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Volumn 7, Issue 23, 2001, Pages 5176-5182

Highly selective guest uptake in a silver sulfonate network imparted by a tetragonal to triclinic shift in the solid state

Author keywords

Cooperative phenomena; Inclusion compounds; Silver; Sulfonate ligands; Supramolecular chemistry

Indexed keywords

GAS CHROMATOGRAPHY; SINGLE CRYSTALS;

EID: 0035802948     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3765(20011203)7:23<5176::AID-CHEM5176>3.0.CO;2-1     Document Type: Article
Times cited : (133)

References (76)
  • 10
    • 0001921386 scopus 로고    scopus 로고
    • (Eds.: J. L. Atwood, J. E. D. Davies, D. D. MacNicol, F. Vögtle), Elsevier Science, New York
    • b) G. Alberli, U. Costantino, in Comprehensive Supramolecular Chemistry, Vol. 7 (Eds.: J. L. Atwood, J. E. D. Davies, D. D. MacNicol, F. Vögtle), Elsevier Science, New York, 1996, pp. 1-24.
    • (1996) Comprehensive Supramolecular Chemistry , vol.7 , pp. 1-24
    • Alberli, G.1    Costantino, U.2
  • 38
    • 20744441411 scopus 로고    scopus 로고
    • note
    • [7b] are stable, with respect to mass loss, to over ≈250°C. The benzenesulfonale salt undergoes a phase change at ≈150°C.
  • 39
    • 0000534359 scopus 로고    scopus 로고
    • Moore and co-workers have recently performed a comprehensive search of the Cambridge Structural Database to quantify occurrences of metal ion geometries, see D. Venkataraman, Y. Du, S. R. Wilson, P. Zhang, K. Hirsch, J. S. Moore, J. Chem. Ed. 1997, 74, 915. Their results, available at http://sulfur.scs.uiuc.edu, indicate that silver(I) may adopt anywhere from a two to six-coordinate geometry but that three and four-coordinate geometries are most common.
    • (1997) J. Chem. Ed. , vol.74 , pp. 915
    • Venkataraman, D.1    Du, Y.2    Wilson, S.R.3    Zhang, P.4    Hirsch, K.5    Moore, J.S.6
  • 45
    • 0001167858 scopus 로고
    • The only other works citing 3-pyridinesulfonate as a ligand, although not in the formation of extended structures, are: a) F. A. Cotton, L. M. Daniels, M. L. Montero, C. M. Murillo, Polyhedron 1992, 11, 2767;
    • (1992) Polyhedron , vol.11 , pp. 2767
    • Cotton, F.A.1    Daniels, L.M.2    Montero, M.L.3    Murillo, C.M.4
  • 48
  • 59
    • 20744435179 scopus 로고    scopus 로고
    • note
    • No significant broadening of the PXRD peaks was observed even after the twentieth sorption/desorption cycle. In contrast to clathrate systems, this structure has, and maintains, a completely interconnected network. It would, therefore, be expected to retain a higher degree of ordering.
  • 73
    • 20744449974 scopus 로고    scopus 로고
    • note
    • Nitrile coordination to the sulfonate-ligated Ag centers displaces sulfonate oxygen atoms and triggers the rearrangement. The likely origin of the selectivity is simply that only the MeCN molecule is small enough to initially access these Ag sites.
  • 75
    • 20744447067 scopus 로고    scopus 로고
    • Bruker AXS Inc., Madison, Wisconsin, 1997
    • Bruker AXS Inc., Madison, Wisconsin, 1997.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.