; Calcaterra, L. T.; Closs, G. L. J. Am. Chem. Soc. 1984, 106, 3047. Closs, G. L.; Miller, J. R. Science 1988, 240, 440. Liang, N.; Miller, J. R.; Closs, G. L. J. Am. Chem. Soc. 1990, 112, 5353.
12. Gould, I. R.; Ege, D.; Moser, J. E.; Farid, S. J. Am. Chem. Soc. 1990, 112, 4290. Gould, I. R.; Farid, S. J. Phys. Chem. 1992, 96, 7635. Arnold, B. R.; Noukakis, D.; Farid, S.; Goodman, J. L.; Gould, I. R. J. Am. Chem. Soc. 1995, 117, 4399. Gould, I. R.; Farid, S. Acc. Chem. Res. 1996, 29, 522.
13. Gould, I. R.; Ege, D.; Moser, J. E.; Farid, S. J. Am. Chem. Soc. 1990, 112, 4290. Gould, I. R.; Farid, S. J. Phys. Chem. 1992, 96, 7635. Arnold, B. R.; Noukakis, D.; Farid, S.; Goodman, J. L.; Gould, I. R. J. Am. Chem. Soc. 1995, 117, 4399. Gould, I. R.; Farid, S. Acc. Chem. Res. 1996, 29, 522.
14. Gould, I. R.; Ege, D.; Moser, J. E.; Farid, S. J. Am. Chem. Soc. 1990, 112, 4290. Gould, I. R.; Farid, S. J. Phys. Chem. 1992, 96, 7635. Arnold, B. R.; Noukakis, D.; Farid, S.; Goodman, J. L.; Gould, I. R. J. Am. Chem. Soc. 1995, 117, 4399. Gould, I. R.; Farid, S. Acc. Chem. Res. 1996, 29, 522.
15. Gould, I. R.; Ege, D.; Moser, J. E.; Farid, S. J. Am. Chem. Soc. 1990, 112, 4290. Gould, I. R.; Farid, S. J. Phys. Chem. 1992, 96, 7635. Arnold, B. R.; Noukakis, D.; Farid, S.; Goodman, J. L.; Gould, I. R. J. Am. Chem. Soc. 1995, 117, 4399. Gould, I. R.; Farid, S. Acc. Chem. Res. 1996, 29, 522.
16. McCleskey, T. M.; Winkler, J. R.; Gray, H. B. J. Am. Chem. Soc. 1992, 114, 6935. McCleskey, T. M.; Winkler, J. R.; Gray, H. B. Inorg. Chim. Acta. 1994, 225, 319.
17. McCleskey, T. M.; Winkler, J. R.; Gray, H. B. J. Am. Chem. Soc. 1992, 114, 6935. McCleskey, T. M.; Winkler, J. R.; Gray, H. B. Inorg. Chim. Acta. 1994, 225, 319.
18. Gramp. G. Angew. Chem., Int. Ed. Engl. 1993, 32, 691. Kikuchi, K.; Miwa, T.; Takahashi, Y.; Ikeda, H.; Miyashi, T. J. Phys. Chem. 1993, 97, 5070.
19. Gramp. G. Angew. Chem., Int. Ed. Engl. 1993, 32, 691. Kikuchi, K.; Miwa, T.; Takahashi, Y.; Ikeda, H.; Miyashi, T. J. Phys. Chem. 1993, 97, 5070.
20. Murtaza, Z.; Graff, D. K.; Zipp, A. P.; Worl, L. A.; Jones, W. F., Jr.; Bates, W. D.; Meyer, T. J. J. Phys. Chem. 1994, 98, 10504.
21. Turro, C.; Zaleski, J. M.; Karabatsos, Y. M.; Nocera, D. G. J. Am. Chem. Soc. 1996, 118, 6060 and references therein.
22. Hug, G. L.; Marciniak, B. J. Phys. Chem. 1995, 99, 1478.
23. Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S.; Belser, P.; Von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85. Krause, R. A. Struct. Bonding 1987, 67, 1.
24. Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S.; Belser, P.; Von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85. Krause, R. A. Struct. Bonding 1987, 67, 1.
25. Kalyanasundaram, K. Coord. Chem. Rev. 1982, 46, 159. Kalyanasundaram, K. Photochemistry of Polypyridine and Porphyrin Complexes; Academic Press: New York, 1992.
26. Kalyanasundaram, K. Coord. Chem. Rev. 1982, 46, 159. Kalyanasundaram, K. Photochemistry of Polypyridine and Porphyrin Complexes; Academic Press: New York, 1992.
27. Kalyanasundaram, K., Gratzel, M., Eds. Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds; Kluwar Academic: Dordrecht, 1993.
