Ionic liquids for clean technology

Journal of Chemical Technology and Biotechnology

Volumn 68, Issue 4, 1997, Pages 351-356

  Seddon, Kenneth R ^a  

^a QUEEN'S UNIVERSITY BELFAST   (United Kingdom)

Author keywords

Chloroaluminates(III); Clean synthesis; Clean technology; Ionic liquids; Molten salts; Neoteric solvents

Indexed keywords

CATALYSIS; ENVIRONMENTAL ENGINEERING; MOLTEN MATERIALS; SALTS; SOLVENTS; SYNTHESIS (CHEMICAL);

CHLOROALUMINATE IONIC LIQUIDS; CLEAN SYNTHESIS; CLEAN TECHNOLOGY; NEOTERIC SOLVENTS;

CHLORINE COMPOUNDS;

SOLVENT;

CATALYSIS; CONFERENCE PAPER; ENVIRONMENTAL TEMPERATURE; TECHNOLOGY;

EID: 0031127122     PISSN: 02682575     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1097-4660(199704)68:4<351::AID-JCTB613>3.0.CO;2-4     Document Type: Conference Paper

References (28)

1. Hussey, C. L., Room temperature molten salt systems. Adv. Molten Salt Chem., 5 (1983) 185-230.
2. Hussey, C. L., Room-temperature haloaluminate ionic liquids - novel solvents for transition-metal solution chemistry. Pure Appl. Chem., 60 (1988) 1763-72.
3. Chauvin, Y. & Olivier-Bourbigou, H., Nonaqueous ionic liquids as reaction solvents. CHEMTECH, 25(9) (1995) 26-30.
4. Chauvin, Y., Mussmann, L. & Olivier, H., A novel class of versatile solvents for 2-phase catalysis - hydrogenation, isomerization, and hydroformylation of alkenes catalyzed by rhodium complexes in liquid 1,3-dialkylimidazolium salts. Angew. Chem. Int. Edit. Engl., 34 (1996) 2698-700.
5. Wilkes, J. S. & Zaworotko, M. J., Air and water stable 1-ethyl-3-methylimidazolium based ionic liquids. J. Chem. Soc., Chem. Commun., (1992) 965-7.
6. Poliakoff, M. & Howdle, S., Supercritical chemistry -synthesis with a scanner. Chem. Brit., 31 (1995) 118-21.
7. Poliakoff, M., Howdle, S. M. & Kazarian, S. G., Vibrational spectroscopy in supercritical fluids - from analysis and hydrogen-bonding to polymers and synthesis. Angew. Chem. Int. Edit. Engl., 34 (1995) 1275-95.
8. Seddon, K. R., Room-temperature ionic liquids: neoteric solvents for clean catalysis. Kinet. Katal., (1997) (in press).
9. http://www.ch.qub.ac.uk/resources/ionic/review/review.html.
10. http://www.ch.qub.ac.uk/resources/ionic/ionic.html.
11. Hussey, C. L., Barnard, P. A., Sun, I. W., Appleby, D., Hitchcock, P. B., Seddon, K. R., Welton, T. & Zora, J. A., An electrochemical study of the ruthenium(III) and ruthenium(IV) hexachlorometallates in a basic room-temperature chloroaluminate molten salt. J. Electrochem. Soc., 138 (1991) 2590-4.
12. Lide, D. R. (ed.) CRC Handbook of Chemistry and Physics, 73rd edn. CRC Press, Boca Raton, 1992.
13. Kapustinskii, A. F., Lattice energy of ionic crystals. Quart. Rev., 10 (1956) 283-94.
14. Robinson, J. & Osteryoung, R. A., An electrochemical and spectroscopic study of some aromatic hydrocarbons in the room temperature molten salt system aluminum chloride-n-butylpyridinium chloride. J. Am. Chem. Soc., 101 (1979) 323-27.
15. Wilkes, J. S., Levisky, J. A., Wilson, R. A. & Hussey, C. L., Dialkylimidazolium chloroaluminate melts - a new class of room-temperature ionic liquids for electrochemistry, spectroscopy and synthesis. Inorg. Chem., 21 (1982) 1263-4.
16. Sanders, J. R., Ward, E. H. & Hussey, C. L., Aluminum bromide-1-methyl-3-ethylimidazolium bromide ionic liquids. 1. Densities, viscosities, electrical conductivities, and phase-transitions. J. Electrochem. Soc., 133 (1986) 325-30.
17. Fannin, A. A., Floreani, D. A., King, L. A., Landers, J. S., Piersma, B. J., Stech, D. J., Vaughn, R. L., Wilkes, J. S. & Williams, J. L., Properties of 1,3-dialkylimidazolium chloride aluminum chloride ionic liquids. 2. Phase-transitions, densities, electrical conductivities, and viscosities. J. Phys. Chem., 88 (1984) 2614-21.
18. Abdul-Sada, A. K., Greenway, A. M., Hitchcock, P. B., Mohammed, T. J., Seddon, K. R. & Zora, J. A., Upon the structure of room-temperature halogenoaluminate ionic liquids. J. Chem. Soc., Chem. Commun., (1986) 1753-4.
19. Hussey, C. L., Scheffler, T. B., Wilkes, J. S. & Fannin, A. A., Chloroaluminate equilibria in the aluminum chloride-1-methyl-3-ethylimidazolium chloride ionic liquid. J. Electrochem. Soc., 133 (1986) 1389-91.
20. - in room-temperature chloroaluminate ionic liquids. Org. Mass Spectrom., 24 (1989) 917-18.
21. Abdul-Sada, A. K., Greenway, A. M., Seddon, K. R. & Welton, T., A fast-atom-bombardment mass-spectrometric study of room-temperature 1-ethyl-3-methylimidazolium chloroaluminate(III) ionic liquids - evidence for the existence of the decachlorotrialuminate(III) anion. Org. Mass Spectrom., 28 (1993) 759-65.
22. Sheldon, R. A., The role of catalysis in waste minimization. In Precision Process Technology: Perspectives for Pollution Prevention, eds M. P. C. Weijnen & A. A. H. Drinkenburg. Kluwer, Dordrecht, 1993, p. 125-38.
23. 3-1-ethyl-3-methyl-1H-imidazolium chloride. J. Am. Chem. Soc., 111 (1989) 525-30.
24. 3). J. Am. Chem. Soc., 111 (1989) 5075-7.
25. Abdul-Sada, A. K., Atkins, M. P., Ellis, B., Hodgson, P. K. G., Morgan, M. L. M. & Seddon, K. R., World Patent, WO 95/21806, 1995.
26. Abdul-Sada, A. K., Ambler, P. W., Hodgson, P. K. G., Seddon, K. R. & Stewart, N. J., World Patent, WO 95/ 21871, 1995.
27. Weissermel, K. & Arpe, H.-J., Industrial Organic Chemistry, 2nd revised edn. VCH, Weinheim, 1993.
28. Bowlas, C. J., Bruce, D. W. & Seddon, K. R., Liquid-crystalline ionic liquids. J. Chem. Soc., Chem. Commun., (1996) 1625-26.