Water-soluble colloidal Adams catalyst: Preparation and use in catalysis [2]

Journal of the American Chemical Society

Volumn 121, Issue 34, 1999, Pages 7933-7934

  Reetz, Manfred T ^a   Koch, Michael G ^a  

^a MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

PLATINUM; WATER;

AQUEOUS SOLUTION; CATALYSIS; CATALYST; COLLOID; HYDROGENATION; LETTER; SOLUBILITY; TRANSMISSION ELECTRON MICROSCOPY; X RAY ANALYSIS;

EID: 0033198530     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9906498     Document Type: Letter

References (36)

1. (a) Voorhees, V.; Adams, R. J. Am. Chem. Soc. 1922, 44, 1397-1405.
2. (b) Adams, R.; Shriner, R. L. J. Am. Chem. Soc. 1923, 45, 2171-2179.
3. (a) Adams, R.; Voorhees, V.; Shriner, R. L. In Org. Synth. Coll., Vol. I., 2nd ed.; Blatt, A. H., Ed.; Wiley: New York, 1941; pp 463-470.
4. (b) Frampton, V. L.; Edwards, J. D., Jr.; Henze, H. R. J. Am. Chem. Soc. 1951, 73, 4432-4434.
5. Paquette, L. A., Ed. Encyclopedia of Reagents for Organic Synthesis, Vol. 6; Wiley: Chichester, 1995.
6. Augustine, R. L. Catalytic Hydrogenation; Dekker: New York, 1965. Previous work on platinum oxide catalysts:
7. (e) Willstätter, R.; Waldschmidt-Leitz, E. Chem. Ber. 1921, 54, 4, B113-B138, and literature cited therein.
8. Ertl, G.; Knözinger, H.; Weitkamp, J., Eds. Handbook of Heterogeneous Catalysis, Vol. 1-5; VCH: Weinheim, Germany, 1997.
9. Reetz, M. T.; Koch, M. G. Patent applied for DE-A 19852547.8, 1998.
10. (a) Schmid, G., Ed. Clusters and Colloids: From Theory to Applications; VCH: Weinheim, Germany, 1994.
11. (b) Fendler, J. H., Ed. Nanoparticles and Nanostructured Films; Wiley-VCH: Weinheim, Germany, 1998.
12. Examples of metal oxide colloids: (a) Lume-Pereira, C.; Baral, S.; Henglein, A.; Janata, E. J. Phys. Chem. 1985, 89, 5772-5778. (b) Harriman, A.; Thomas, J. M.; Millward, G. R. New J. Chem. 1987, 11, 757-762. (c) Kalyanasundaram, K.; Grätzel, M. Angew. Chem. 1979, 91, 759-760; Angew. Chem., Int. Ed. Engl. 1979, 18, 701. (d) Christensen, P. A.; Harriman, A.; Porter, G.; Neta, P. J. Chem. Soc., Faraday Trans. 2 1984, 80, 1451-1464. (e) Claerbout, A.; Nagy, J. B. Preparation of Catalysts V. In Stud. Surf. Sci. Catal., Vol. 63; Poncelet, G., Ed.; Elsevier: Amsterdam, 1991; pp 705-716. (f) Pileni, M. P. Langmuir 1997, 13, 3266-3276. (g) Reetz, M. T.; Quaiser, S. A.; Winter, M.; Becker, J. A.; Schäfer, R.; Stimming, U.; Marmann, A.; Vogel, R.; Konno, T. Angew. Chem. 1996, 108, 2228-2230; Angew. Chem., Int. Ed. Engl. 1996, 35, 2092. Examples of metal sulfide colloids: (h) Weller, H.; Eychmüller, A. Semiconductor Nanoclusters: Physical, Chemical, and Catalytic Aspects. In Stud. Surf. Sci. Catal., Vol. 103; Kamat, P. V.; Meisel, D., Eds.; Elsevier: Amsterdam, 1996; pp 5-22.
