Preparation and use of hybrid organic-inorganic catalysts

Catalysis Reviews - Science and Engineering

Volumn 44, Issue 2, 2002, Pages 321-374

  Valkenberg, Michael H ^a   Hölderich, Wolfgang F ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

Catalysts; Co condensation; Grafting; Immobilization; Support; Tethered metal complexes

Indexed keywords

EID: 0036577999     PISSN: 01614940     EISSN: None     Source Type: Journal    
DOI: 10.1081/CR-120003497     Document Type: Article

References (150)

1. The role of catalysis in the design. Development, and implementation of green chemistry
2. Oxidation reactions in the synthesis of fine and intermediate chemicals using environmentally benign oxidants and the right reactor system
3. Striving for catalytically green processes in the 21st century
4. Industrial application of solid acid-base catalysts
5. Environmentally friendly catalysts using supported reagents: Enhanced selectivity without loss in activity in the alkylation of benzene using hexagonal mesoporous silica (HMS)-supported aluminium chloride
6. The use of zeolites in the synthesis of fine and intermediate chemicals
7. Zeolite effect in the enantioselective transhydrogenation over a Co-Salen "Ship-in-the-Bottle" complex
8. Immobilised catalysts and their use in the synthesis of fine and intermediate chemicals
9. Catalysis by unique metal ion structures in solid matrices. From science to application
10. Environmentally friendly catalysis using supported reagents: Evolution of a highly active form of immobilised aluminium chloride
11. Preparation of supported catalysts
12. Preparation of catalyst supports, zeolites and mesoporous materials
13. Staging of organic and inorganic gallery cations in layered silicate heterostructures
14. From layer compounds to catalytic materials
15. Polymer-layered silicate nanocomposites: An overview
16. Novel zeolitic hosts for "Ship-in-a-Bottle" catalysts
17. Modification of faujasites to generate novel hosts for "Ship-in-a-Bottle" complexes
18. Liquid phase oxidation at metal ions and complexes in constrained environments
19. Propene polymerization with silica-supported metallocene/MAO catalysts
20. Heterogenization of metallocene catalysts for alkene polymerization
21. Alternative supported aqueous-phase catalyst systems
22. Polymer-supported reagents, catalysts, and sorbents: Evolution and exploitation-A personalized view
23. Catalyst preparation methods
24. From supported homogeneous catalysts to heterogeneous molecular catalysts
25. A new family of mesoporous molecular sieves prepared with liquid crystal templates
26. Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism
27. Possibilities of mesoporous materials in catalysis
28. Preparation and catalytic properties of new mesoporous materials
29. Micro- and meso-porous materials as catalysts
30. Access in mesoporous materials: Advantages of a uniform pore structure in the design of a heavy metal ion adsorbent for environmental remediation
31. A neutral templating route to mesoporous molecular sieves
32. Templating of mesoporous molecular sieves by nonionic polyethylene oxide surfactants
33. Non-ionic surfactant assembly of wormhole silica molecular sieves from water soluble silicates
34. Textural mesoporosity and the catalytic activity of mesoporous molecular sieves with wormhole framework structures
35. Site-directed surface derivatization of MCM-41: Use of high-resolution transmission electron microscopy and molecular recognition for determining the position of functionality within mesoporous materials
36. Modified mesoporous silicate MCM-41 materials: Immobilised perruthenate - A new highly active heterogeneous oxidation catalyst for clean organic synthesis using molecular oxygen
37. Superior performance of a chiral catalyst confined within mesoporous silica
38. Designing new inorganic catalysts
39. Recent advances in the partial oxidation of organic molecules using heterogeneous catalysis
40. Transition-metal ligands bound onto the micelle- templated silica surface
41. Surface-modified silica gels as solid stationary phases in gas chromatography
42. Supported transition metal complexes II. Silica as the support
43. Selective reduction of alkynes to Z-alkenes using hydrosilane functions immobilized on silica gel
44. MCM-41 type silicas as supports for immobilized catalysts
45. 13C MAS-NMR characterization of surface modification of micelle-templated silicas during the grafting of organic moieties and end-capping
46. Grafting of alkoxysilane coupling agents on the hydrophobic portion of the surface of micelle-templated silica
47. Reactions of ethoxysilanes with silica: A solid-state NMR study
48. Reaction of alkoxysilane coupling agents with dehydroxylated silica surfaces
49. Preferential grafting of alkoxysilane coupling agents on the hydrophobic portion of micelle-templated silica
50. Immobilisation of chloroaluminate ionic liquids on silica materials
