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Volumn 31, Issue 8, 1998, Pages 485-493

Heterogeneous Catalysts for Liquid-Phase Oxidations: Philosophers' Stones or Trojan Horses?

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EID: 0000656358     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar9700163     Document Type: Article
Times cited : (924)

References (92)
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    • Shell Oil (Wulff, H. P.), GB Patent 1,249,079, 1971.
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    • Halcon (Kollar, J.), U.S. Patents 3,350,422 and 3,351,635, 1967.
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    • ARCO (Sheng, M. N.; Zajacek, J. G.), GB Patent 1,136,923, 1968.
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    • Cornils, B., Herrmann, W., Eds.; VCH: Weinheim
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    • (1996) Applied Homogeneous Catalysis , vol.1 , pp. 411-423
    • Sheldon, R.A.1
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    • U.S. Patent 4,410,501, 1983, to Snamprogetti
    • Taramasso, M.; Perego, G.; Notari, B. U.S. Patent 4,410,501, 1983, to Snamprogetti. Taramasso, M.; Manara, G.; Fattore, V.; Notari, B. U.S. Patent 4,666,692, 1987, to Snamprogetti.
    • Taramasso, M.1    Perego, G.2    Notari, B.3
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    • U.S. Patent 4,666,692, 1987, to Snamprogetti
    • Taramasso, M.; Perego, G.; Notari, B. U.S. Patent 4,410,501, 1983, to Snamprogetti. Taramasso, M.; Manara, G.; Fattore, V.; Notari, B. U.S. Patent 4,666,692, 1987, to Snamprogetti.
    • Taramasso, M.1    Manara, G.2    Fattore, V.3    Notari, B.4
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    • note
    • Ti = 35). For a highly ordered silicalite, a HI of 45 was reported.
  • 22
  • 24
    • 85033915060 scopus 로고    scopus 로고
    • A redox metal is defined as a metal that catalyzes an oxidation (oxidative transformation)
    • A redox metal is defined as a metal that catalyzes an oxidation (oxidative transformation).
  • 40
    • 85033930114 scopus 로고    scopus 로고
    • note
    • The kinetic diameter can be defined as the diameter of the smallest window of circular shape through which the molecule can move; we thank Dr. K. S. Smirnov for this definition.
  • 66
    • 0000858607 scopus 로고    scopus 로고
    • However, for exceptions see: (a) Abbenhuis, H. C. L.; Krijnen, S.; van Santen, R. A. J. Chem. Soc., Chem. Commun. 1997, 331-332. (b) Di Furia, F.; Licini, G.; Modena, G.; Motterle, R.; Nugent, W. A. J. Org. Chem. 1996, 61, 5175-5177.
    • (1996) J. Org. Chem. , vol.61 , pp. 5175-5177
    • Di Furia, F.1    Licini, G.2    Modena, G.3    Motterle, R.4    Nugent, W.A.5
  • 82
    • 85033935240 scopus 로고    scopus 로고
    • note
    • In TS-1 and Ti-beta, titanium is isomorphously substituted and coordinated by four O-Si bridges in the as-synthesized materials. However, in the presence of water, one Ti-O-Si bond could easily be hydrolyzed which results in three Si-O links. Furthermore, in a sieve like MCM-41, titanium is more likely to possess only three silanoxy links in the as-synthesized material.


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