13. Examples of metal oxide colloids: (a) Lume-Pereira, C.; Baral, S.; Henglein, A.; Janata, E. J. Phys. Chem. 1985, 89, 5772-5778. (b) Harriman, A.; Thomas, J. M.; Millward, G. R. New J. Chem. 1987, 11, 757-762. (c) Kalyanasundaram, K.; Grätzel, M. Angew. Chem. 1979, 91, 759-760; Angew. Chem., Int. Ed. Engl. 1979, 18, 701. (d) Christensen, P. A.; Harriman, A.; Porter, G.; Neta, P. J. Chem. Soc., Faraday Trans. 2 1984, 80, 1451-1464. (e) Claerbout, A.; Nagy, J. B. Preparation of Catalysts V. In Stud. Surf. Sci. Catal., Vol. 63; Poncelet, G., Ed.; Elsevier: Amsterdam, 1991; pp 705-716. (f) Pileni, M. P. Langmuir 1997, 13, 3266-3276. (g) Reetz, M. T.; Quaiser, S. A.; Winter, M.; Becker, J. A.; Schäfer, R.; Stimming, U.; Marmann, A.; Vogel, R.; Konno, T. Angew. Chem. 1996, 108, 2228-2230; Angew. Chem., Int. Ed. Engl. 1996, 35, 2092. Examples of metal sulfide colloids: (h) Weller, H.; Eychmüller, A. Semiconductor Nanoclusters: Physical, Chemical, and Catalytic Aspects. In Stud. Surf. Sci. Catal., Vol. 103; Kamat, P. V.; Meisel, D., Eds.; Elsevier: Amsterdam, 1996; pp 5-22.
14. Examples of metal oxide colloids: (a) Lume-Pereira, C.; Baral, S.; Henglein, A.; Janata, E. J. Phys. Chem. 1985, 89, 5772-5778. (b) Harriman, A.; Thomas, J. M.; Millward, G. R. New J. Chem. 1987, 11, 757-762. (c) Kalyanasundaram, K.; Grätzel, M. Angew. Chem. 1979, 91, 759-760; Angew. Chem., Int. Ed. Engl. 1979, 18, 701. (d) Christensen, P. A.; Harriman, A.; Porter, G.; Neta, P. J. Chem. Soc., Faraday Trans. 2 1984, 80, 1451-1464. (e) Claerbout, A.; Nagy, J. B. Preparation of Catalysts V. In Stud. Surf. Sci. Catal., Vol. 63; Poncelet, G., Ed.; Elsevier: Amsterdam, 1991; pp 705-716. (f) Pileni, M. P. Langmuir 1997, 13, 3266-3276. (g) Reetz, M. T.; Quaiser, S. A.; Winter, M.; Becker, J. A.; Schäfer, R.; Stimming, U.; Marmann, A.; Vogel, R.; Konno, T. Angew. Chem. 1996, 108, 2228-2230; Angew. Chem., Int. Ed. Engl. 1996, 35, 2092. Examples of metal sulfide colloids: (h) Weller, H.; Eychmüller, A. Semiconductor Nanoclusters: Physical, Chemical, and Catalytic Aspects. In Stud. Surf. Sci. Catal., Vol. 103; Kamat, P. V.; Meisel, D., Eds.; Elsevier: Amsterdam, 1996; pp 5-22.
