Consideration of reaction mechanisms leading to pyrolytic carbon of different textures

Carbon

Volumn 40, Issue 14, 2002, Pages 2515-2528

  Dong, G L ^a   Huttinger K J ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

Author keywords

A. Pyrolytic carbon; B. Chemical vapor deposition; C. Chromatography; D. Texture; Modeling

Indexed keywords

AROMATIC HYDROCARBONS; CHEMICAL VAPOR DEPOSITION; CHROMATOGRAPHY; GROWTH (MATERIALS); NUCLEATION; REACTION KINETICS; TEXTURES;

PYROLYTIC CARBON;

CARBON;

EID: 0036384870     PISSN: 00086223     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0008-6223(02)00174-4     Document Type: Article

References (61)

1. Bourrat X. Structure in carbon and carbon artefacts Marsh H., Rodriguez-Reinoso F., Sciences of carbon materials 1999 1-37 Secretariadó de Publicaciones Universidad de Alicante, Spain.
2. Oberlin A. Pyrocarbons Carbon 40: 1 2002 7-24.
3. Reznik B., Hüttinger K.J. On the terminology for pyrolytic carbon Carbon 40: 4 2002 621-624.
4. Hu Z.J., Hüttinger K.J. Mechanisms of carbon deposition - a kinetic approach Carbon 40: 4 2002 625-628.
5. Bourrat X., Lavenac J., Langlais F., Naslain R. The role of pentagons in the growth of laminar pyrocarbon Carbon 39: 15 2001 2369-2386.
6. Becker A., Hüttinger K.J. Chemistry and kinetics of chemical vapor deposition of pyrocarbon - II. Pyrocarbon deposition from ethylene, acetylene and 1,3 butadiene in the low temperature regime Carbon 36: 3 1998 177-199.
7. Becker A., Hüttinger K.J. Chemistry and kinetics of chemical vapor deposition of pyrocarbon - III. Pyrocarbon deposition from propylene and benzene in the low temperature regime Carbon 36: 3 1998 201-211.
8. Becker A., Hüttinger K.J. Chemistry and kinetics of chemical vapor deposition of pyrocarbon - IV. Pyrocarbon deposition from methane in the low temperature regime Carbon 36: 3 1998 213-224.
9. Hüttinger KJ. Fundamentals of chemical vapor deposition of carbon, In: Delhaes P, editor. World of carbon, vol. 2, Fibers and composites. London: Taylor and Francis, in press.
10. Feron O., Langlais F., Naslain R., Thébault J. On kinetic and microstructural transitions in the CVD of pyrocarbon from propane Carbon 37: 9 1999 1343-1353.
11. Hu Z.J., Hüttinger K.J. Chemistry and kinetics of chemical vapor deposition of pyrocarbon - VIII. Carbon deposition from methane at low pressures Carbon 39: 3 2001 433-441.
12. 2; rate constant for the homogeneous unimolecular dissociation of methane and its pressure dependence Can J Chem 53: 23 1975 3580-3590.
13. Chen C.J., Back M.H., Back R.A. The thermal decomposition of methane. II. Secondary reactions, autocatalysis and carbon formation: non-Arrhenius behavior of the reaction of methyl radical with ethane Can J Chem 54: 20 1976 3175-3184.
14. Dean A.M. Detailed kinetic modelling of autocatalysis in methane pyrolysis J Phys Chem 94: 4 1990 1432-1439.
15. Westmoreland P.R., Dean A.M., Howard J.B., Longwell J.P. Forming benzene in flames by chemically activated isomerization J Phys Chem 93: 1989 8171-8180.
16. Frenklach M., Wang H. Modelling of soot particle formation Bockhorn H., Soot formation in combustion 1994 165-192 Springer Berlin.
17. Miller J.A., Kee R.J., Westbrook C.K. Chemical kinetics and combustion modelling Annu Rev Phys Chem 41: 1990 345-387.
18. Stein S.E., Walker J.A., Suryan M.M., Fahr A. A new path to benzene in flames Twenty-third International Symposium on Combustion 1991 85 The Combustion Institute.
19. Miller J.A., Melius C.F. Kinetic and thermodynamic issues in the formation of aromatic compounds in flames of aliphatic fuels Combust Flame 91: 1992 21-39.
