Palladium(II)-supported hydrotalcite as a catalyst for selective oxidation of alcohols using molecular oxygen

Chemical Communications

Volumn , Issue 14, 2000, Pages 1245-1246

  Nishimura, Takahiro ^a   Kakiuchi, Nobuyuki ^a   Inoue, Masashi ^a   Uemura, Sakae ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DERIVATIVE; ALDEHYDE; HYDROTALCITE; KETONE DERIVATIVE; METAL; OXYGEN; PALLADIUM; PYRIDINE;

ALCOHOL METABOLISM; ARTICLE; ATMOSPHERIC PRESSURE; CATALYST; CHEMICAL REACTION; ISOMERISM; OXIDATION;

EID: 0034698393     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b002447n     Document Type: Article

References (22)

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14. For recent examples of aerobic oxidation using heterogeneous palladium catalysts, see: M. Hronec, Z. Cvengrosová and J. Kizlink, J. Mol. Catal., 1993, 83, 75; K. Kaneda, M. Fujii and K. Morioka, J. Org. Chem., 1996, 61, 4502; G. Noronha and P. M. Henry, J. Mol. Catal. A, 1997, 120, 75; K. Kaneda, Y. Fujie and K. Ebitani, Tetrahedron Lett., 1997, 38, 9023; K. Ebitani, Y. Fujie and K. Kaneda, Langmuir, 1999, 15, 3557.
15. For recent examples of aerobic oxidation using heterogeneous palladium catalysts, see: M. Hronec, Z. Cvengrosová and J. Kizlink, J. Mol. Catal., 1993, 83, 75; K. Kaneda, M. Fujii and K. Morioka, J. Org. Chem., 1996, 61, 4502; G. Noronha and P. M. Henry, J. Mol. Catal. A, 1997, 120, 75; K. Kaneda, Y. Fujie and K. Ebitani, Tetrahedron Lett., 1997, 38, 9023; K. Ebitani, Y. Fujie and K. Kaneda, Langmuir, 1999, 15, 3557.
16. For recent examples of aerobic oxidation using heterogeneous palladium catalysts, see: M. Hronec, Z. Cvengrosová and J. Kizlink, J. Mol. Catal., 1993, 83, 75; K. Kaneda, M. Fujii and K. Morioka, J. Org. Chem., 1996, 61, 4502; G. Noronha and P. M. Henry, J. Mol. Catal. A, 1997, 120, 75; K. Kaneda, Y. Fujie and K. Ebitani, Tetrahedron Lett., 1997, 38, 9023; K. Ebitani, Y. Fujie and K. Kaneda, Langmuir, 1999, 15, 3557.
17. For recent examples of aerobic oxidation using heterogeneous palladium catalysts, see: M. Hronec, Z. Cvengrosová and J. Kizlink, J. Mol. Catal., 1993, 83, 75; K. Kaneda, M. Fujii and K. Morioka, J. Org. Chem., 1996, 61, 4502; G. Noronha and P. M. Henry, J. Mol. Catal. A, 1997, 120, 75; K. Kaneda, Y. Fujie and K. Ebitani, Tetrahedron Lett., 1997, 38, 9023; K. Ebitani, Y. Fujie and K. Kaneda, Langmuir, 1999, 15, 3557.
18. For recent examples of aerobic oxidation using heterogeneous palladium catalysts, see: M. Hronec, Z. Cvengrosová and J. Kizlink, J. Mol. Catal., 1993, 83, 75; K. Kaneda, M. Fujii and K. Morioka, J. Org. Chem., 1996, 61, 4502; G. Noronha and P. M. Henry, J. Mol. Catal. A, 1997, 120, 75; K. Kaneda, Y. Fujie and K. Ebitani, Tetrahedron Lett., 1997, 38, 9023; K. Ebitani, Y. Fujie and K. Kaneda, Langmuir, 1999, 15, 3557.
19. 2 with pyridine, see: S. V. Kravtsova, I. P. Romm, A. I. Stash and V. K. Belsky, Acta Crystallogr., Sect. C, 1996, 52, 2201; T. A. Stephenson, S. M. Morehouse, A. R. Powell, J. P. Heffer and G. Wilkinson, J. Chem. Soc., 1965, 3632.
20. 2 with pyridine, see: S. V. Kravtsova, I. P. Romm, A. I. Stash and V. K. Belsky, Acta Crystallogr., Sect. C, 1996, 52, 2201; T. A. Stephenson, S. M. Morehouse, A. R. Powell, J. P. Heffer and G. Wilkinson, J. Chem. Soc., 1965, 3632.
21. The presence of pyridine in Pd(II)-hydrotalcite was detected by TG/MS analysis, while desorption of pyridine was not observed from hydrotalcite which was treated with pyridine in toluene and washed by the same procedure as in the preparation of Pd(II)-hydrotalcite. We postulate that the Pd(II)-pyridine complex was adsorbed on the surface (not between layers) by ionic bonding between the Pd(II)-pyridine complex and hydroxy groups on the surface of the hydrotalcite.
22. Low catalytic activity of the MS-system might be due to strong complexation of palladium by the olefin. In Pd(II)-hydrotalcite, however, such complexation may be inhibited because of the steric bulk of hydrotalcite surface and this may be a reason for very low geometric isomerizations observed with the Pd(II)-hydrotalcite system.