15. Examples of metal oxide colloids: (a) Lume-Pereira, C.; Baral, S.; Henglein, A.; Janata, E. J. Phys. Chem. 1985, 89, 5772-5778. (b) Harriman, A.; Thomas, J. M.; Millward, G. R. New J. Chem. 1987, 11, 757-762. (c) Kalyanasundaram, K.; Grätzel, M. Angew. Chem. 1979, 91, 759-760; Angew. Chem., Int. Ed. Engl. 1979, 18, 701. (d) Christensen, P. A.; Harriman, A.; Porter, G.; Neta, P. J. Chem. Soc., Faraday Trans. 2 1984, 80, 1451-1464. (e) Claerbout, A.; Nagy, J. B. Preparation of Catalysts V. In Stud. Surf. Sci. Catal., Vol. 63; Poncelet, G., Ed.; Elsevier: Amsterdam, 1991; pp 705-716. (f) Pileni, M. P. Langmuir 1997, 13, 3266-3276. (g) Reetz, M. T.; Quaiser, S. A.; Winter, M.; Becker, J. A.; Schäfer, R.; Stimming, U.; Marmann, A.; Vogel, R.; Konno, T. Angew. Chem. 1996, 108, 2228-2230; Angew. Chem., Int. Ed. Engl. 1996, 35, 2092. Examples of metal sulfide colloids: (h) Weller, H.; Eychmüller, A. Semiconductor Nanoclusters: Physical, Chemical, and Catalytic Aspects. In Stud. Surf. Sci. Catal., Vol. 103; Kamat, P. V.; Meisel, D., Eds.; Elsevier: Amsterdam, 1996; pp 5-22.
16. Examples of metal oxide colloids: (a) Lume-Pereira, C.; Baral, S.; Henglein, A.; Janata, E. J. Phys. Chem. 1985, 89, 5772-5778. (b) Harriman, A.; Thomas, J. M.; Millward, G. R. New J. Chem. 1987, 11, 757-762. (c) Kalyanasundaram, K.; Grätzel, M. Angew. Chem. 1979, 91, 759-760; Angew. Chem., Int. Ed. Engl. 1979, 18, 701. (d) Christensen, P. A.; Harriman, A.; Porter, G.; Neta, P. J. Chem. Soc., Faraday Trans. 2 1984, 80, 1451-1464. (e) Claerbout, A.; Nagy, J. B. Preparation of Catalysts V. In Stud. Surf. Sci. Catal., Vol. 63; Poncelet, G., Ed.; Elsevier: Amsterdam, 1991; pp 705-716. (f) Pileni, M. P. Langmuir 1997, 13, 3266-3276. (g) Reetz, M. T.; Quaiser, S. A.; Winter, M.; Becker, J. A.; Schäfer, R.; Stimming, U.; Marmann, A.; Vogel, R.; Konno, T. Angew. Chem. 1996, 108, 2228-2230; Angew. Chem., Int. Ed. Engl. 1996, 35, 2092. Examples of metal sulfide colloids: (h) Weller, H.; Eychmüller, A. Semiconductor Nanoclusters: Physical, Chemical, and Catalytic Aspects. In Stud. Surf. Sci. Catal., Vol. 103; Kamat, P. V.; Meisel, D., Eds.; Elsevier: Amsterdam, 1996; pp 5-22.
17. Examples of metal oxide colloids: (a) Lume-Pereira, C.; Baral, S.; Henglein, A.; Janata, E. J. Phys. Chem. 1985, 89, 5772-5778. (b) Harriman, A.; Thomas, J. M.; Millward, G. R. New J. Chem. 1987, 11, 757-762. (c) Kalyanasundaram, K.; Grätzel, M. Angew. Chem. 1979, 91, 759-760; Angew. Chem., Int. Ed. Engl. 1979, 18, 701. (d) Christensen, P. A.; Harriman, A.; Porter, G.; Neta, P. J. Chem. Soc., Faraday Trans. 2 1984, 80, 1451-1464. (e) Claerbout, A.; Nagy, J. B. Preparation of Catalysts V. In Stud. Surf. Sci. Catal., Vol. 63; Poncelet, G., Ed.; Elsevier: Amsterdam, 1991; pp 705-716. (f) Pileni, M. P. Langmuir 1997, 13, 3266-3276. (g) Reetz, M. T.; Quaiser, S. A.; Winter, M.; Becker, J. A.; Schäfer, R.; Stimming, U.; Marmann, A.; Vogel, R.; Konno, T. Angew. Chem. 1996, 108, 2228-2230; Angew. Chem., Int. Ed. Engl. 1996, 35, 2092. Examples of metal sulfide colloids: (h) Weller, H.; Eychmüller, A. Semiconductor Nanoclusters: Physical, Chemical, and Catalytic Aspects. In Stud. Surf. Sci. Catal., Vol. 103; Kamat, P. V.; Meisel, D., Eds.; Elsevier: Amsterdam, 1996; pp 5-22.
