A layered silver sulfonate incorporating nine-coordinate Ag(I) in a hexagonal grid

Chemical Communications

Volumn , Issue 16, 1999, Pages 1485-1486

  Shimizu, George K H ^a,b   Enright, Gary D ^a   Ratcliffe, Chris I ^a   Preston, Keith F ^a   Reid, Jennifer L ^a   Ripmeester, John A ^a  

^a NATIONAL RESEARCH COUNCIL CANADA   (Canada)

^b UNIVERSITY OF CALGARY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

PHENYL GROUP; SILVER; SULFONIC ACID DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE;

EID: 0033592196     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a904445k     Document Type: Article

References (22)

1. G. Alberti and U. Costantiono, in Comprehensive Supramolecular Chemistry, ed. J. L. Atwood, J. E. D. Davies, D. D. MacNicol and F. Vögtle, Elsevier Science, New York, 1996, vol. 7, ch. 1, pp. 1-24.
2. For α-and γ-Zr phosphonates, see: G. Alberti and U. Costantino, in Inclusion Compounds, ed. J. L. Atwood, J. E. Davies and D. D. MacNicol, Oxford University Press, New York, 1991, vol. 5, ch. 5, pp. 136-176; for a review to 1997, see, A. Clearfield, Prog. Inorg. Chem., 1998, 47, 371.
3. For α-and γ-Zr phosphonates, see: G. Alberti and U. Costantino, in Inclusion Compounds, ed. J. L. Atwood, J. E. Davies and D. D. MacNicol, Oxford University Press, New York, 1991, vol. 5, ch. 5, pp. 136-176; for a review to 1997, see, A. Clearfield, Prog. Inorg. Chem., 1998, 47, 371.
4. C. Bellito and P. Day, in Comprehensive Supramolecular Chemistry, ed. J. L. Atwood, J. E. D. Davies, D. D. MacNicol and F. Vögtle, Elsevier Science, New York, 1996, vol. 7, ch. 9, pp. 293-313.
5. G. K. H. Shimizu, G. D. Enright, C. I. Ratcliffe, G. S. Rego, J. L. Reid and J. A. Ripmeester, Chem. Mater., 1998, 10, 3282.
6. Sulfonates have been employed as H-bond acceptors in the generation of layered guanidinium sulfonates. Interestingly, in these complexes the sulfonate group forms six H-bonds much like the sulfonates herein form six-coordinate covalent bonds, see: V. A. Russell, C. C. Evans, W. Li and M. D. Ward, Science, 1997, 276, 575; J. A. Swift, A. M. Pivovar, A. M. Reynolds and M. D. Ward, J. Am. Chem. Soc., 1999, 121, 5887; V. A. Russell, M. C. Etter and M. D. Ward, J. Am. Chem. Soc., 1994, 116, 1941.
7. Sulfonates have been employed as H-bond acceptors in the generation of layered guanidinium sulfonates. Interestingly, in these complexes the sulfonate group forms six H-bonds much like the sulfonates herein form six-coordinate covalent bonds, see: V. A. Russell, C. C. Evans, W. Li and M. D. Ward, Science, 1997, 276, 575; J. A. Swift, A. M. Pivovar, A. M. Reynolds and M. D. Ward, J. Am. Chem. Soc., 1999, 121, 5887; V. A. Russell, M. C. Etter and M. D. Ward, J. Am. Chem. Soc., 1994, 116, 1941.
8. Sulfonates have been employed as H-bond acceptors in the generation of layered guanidinium sulfonates. Interestingly, in these complexes the sulfonate group forms six H-bonds much like the sulfonates herein form six-coordinate covalent bonds, see: V. A. Russell, C. C. Evans, W. Li and M. D. Ward, Science, 1997, 276, 575; J. A. Swift, A. M. Pivovar, A. M. Reynolds and M. D. Ward, J. Am. Chem. Soc., 1999, 121, 5887; V. A. Russell, M. C. Etter and M. D. Ward, J. Am. Chem. Soc., 1994, 116, 1941.
9. 1 clusters bridged by succinates have been previously observed, A. Michaelides, V. Kiritis, S. Skoulika and A. Aubry, Angew. Chem., Int. Ed. Engl., 1993, 32, 1495.
10. 2H solid state NMR, a model for the dynamics about the twofold axis of the phenyl ring consistent with the disorder was determined.
11. 2, see: M. D. Poojary, H.-L. Hu, F. L. Campbell III and A. Clearfield, Acta Crystallogr., Sect. B, 1993, 49, 996.
12. 3.
13. 1 are known. The Ag-Ag distances reported here are all significantly less than the van der Waals contact distance for Ag-Ag of 3.40 Å.
14. The most common geometry for nine-coordinate species, primarily observed for nonahydrated lanthanide complexes, is a tricapped trigonal prism, see F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, John Wiley, Toronto, 5th edn., 1988, p. 17. The present structure would fit this description if the two sulfonate groups bonded to each silver(I) were in an eclipsed orientation.
15. 3 to metals does not include the six-fold bridging mode observed here. See: G. A. Lawrance, Chem. Rev., 1986, 86, 17.
16. H. Zabel and S. A. Solin, Graphite Intercalation Compounds I, Springer Series in Material Science 14, Springer, Berlin, 1990.
17. Based upon the structural similarity to graphite, the prospect that the network may be a conductor was entertained. However, EPR spectra revealed a noiseless signal to 77 K, indicative that all the electrons were highly localized and the material is not a conductor.
18. For a hexagonal unit cell, the symmetry requirements are: a = b, α = β = 90, γ = 120°. The observed unit cell parameters, with doubling of γ, are slight distortions from these conditions.
19. 1, see: K. A. Hirsch, S. R. Wilson and J. S. Moore, Inorg. Chem., 1997, 36, 2960; L. Carlucci, G. Ciani, D. M. Proserpio and A. Sironi, Angew. Chem., Int. Ed. Engl., 1995, 34, 1895; G. K. H. Shimizu, G. D. Enright, C. I. Ratcliffe, J. A. Ripmeester and D. D. M. Wayner, Angew. Chem. Int. Ed., 1998, 37, 1407.
20. 1, see: K. A. Hirsch, S. R. Wilson and J. S. Moore, Inorg. Chem., 1997, 36, 2960; L. Carlucci, G. Ciani, D. M. Proserpio and A. Sironi, Angew. Chem., Int. Ed. Engl., 1995, 34, 1895; G. K. H. Shimizu, G. D. Enright, C. I. Ratcliffe, J. A. Ripmeester and D. D. M. Wayner, Angew. Chem. Int. Ed., 1998, 37, 1407.
21. 1, see: K. A. Hirsch, S. R. Wilson and J. S. Moore, Inorg. Chem., 1997, 36, 2960; L. Carlucci, G. Ciani, D. M. Proserpio and A. Sironi, Angew. Chem., Int. Ed. Engl., 1995, 34, 1895; G. K. H. Shimizu, G. D. Enright, C. I. Ratcliffe, J. A. Ripmeester and D. D. M. Wayner, Angew. Chem. Int. Ed., 1998, 37, 1407.
22. E. J. Gabe, Y. LePage, J.-P. Charland, F. L. Lee and P. S. White, J. Appl. Crystallogr., 1989, 32, 384.