20. Atakan B., Hartlieb A.T., Brand J., Kohse-Höinghaus K. An experimental investigation of premixed fuel-rich low-pressure propene/oxygen/argon flames by laser spectroscopy and molecular-beam mass spectrometry Twenty-seventh International Symposium on Combustion 1998 435-444 The Combustion Institute Pittsburgh.
21. Wang H., Frenklach M. A detailed kinetic modeling study of aromatics formation in laminar premixed acetylene and ethylene flames Combust Flame 110: 1/2 1997 173-221.
22. Böhm H., Jander H., Tanke D. PAH growth and soot formation in the pyrolysis of acetylene and benzene at high temperatures and pressures: Modeling and Experiment Twenty-seventh International Symposium on Combustion 1998 1605-1612 The Combustion Institute Pittsburgh.
23. Marinov N.M., Pitz W.J., Westbrook C.K., Castaldi M.J., Senkon S.M. Modeling of aromatic and polycyclic aromatic hydrocarbon formation in premixed methane and ethane flames Combust Sci Technol 116/117: 1996 211-287.
24. Colket M.B., Seery D.J. Reaction mechanisms for toluene pyrolysis Twenty-fifth International Symposium on Combustion 1994 883-891 The Combustion Institute Pittsburgh.
25. Manion J.A., Louw R. Rates, products and mechanisms in the gas-phase hydrogenolysis of phenol between 922 and 1175 K J Phys Chem 93: 1989 3563-3573.
26. Bockhorn H., Soot formation in combustion: mechanisms and models 1994 Springer Berlin.
27. Frenklach M., Clary D., Gardiner W.C., Stein S.E. Detailed kinetic modeling of soot formation in shock-tube pyrolysis of acetylene Twentieth International Symposium on Combustion 1984 887-901 The Combustion Institute Pittsburgh.
28. McKinnon J.T., Howard J.B. The role PAH and acetylene in soot nucleation and growth Twenty-fourth International Symposium on Combustion 1992 965-971 The Combustion Institute Pittsburgh.
29. Badger G.M. Pyrolysis of hydrocarbons Prog Phys Org Chem 3: 1 1965 1-40.
30. Badger G.M., Donnelly J.K., Spotswook T.M. The formation of aromatic hydrocarbons at high temperatures XXIII. The pyrolysis of anthracene Aust J Chem 17: 1964 1147-1156.
31. Sarofim A.F., Longwell J.P., Wornat M.J., Mukherjee J. The role of biaryl reactions in PAH and soot formation Bockhorn H., Soot formation in combustion 1994 485-500 Springer Berlin.
32. Siegmann K., Hepp H., Sattler K. Reactive dimerization: a new PAH growth mechanism Combust Sci Technol 109: 1995 165-181.
33. Griesheimer J., Homann K.-H. Large molecules, radicals, ions, and small soot particles in fuel-rich hydrocarbon flames. Part II. Aromatic radicals and intermediate PAHs in a premixed low-pressure naphthalene/oxygen/argon flame Twenty-seventh International Symposium on Combustion 1998 1753-1759 The Combustion Institute Pittsburgh.
34. Fitzer E., Müller K., Schäfer W. The chemistry of the pyrolytic conversion of organic compounds to carbon Walker P.L. Jr., Chemistry and physics of carbon vol. 7: 1971 237-384 Marcel Dekker New York.
35. Cioslowski J., Piskorz P., Moncrieff D. Thermally induced cyclodehydrogenation of biaryls: a simple radical reaction or a sequence of rearrangements? J Org Chem 63: 1998 4051-4054.
36. Cioslowski J., Liu G., Martinov M., Piskorz P., Moncrieff D. Energetics and site specificity of the homolytic C-H bond cleavage in benzenoid hydrocarbons: an ab initio electronic structure study J Am Chem Soc 118: 1996 5261-5264.
37. 3 bond energies at borders of polycyclic aromatic hydrocarbons Phys Chem Chem Phys 22: 2 2000 5084-5088.
38. Böhm H., Jander H. PAH formation in acetylene-benzene pyrolysis Phys Chem Chem Phys 1: 1999 3775-3781.
39. Homann K.-H. Fullerenes and soot formation - New pathways to large particles in flames Angew Chem Int Ed Engl 37: 18 1998 2435-2451.