18. Examples of metal oxide colloids: (a) Lume-Pereira, C.; Baral, S.; Henglein, A.; Janata, E. J. Phys. Chem. 1985, 89, 5772-5778. (b) Harriman, A.; Thomas, J. M.; Millward, G. R. New J. Chem. 1987, 11, 757-762. (c) Kalyanasundaram, K.; Grätzel, M. Angew. Chem. 1979, 91, 759-760; Angew. Chem., Int. Ed. Engl. 1979, 18, 701. (d) Christensen, P. A.; Harriman, A.; Porter, G.; Neta, P. J. Chem. Soc., Faraday Trans. 2 1984, 80, 1451-1464. (e) Claerbout, A.; Nagy, J. B. Preparation of Catalysts V. In Stud. Surf. Sci. Catal., Vol. 63; Poncelet, G., Ed.; Elsevier: Amsterdam, 1991; pp 705-716. (f) Pileni, M. P. Langmuir 1997, 13, 3266-3276. (g) Reetz, M. T.; Quaiser, S. A.; Winter, M.; Becker, J. A.; Schäfer, R.; Stimming, U.; Marmann, A.; Vogel, R.; Konno, T. Angew. Chem. 1996, 108, 2228-2230; Angew. Chem., Int. Ed. Engl. 1996, 35, 2092. Examples of metal sulfide colloids: (h) Weller, H.; Eychmüller, A. Semiconductor Nanoclusters: Physical, Chemical, and Catalytic Aspects. In Stud. Surf. Sci. Catal., Vol. 103; Kamat, P. V.; Meisel, D., Eds.; Elsevier: Amsterdam, 1996; pp 5-22.
19. Examples of metal oxide colloids: (a) Lume-Pereira, C.; Baral, S.; Henglein, A.; Janata, E. J. Phys. Chem. 1985, 89, 5772-5778. (b) Harriman, A.; Thomas, J. M.; Millward, G. R. New J. Chem. 1987, 11, 757-762. (c) Kalyanasundaram, K.; Grätzel, M. Angew. Chem. 1979, 91, 759-760; Angew. Chem., Int. Ed. Engl. 1979, 18, 701. (d) Christensen, P. A.; Harriman, A.; Porter, G.; Neta, P. J. Chem. Soc., Faraday Trans. 2 1984, 80, 1451-1464. (e) Claerbout, A.; Nagy, J. B. Preparation of Catalysts V. In Stud. Surf. Sci. Catal., Vol. 63; Poncelet, G., Ed.; Elsevier: Amsterdam, 1991; pp 705-716. (f) Pileni, M. P. Langmuir 1997, 13, 3266-3276. (g) Reetz, M. T.; Quaiser, S. A.; Winter, M.; Becker, J. A.; Schäfer, R.; Stimming, U.; Marmann, A.; Vogel, R.; Konno, T. Angew. Chem. 1996, 108, 2228-2230; Angew. Chem., Int. Ed. Engl. 1996, 35, 2092. Examples of metal sulfide colloids: (h) Weller, H.; Eychmüller, A. Semiconductor Nanoclusters: Physical, Chemical, and Catalytic Aspects. In Stud. Surf. Sci. Catal., Vol. 103; Kamat, P. V.; Meisel, D., Eds.; Elsevier: Amsterdam, 1996; pp 5-22.