51. Functional surface groups for single-site heterogeneous α-olefin polymerization catalysts
52. 3 on a cyclopentadienyl surface of silica
53. Aminosilane as a coupling agent for cyclopentadienyl ligands on silica
54. Sulfonic acid funtionalised ordered mesoporous materials as catalysts for condensation and esterification reactions
55. Best design of heterogenized β-aminoalcohols for improvement of enantioselective addition of diethylzinc to benzaldehyde
56. Amine functions linked to MCM-41 type silicas as a new class of solid base catalysts for condensation reactions
57. Functionalized monolayers on ordered mesoporous supports
58. The Danishefsky Hetero Diels-Alder reaction mediated by organolanthanide-modified mesoporous silicate MCM-41
59. Synthesis of a hybrid inorganic-organic mesoporous silica by co-condensation of siloxane and organosiloxane precursors
60. Direct preparation of organically modified MCM-type materials. Preparation and characterisation of aminopropyl-MCM and 2-cyanoethyl-MCM
61. Organically modified hexagonal mesoporous silicas
62. Template-directed synthesis of bifunctionalized organo-MCM-41 and phenyl-MCM-48 mesophases
63. Synthesis and characterization of ordered organo-silica-surfactant mesophases with functionalized MCM-41-type architecture
64. Organomodified hexagonal mesoporous silicates
65. Molecular imprinting of bulk, microporous silica
66. Supported organometallic complexes. Part XIII. Catalytic studies on sol-gel processed (Ether Phosphine)ruthenium(II) complexes with different spacer lengths and different polysiloxane matrices
67. Immobilised ionic liquids as Lewis acid catalysts for the alkylation of aromatic compounds with dodecene
68. Heterogeneous catalysts for liquid-phase oxidations: Philosopher's stones or trojan horses
69. Preparation of MCM-41 type silica-bound manganese(III) Schiff-base complexes
70. Functionalized micelle-templated silica and their use as catalysts for fine chemicals
71. A novel MCM-41 supported manganese(III) complex with nitrogen donor ligand for cyclohexene oxidation
72. Asymmetric epoxidation of alkenes catalysed by chromium binaphthyl schiff base complex supported on MCM-41
73. Catalytic oxidation of alkyl aromatics using a novel silica supported Schiff base complex
74. Liquid phase oxidations using novel surface functionalised silica supported metal catalysts
75. Room temperature Baeyer-Villiger oxidation of cyclic and linear ketones using molecular oxygen, catalysed by a novel silica-supported nickel complex
76. A novel immobilised cobalt(III) oxidation catalyst
77. Environmentally friendly catalysis using supported reagents: Catalytic epoxidation using a chemically modified silica gel
78. Alkene epoxidation by iodosylbenzene catalysed by iron(III) 5,10,15,20-tetra-(2,6-dichlorophenyl)porphyrin coordinated to pyrdine-modified silica
79. Alkene epoxidation catalysed by iron(III) and manganese(III) tetraarylporphyrins coordinatively bound to polymer and silica supports
80. Ruthenium porphyrin encapsulated in modified mesoporous molecular sieve MCM-41 for alkene oxidation
81. Manganese porphyrins covalently bound to silica and montmorillonite K10 as efficient catalysts for alkene and alkane oxidation by hydrogen peroxide
82. Metallophthalocyanine functionalized silicas: Catalysts for the selective oxidation of aromatic compounds
83. MCM-41 type molecular sieves as carriers for metal-phthalocyanine complexes
84. Synthesis and characterisation of cobalt phthalocyanines covalently attached to silica
85. Heterogeneous oxidation of aromaticcompounds catalyzed by metallophthalocyanine functionalized silicas
86. 2 by sol-gel processing. Part 1: Preparation and microstructure
87. 2 by sol-gel processing Part 2. Activity in sulfide and ethanediol oxidation
88. Practical heterogenisation of an active manganese triazacyclononane epoxidation catalyst via surface glycidylation
89. 2 and manganese complexes of the cyclic triamine 1,4,7-trimethyl-1,4,7-triazacyclononane
90. 2 und einem heterogenisierten Mn-katalysator: Epoxidierung und ein neuer zugang zu vicinalen cis-diolen
91. 2
92. New chiral hybrid organic-inorganic mesoporous materials for enantioselective epoxidation
93. Functionalizition of silica gel and montmorillonite by silane coupling reagent. IV. Application as immobilized catalysts in dioxygen oxidation of organic compounds
94. Ein Co(III)-MCM-41-heterogenkatalysator für die selektive niedertemperatur-oxidation von cyclohexan zu cyclohexanon
95. Preparation of silica-supported peroxycarboxylic acid and its use in the epoxidation of alkenes
96. The Baeyer-Villiger oxidation of ketones using HMS supported peroxycarboxylic acids
97. Surface organometallic chemistry on zeolites: A tool for modifying the sorption properties of zeolites
98. Mikroporöse mischoxide-katalysatoren mit einstellbarer oberflächenpolarität