40. Stein S.E. Thermochemical kinetics of anthracene pyrolysis Carbon 19: 6 1981 421-429.
41. Stein S.E., Griffith L.L., Billmers R., Chen R.H. Pyrocondensation of anthracene J Org Chem 52: 8 1987 1582-1591.
42. Madison J.J., Roberts R.M. Pyrolysis of aromatics and related heterocyclics Ind Eng Chem 50: 1958 237-250.
43. Frenklach M., Moriarty N.W., Brown N.J. Hydrogen migration in polyaromatic growth Twenty-seventh International Symposium on Combustion 1998 1655-1661 The Combustion Institute Pittsburgh.
44. Necula A. Automerization and skeleton rearrangements of polycyclic aromatic hydrocarbons. Ph.D. Thesis, Boston College, 1996.
45. Wornat M.J., Sarofim A.F., Lafleur A.L. The pyrolysis of anthracene as a model coal-derived aromatic compound Twenty-fourth International Symposium on Combustion 1992 955-963 The Combustion Institute.
46. Keller A., Kovacs R., Homann K.-H. Large molecules, ions, radicals and small soot particles in fuel-rich hydrocarbon flames. Part IV. Large polycyclic aromatic hydrocarbons and their radicals in a fuel-rich benzene-oxygen flame Phys Chem Chem Phys 2: 8 2000 1667-1675.
47. Gräber W-D. Kinetik und Chemie der Methanbildung bei der hydrierenden Vergasung von Modellaromaten. Ph.D. Thesis. Universität Karlsruhe, 1982.
48. Weilmünster P., Keller A., Homann K.-H. Large molecules, radicals, ions, and small soot particles in fuel-rich hydrocarbon flames. Part I: Positive ions of polycyclic aromatic hydrocarbons (PAH) in low-pressure premixed flames of acetylene and oxygen Combust Flame 116: 1/2 1999 62-83.
49. Fialkov A.B., Dennebaum J., Homann K.-H. Large molecules, ions, radicals, and small soot particles in fuel-rich hydrocarbon flames. Part V: Positive ions of polycyclic aromatic hydrocarbons (PAH) in low-pressure premixed flames of benzene and oxygen Combust Flame 125: 1/2 2001 763-777.
50. Kazakov A., Frenklach M. On the relative contribution of acetylene and aromatics to soot particle surface growth Combust Flame 112: 1998 270-274.
51. Glasier G.F., Filfil R., Pacey P.D. Formation of polycyclic aromatic hydrocarbons coincident with pyrolytic carbon deposition Carbon 39: 2001 497-506.
52. Feron O., Langlais F., Naslain R. Analysis of the gas phase by in situ FTIR spectrometry and mass spectrometry during the CVD of pyrocarbon from propane Adv Mater CVD 5: 1 1999 37-47.
53. Blekkan E.A., Myrstad R., Olsvik O., Rokstad O.A. Characterization of tars and coke formed during the pyrolysis of methane in a tubular reactor Carbon 30: 4 1992 665-673.
54. Zhang WG, Hu ZJ, Hüttinger KJ. CVI of carbon fiber felt: optimization of densification and carbon microstructure, Carbon, in press.
55. Hu ZJ, Reznik B, Zhang WG, Gerthsen D, Hüttinger KJ. Influence of pressure, temperature and surface area/volume ratio on the texture of pyrolytic carbon deposited from methane. Carbon, to be submitted.
56. Endo M., Iijima S., Dresselhaus M.S., Carbon nanotubes 1996 Pergamon Press Oxford.
57. 3 carbon and 7-membered rings in fullerene annealing and fragmentation Nature 366: 1993 665-667.
58. Fonseca A., Hernadi K., Nagy J.B., Lambin P.H., Lucas A.A. Model structure of perfectly graphitizable coiled carbon nanotubes Endo M., Iijima S., Dresselhaus M.S., Carbon nanotubes 1996 87-103 Pergamon Press.
59. 3 defect structures in graphite and carbon nanotubes Nature 367: 1994 148-151.
60. Martin R.H. Die Helicene Angew Chem 86: 20 1974 727-738.
61. Murphy D.B., Carroll R.W., Klonowski J.E. Analysis of the products of high-temperature pyrolysis of various hydrocarbons 21st Biennial Conference on Carbon, Extended Abstracts 1993 181-182.