20. Examples of metal oxide colloids: (a) Lume-Pereira, C.; Baral, S.; Henglein, A.; Janata, E. J. Phys. Chem. 1985, 89, 5772-5778. (b) Harriman, A.; Thomas, J. M.; Millward, G. R. New J. Chem. 1987, 11, 757-762. (c) Kalyanasundaram, K.; Grätzel, M. Angew. Chem. 1979, 91, 759-760; Angew. Chem., Int. Ed. Engl. 1979, 18, 701. (d) Christensen, P. A.; Harriman, A.; Porter, G.; Neta, P. J. Chem. Soc., Faraday Trans. 2 1984, 80, 1451-1464. (e) Claerbout, A.; Nagy, J. B. Preparation of Catalysts V. In Stud. Surf. Sci. Catal., Vol. 63; Poncelet, G., Ed.; Elsevier: Amsterdam, 1991; pp 705-716. (f) Pileni, M. P. Langmuir 1997, 13, 3266-3276. (g) Reetz, M. T.; Quaiser, S. A.; Winter, M.; Becker, J. A.; Schäfer, R.; Stimming, U.; Marmann, A.; Vogel, R.; Konno, T. Angew. Chem. 1996, 108, 2228-2230; Angew. Chem., Int. Ed. Engl. 1996, 35, 2092. Examples of metal sulfide colloids: (h) Weller, H.; Eychmüller, A. Semiconductor Nanoclusters: Physical, Chemical, and Catalytic Aspects. In Stud. Surf. Sci. Catal., Vol. 103; Kamat, P. V.; Meisel, D., Eds.; Elsevier: Amsterdam, 1996; pp 5-22.
21. Examples of metal oxide colloids: (a) Lume-Pereira, C.; Baral, S.; Henglein, A.; Janata, E. J. Phys. Chem. 1985, 89, 5772-5778. (b) Harriman, A.; Thomas, J. M.; Millward, G. R. New J. Chem. 1987, 11, 757-762. (c) Kalyanasundaram, K.; Grätzel, M. Angew. Chem. 1979, 91, 759-760; Angew. Chem., Int. Ed. Engl. 1979, 18, 701. (d) Christensen, P. A.; Harriman, A.; Porter, G.; Neta, P. J. Chem. Soc., Faraday Trans. 2 1984, 80, 1451-1464. (e) Claerbout, A.; Nagy, J. B. Preparation of Catalysts V. In Stud. Surf. Sci. Catal., Vol. 63; Poncelet, G., Ed.; Elsevier: Amsterdam, 1991; pp 705-716. (f) Pileni, M. P. Langmuir 1997, 13, 3266-3276. (g) Reetz, M. T.; Quaiser, S. A.; Winter, M.; Becker, J. A.; Schäfer, R.; Stimming, U.; Marmann, A.; Vogel, R.; Konno, T. Angew. Chem. 1996, 108, 2228-2230; Angew. Chem., Int. Ed. Engl. 1996, 35, 2092. Examples of metal sulfide colloids: (h) Weller, H.; Eychmüller, A. Semiconductor Nanoclusters: Physical, Chemical, and Catalytic Aspects. In Stud. Surf. Sci. Catal., Vol. 103; Kamat, P. V.; Meisel, D., Eds.; Elsevier: Amsterdam, 1996; pp 5-22.
22. (a) Reetz, M. T.; Helbig, W. J. Am. Chem. Soc. 1994, 116, 7401-7402.
23. (b) Reetz, M. T.; Helbig, W.; Quaiser, S. A. In Active Metals: Preparation, Characterization, Applications; Fürstner, A., Ed.; VCH: Weinheim, Germany, 1996; pp 279-297.
24. Reetz, M. T.; Helbig, W.; Quaiser, S. A., EP 0672 765 A1, March 4, 1995.
25. 2/2 colloid isolated by precipitation contains small amounts of Li (0.6%) and Cl (4.5%) in addition to Pt (13%), samples obtained by dialysis are essentially Li- and Cl-free: Li (0.02%), Cl (<0.1%).