28. Connolly, J. S., Eds. Photochemical Conversion and Storage of Solar Energy; Academic Press: New York, 1981.
29. Gratzel, M., Eds. Energy Resources through Photochemistry and Catalysis; Academic Press: New York, 1983.
30. Miedlar, K.; Das, P. K. J. Am. Chem. Soc. 1982, 104, 7462.
31. Rajagopal, S.; Allen Gnanaraj. G.; Mathew, A.; Srinivasan, C. J. Photochem. Photobiol. A 1992, 69, 83.
32. Vera. D. M.; Arguello, G. A.; Arguello, G. A.; Gsponer, H. E. J. Photochem. Photobiol. A 1993, 76, 13. Senz, A.; Gsponer, H. E. J. Colloid Interface Sci. 1994, 165, 60 and references therein.
33. Vera. D. M.; Arguello, G. A.; Arguello, G. A.; Gsponer, H. E. J. Photochem. Photobiol. A 1993, 76, 13. Senz, A.; Gsponer, H. E. J. Colloid Interface Sci. 1994, 165, 60 and references therein.
34. Rillema, D. P.; Jones, D. S.; Woods, C.; Levy, H. A. Inorg.Chem. 1992, 31, 2935.
35. Kawanishi, Y.; Kitamura, N.; Tazuke, S. Inorg. Chem. 1989, 28, 2968. Haga, M. A.; Dodsworth, E. S.; Eryavec, G.; Seymour, P.; Lever, A. B. P. Inorg. Chem. 1985, 24, 1901. Liu, C. T.; Bottcher, W.; Chou, M.; Crutz, C.; Sutin, N. J. Am. Chem. Soc. 1976, 98, 6536. Brewer, K. J.; Murphy, W. R., Jr.; Spurlin, S. R.; Peterson, J. D. Inorg. Chem. 1986, 25, 882. Kitamura, N.; Rajagopal, S.; Tazuke, S. J. Phys. Chem. 1987, 91, 3767.
36. Kawanishi, Y.; Kitamura, N.; Tazuke, S. Inorg. Chem. 1989, 28, 2968. Haga, M. A.; Dodsworth, E. S.; Eryavec, G.; Seymour, P.; Lever, A. B. P. Inorg. Chem. 1985, 24, 1901. Liu, C. T.; Bottcher, W.; Chou, M.; Crutz, C.; Sutin, N. J. Am. Chem. Soc. 1976, 98, 6536. Brewer, K. J.; Murphy, W. R., Jr.; Spurlin, S. R.; Peterson, J. D. Inorg. Chem. 1986, 25, 882. Kitamura, N.; Rajagopal, S.; Tazuke, S. J. Phys. Chem. 1987, 91, 3767.
37. Kawanishi, Y.; Kitamura, N.; Tazuke, S. Inorg. Chem. 1989, 28, 2968. Haga, M. A.; Dodsworth, E. S.; Eryavec, G.; Seymour, P.; Lever, A. B. P. Inorg. Chem. 1985, 24, 1901. Liu, C. T.; Bottcher, W.; Chou, M.; Crutz, C.; Sutin, N. J. Am. Chem. Soc. 1976, 98, 6536. Brewer, K. J.; Murphy, W. R., Jr.; Spurlin, S. R.; Peterson, J. D. Inorg. Chem. 1986, 25, 882. Kitamura, N.; Rajagopal, S.; Tazuke, S. J. Phys. Chem. 1987, 91, 3767.
38. Kawanishi, Y.; Kitamura, N.; Tazuke, S. Inorg. Chem. 1989, 28, 2968. Haga, M. A.; Dodsworth, E. S.; Eryavec, G.; Seymour, P.; Lever, A. B. P. Inorg. Chem. 1985, 24, 1901. Liu, C. T.; Bottcher, W.; Chou, M.; Crutz, C.; Sutin, N. J. Am. Chem. Soc. 1976, 98, 6536. Brewer, K. J.; Murphy, W. R., Jr.; Spurlin, S. R.; Peterson, J. D. Inorg. Chem. 1986, 25, 882. Kitamura, N.; Rajagopal, S.; Tazuke, S. J. Phys. Chem. 1987, 91, 3767.
39. Kawanishi, Y.; Kitamura, N.; Tazuke, S. Inorg. Chem. 1989, 28, 2968. Haga, M. A.; Dodsworth, E. S.; Eryavec, G.; Seymour, P.; Lever, A. B. P. Inorg. Chem. 1985, 24, 1901. Liu, C. T.; Bottcher, W.; Chou, M.; Crutz, C.; Sutin, N. J. Am. Chem. Soc. 1976, 98, 6536. Brewer, K. J.; Murphy, W. R., Jr.; Spurlin, S. R.; Peterson, J. D. Inorg. Chem. 1986, 25, 882. Kitamura, N.; Rajagopal, S.; Tazuke, S. J. Phys. Chem. 1987, 91, 3767.
