Molecular imprinting of bulk, microporous silica

Nature

Volumn 403, Issue 6767, 2000, Pages 286-289

  Katz, Alexander ^a,b   Davis, Mark E ^a  

^a California Institute of Technology   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

POLYMER; SILICON DIOXIDE;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; COVALENT BOND; MOLECULAR INTERACTION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; POROSITY; PRIORITY JOURNAL; SYNTHESIS; X RAY POWDER DIFFRACTION;

EID: 0034688221     PISSN: 00280836     EISSN: None     Source Type: Journal    
DOI: 10.1038/35002032     Document Type: Article

References (18)

1. Whitcombe, M. J., Rodriguez, M. E., Villar, P. & Vulfson, E. A new method for the introduction of recognition site functionality into polymers prepared by molecular imprinting - Synthesis and characterization of polymer receptors for cholesterol. J. Am. Chem. Soc. 117, 7105-7111 (1995).
2. Vlatakis, G., Anderson, L. I., Müller, R. & Mosbach, K. Drug assay using antibody mimics made by molecular imprinting. Nature 361, 645-547 (1993).
3. Wulff, G. Molecular imprinting in cross-linked materials with the aid of molecular templates - a way towards artificial antibodies. Angew. Chem. Int. Edn Engl. 34, 1812-1832 (1995).
4. Davis, M. E., Katz, A. & Ahmad, W. R. Rational catalyst design via imprinted nanostructured materials. Chem. Mater. 8, 1820-1839 (1996).
5. Shea, K. J. Molecular imprinting of synthetic network polymers: the de novo synthesis of macromolecular binding and catalytic sites. Trends Polym. Sci 2, 166-173(1994).
6. D'Souza, S. M. et al. Directed nucleation of calcite at a crystal-imprinted polymer surface. Nature 398, 312-316 (1999).
7. Shi, H., Tsai, W., Garrison, M. D., Ferrari, S. & Ratner, B. D. Template-imprinted nanostructured surfaces for protein recognition. Nature 398, 593-597 (1999).
8. Wulff, G., Heide, B. & Helfmeier, G. Molecular recognition through the exact placement of functional groups on rigid matrices via a template approach. J. Am. Chem. Soc. 108, 1089-1091 (1986).
9. Dai, S. et al. Imprint coating: A novel synthesis of selective functionalized ordered mesoporous sorbents. Angew. Chem. Int. Edn Engl. 38, 1235-1239 (1999).
10. Heilmann, J. & Maier, W. F. Selective catalysis on silicon dioxide with substrate-specific cavities. Angew. Chem. Int. Edn Engl. 33, 471-473 (1994).
11. Ahmad, W. R. & Davis, M. E. Transesterification on "imprinted" silica. Catal. Lett. 40, 109-114 (1996).
12. Maier, W. F. & Ben Mustapha, W. Transesterification on "imprinted" silica - Reply. Catal. Lett. 46, 137-140 (1997).
13. Katz, A. & Davis, M. E. Investigations into the mechanisms of molecular recognition with imprinted polymers. Macromolecules 32, 4113-4121 (1999).
14. Jones, C. W., Tsuji, K. & Davis, M. E. Organic-functionalized molecular sieves as shape-selective catalysts. Nature 393, 52-54 (1998).
15. Brinker, C. J., Keefer, K. D., Schaefer, D. W. & Ashley, C. S. Sol-gel transition in simple silicates. J. Non-Cryst. Solids 48, 47-64 (1982).
16. Fuji, K. at al. Visualization of molecular length of α,ω-diamines and temperature by a receptor based on phenolphthalein and crown ether. J. Am. Chem. Soc. 121, 3807-3808 (1999).
17. Dunn, D. & Zink, J. I. Probes of pore environment and molecule-matrix interaction in sol-gel materials. Chem. Mater. 4, 2280-2291 (1997).
18. Houk, J. & Whitesides, G. M. Structure reactivity relations for thiol disulfide interchange. J. Am. Chem. Soc. 109, 6825-6836 (1987).