26. We thank W. Grünert and M. Heber (Ruhr-Universität Bochum) for the XPS measurements.
27. We thank U. Kolb for the EXAFS studies.
28. (a) Hoekstra, H. R.; Siegel, S.; Gallagher, F. X. In Platinum Group Metals and Compounds; Advances in Chemistry Series, Vol. 98; American Chemical Society: Washington, DC, 1971; pp 39-53.
29. (b) Muller, O.; Roy, R. J. Less-Common Met. 1968, 16, 129-146.
30. 2/g.
31. Weast, R. C., Ed., CRC Handbook of Chemistry and Physics, 1st student ed.; CRC Press: Boca Raton, FL, 1988.
32. 2 colloids.
33. Other approaches to the preparation of electrocatalysts: (a) Oetjen, H.-F.; Schmidt, V. M.; Stimming, U.; Trila, F. J. Electrochem. Soc. 1996, 143, 3838-3842. (b) Krausa, M.; Vielstich, W. J. Electroanal. Chem. 1994, 579, 307-314. (c) Schmidt, T. J.; Noeske, M.; Gasteiger, H. A.; Behm, R. J.; Britz, P.; Brijoux, W.; Bönnemann, H. Langmuir 1997, 13, 2591-2595. (d) Reddington, E.; Sapienza, A.; Guran, B.; Viswanathan, R.; Sarangapani, S.; Smotkin, E. S.; Mallouk, T. E. Science (Washington, D.C.) 1998, 280, 1735- 1737.
34. Other approaches to the preparation of electrocatalysts: (a) Oetjen, H.-F.; Schmidt, V. M.; Stimming, U.; Trila, F. J. Electrochem. Soc. 1996, 143, 3838-3842. (b) Krausa, M.; Vielstich, W. J. Electroanal. Chem. 1994, 579, 307-314. (c) Schmidt, T. J.; Noeske, M.; Gasteiger, H. A.; Behm, R. J.; Britz, P.; Brijoux, W.; Bönnemann, H. Langmuir 1997, 13, 2591-2595. (d) Reddington, E.; Sapienza, A.; Guran, B.; Viswanathan, R.; Sarangapani, S.; Smotkin, E. S.; Mallouk, T. E. Science (Washington, D.C.) 1998, 280, 1735- 1737.
35. Other approaches to the preparation of electrocatalysts: (a) Oetjen, H.-F.; Schmidt, V. M.; Stimming, U.; Trila, F. J. Electrochem. Soc. 1996, 143, 3838-3842. (b) Krausa, M.; Vielstich, W. J. Electroanal. Chem. 1994, 579, 307-314. (c) Schmidt, T. J.; Noeske, M.; Gasteiger, H. A.; Behm, R. J.; Britz, P.; Brijoux, W.; Bönnemann, H. Langmuir 1997, 13, 2591-2595. (d) Reddington, E.; Sapienza, A.; Guran, B.; Viswanathan, R.; Sarangapani, S.; Smotkin, E. S.; Mallouk, T. E. Science (Washington, D.C.) 1998, 280, 1735- 1737.
36. Other approaches to the preparation of electrocatalysts: (a) Oetjen, H.-F.; Schmidt, V. M.; Stimming, U.; Trila, F. J. Electrochem. Soc. 1996, 143, 3838-3842. (b) Krausa, M.; Vielstich, W. J. Electroanal. Chem. 1994, 579, 307-314. (c) Schmidt, T. J.; Noeske, M.; Gasteiger, H. A.; Behm, R. J.; Britz, P.; Brijoux, W.; Bönnemann, H. Langmuir 1997, 13, 2591-2595. (d) Reddington, E.; Sapienza, A.; Guran, B.; Viswanathan, R.; Sarangapani, S.; Smotkin, E. S.; Mallouk, T. E. Science (Washington, D.C.) 1998, 280, 1735-1737.