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[7b] are stable, with respect to mass loss, to over ≈250°C. The benzenesulfonale salt undergoes a phase change at ≈150°C.
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20744435179
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No significant broadening of the PXRD peaks was observed even after the twentieth sorption/desorption cycle. In contrast to clathrate systems, this structure has, and maintains, a completely interconnected network. It would, therefore, be expected to retain a higher degree of ordering.
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20744449974
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Nitrile coordination to the sulfonate-ligated Ag centers displaces sulfonate oxygen atoms and triggers the rearrangement. The likely origin of the selectivity is simply that only the MeCN molecule is small enough to initially access these Ag sites.
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