40. Ramamurthy, P. Chem. Educ. 1993, 9, 56.
41. Parsons, B. J.; Beaumont, P. C.; Navaratnam, S.; Harrison, W. D.; Akasheh, T. S.; Othman, M. Inorg. Chem. 1994, 33, 157. Akasheh, T. S.; Beaumont, P. C.; Parsons, B. J.; Phillips, G. O. J. Phys. Chem. 1986, 90, 5651. Neshvad, G.; Hoffman, M. Z. J. Phys. Chem. 1989, 93, 2445.
42. Parsons, B. J.; Beaumont, P. C.; Navaratnam, S.; Harrison, W. D.; Akasheh, T. S.; Othman, M. Inorg. Chem. 1994, 33, 157. Akasheh, T. S.; Beaumont, P. C.; Parsons, B. J.; Phillips, G. O. J. Phys. Chem. 1986, 90, 5651. Neshvad, G.; Hoffman, M. Z. J. Phys. Chem. 1989, 93, 2445.
43. Parsons, B. J.; Beaumont, P. C.; Navaratnam, S.; Harrison, W. D.; Akasheh, T. S.; Othman, M. Inorg. Chem. 1994, 33, 157. Akasheh, T. S.; Beaumont, P. C.; Parsons, B. J.; Phillips, G. O. J. Phys. Chem. 1986, 90, 5651. Neshvad, G.; Hoffman, M. Z. J. Phys. Chem. 1989, 93, 2445.
44. Debye, P. Trans. Electrochem. Soc. 1942, 82, 265. Brede, O.; Orthner, H.; Zubarev, V.; Hermann, R. J. Phys. Chem. 1996, 100, 7097.
45. Debye, P. Trans. Electrochem. Soc. 1942, 82, 265. Brede, O.; Orthner, H.; Zubarev, V.; Hermann, R. J. Phys. Chem. 1996, 100, 7097.
46. Maruyama, Y.; Kaizu, Y. J. Phys. Chem. 1995, 99, 6152.
47. Jakobsen, S.; Mikkelsen, K. V.; Pedersen, S. U. J. Phys. Chem. 1996, 100, 7411.
48. Armstrong, D. A.; Sun, Q.; Schuler, R. H. J. Phys. Chem. 1996, 100, 9892.
49. Arnett, E. M.; Amarnath, K.; Harvey, N. G.; Venimadhavan, S. J. J. Am. Chem. Soc. 1990, 112, 7346.
50. Bordwell, F. G.; Cheng, J. P. J. Am. Chem. Soc. 1991, 113, 1736.
51. Andrieux, C. P.; Saveant, J. M. In Investigation of Rates and Mechanisms of Reactions; Bernasconi, C. F., Ed.; John Wiley: New York, 1986; Vol. 6, Chapter 7. Denisov, E. T.; Khudyakov, I. V. Chem. Rev. 1987, 87, 1313. Hapiot, P.; Pinson, J.; Yousfi, N. New J. Chem. 1992, 16, 877.
52. Andrieux, C. P.; Saveant, J. M. In Investigation of Rates and Mechanisms of Reactions; Bernasconi, C. F., Ed.; John Wiley: New York, 1986; Vol. 6, Chapter 7. Denisov, E. T.; Khudyakov, I. V. Chem. Rev. 1987, 87, 1313. Hapiot, P.; Pinson, J.; Yousfi, N. New J. Chem. 1992, 16, 877.
53. Andrieux, C. P.; Saveant, J. M. In Investigation of Rates and Mechanisms of Reactions; Bernasconi, C. F., Ed.; John Wiley: New York, 1986; Vol. 6, Chapter 7. Denisov, E. T.; Khudyakov, I. V. Chem. Rev. 1987, 87, 1313. Hapiot, P.; Pinson, J.; Yousfi, N. New J. Chem. 1992, 16, 877.
54. Gould, I. R.; Noukakis, D.; Gomez-Jahn, L.; Goodman, J. L.; Farid, S. J. Am. Chem. Soc. 1993, 115, 4405.
55. Doolen, R.; Simon, J. D.; Baldridge, K. K. J. Phys. Chem. 1995, 99, 13938.
56. Clark, C. D.; Hoffman, M. Z. J. Phys. Chem. 1996, 100, 14688.
57. Marcus, R. A. Angew. Chem., Int. Ed. Engl. 1993, 32, 1111.