99. 2 catalyzed by titanium-containing mesoporous molecular sieves
100. Strategies to improve the epoxidation activity and selectivity of Ti-MCM-41
101. Hydration of cyclohexene by alkyl-immobilized H-ZSM-5 catalyst in decalin-water system
102. The first stereospecific catalytic hydrogenation with a polymer supported optically active rhodium complex
103. Reduction of nitroaromatics with a new heterogenised MCM-silylamine palladium (II) catalyst
104. MCM-silylamine Pd(II) complex: A heterogeneous catalyst for selective azide reductions
105. 3Cl on phosphinated MCM-41 for catalytic hydrogenation of olefins
106. Synthesis, immobilization and catalytic activity of some silylated cyclopentadienyl rhodium(I) complexes
107. The synthesis of new chiral salen complexes immobilized on MCM-41 by grafting and their catalytic activity in the asymmetric borohydride reduction of ketones
108. Immobilized catalysts for enantioselective hydrogenation: The effect of site isolation
109. Immobilization of carbonylnickel complexes: A solid-state NMR study
110. A one-step, enantioselective reduction of ethyl nicotinate to ethyl nipecotinate using a constrained, chiral, heterogeneous catalyst
111. Poly(N-isopropylacrylamide)-grafted silica as a support of platinum colloids: Preparation method. Characterization, and catalytic properties in hydrogenation
112. Hydrodefluorination of fluorobenzene and 1,2-difluorobenzene under mild conditions over rhodium pyridylphosphine and bipyridyl complexes tethered on a silica-supported palladium catalyst
113. Rhodium and platinum isocyanide complexes tethered on silica-supported metal heterogeneous catalysts: Arene and cyclohexanone hydrogenation
114. Combined homogeneous and heterogeneous catalysts. Rhodium carbonyl thiolate complexes tethered on silica-supported metal heterogeneous catalysts: Olefin hydroformylation and arene hydrogenation
115. Catalysis of the Knoevenagel reaction by - Aminopropylsilica
116. Silica gel functionalized with amino groups as a new catalyst for Knoevenagel condensation under heterogeneous catalysis conditions
117. Amino groups immobilized on silica gel: An efficient and reusable heterogeneous catalyst for the Knoevenagel condensation
118. Aminopropylated MCMs as base catalyst: A comparison with aminopropylated silica
119. Synthesis and characterization of a reactive vinyl-functionalized MCM-41: Probing the internal pore structure by a bromination reaction
120. 1,5,7-Triazabicyclo[4.4.0]dec-5-ene immobilized in MCM-41: A strongly basic porous catalyst
121. Functionalisation of silica and its use as a catalyst: Application of the modified silica for several nucleophilic reactions
122. Guanidines encapsulated in zeolite Y and anchored to MCM-41: Synthesis and catalytic activity
123. Catalysis of the Michael reaction
124. Supported phenolates as efficient catalysts of the Michael reaction
125. Michael additions catalysed by N, N-dimethyl-3-aminopropyl-derivatised amorphous silica and hexagonal mesoporous silica (HMS)
126. Supported BINOLate salts as base catalysts. Preparation and use in the Michael reaction
127. Monoglyceride synthesis by heterogeneous catalysis using MCM-41 type silicas functionalized with amino groups
128. Novel Lewis-acid catalysts by immobilisation of ionic liquids
129. Ionic liquids for clean technology
130. Chiral mesoporous templated silicas as heterogeneous inorganic-organic catalysts in the enantioselective alkylation of benzaldehyde
131. Factors affecting the efficiency of hybrid chiral mesoporous silicas used as heterogeneous inorganic. Organic catalysts in the enantioselective alkylation of benzaldehyde
132. Heterogeneous enantioselective carbon-carbon bond formation: Role of the inorganic support in the synthesis and activity of supported chiral auxiliaries
133. New chiral heterogeneous catalysts based on mesoporous silica: Asymmetric diethylzinc addition to benzaldehyde
134. Organic-functionalized molecular sieves as shape-selective catalysts
135. Hydrosilylation of alkenes catalysed by rhodium complexes on silica via a pyridine group
136. A robust, environmentally benign catalysts for highly selective hydroformylation
137. Supported organometallic complexes. Part XX. Hydrofomylation of olefins with rhodium(I) hybrid catalysts
138. Virtually no environmental impact: The biphasic oxo process
139. Recent developments of 2-phase catalysis at Hoechst
140. Progress in hydroformylation and carbonylation
141. Amine synthesis via carbonylation reactions: Aminomethylation
142. Polymerization reaction engineering-metallocene catalysts
143. Heterogeneous constrained-geometry zirconium catalysts
144. 1 anchor: Catalysts for isospecific propene polymerization
145. Polymerization of ethylene by using zirconocene catalyst anchored on silica with trisiloxane and pentamethylene spacers
146. Preferential grafting of alkoxysilane coupling agents on the hydrophobic portion of micelle-templated silica