Selective alkene oxidation with H2O2 and a heterogenized Mn catalyst: Epoxidation and a new entry to vicinal cis-diols

Angewandte Chemie - International Edition

Volumn 38, Issue 7, 1999, Pages 980-983

  De Vos, Dirk E ^a   De Wildeman, Stefaan ^a   Sels, Bert F ^a   Grobet, Piet J ^a   Jacobs, Pierre A ^a  

^a UNIVERSITY OF LEUVEN   (Belgium)

Author keywords

Dihydroxylations epoxidations; Heterogeneous catalysis; Immobilization; Manganese

Indexed keywords

ALKENE; HYDROGEN PEROXIDE;

ARTICLE; CATALYST; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL STRUCTURE; EPOXIDATION; OXIDATION; REACTION ANALYSIS; STOICHIOMETRY; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0033119499     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990401)38:7<980::AID-ANIE980>3.0.CO;2-W     Document Type: Article

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42. As suggested by a referee, this hypothesis can be tested by addition of oxalate to the heterogenized Mn catalyst. This completely stops the dihydroxylation, while some epoxidation still goes on.