Self-assembly of lamellar and expanded lamellar coordination networks

Angewandte Chemie - International Edition

Volumn 37, Issue 10, 1998, Pages 1407-1409

  Shimizu, George K H ^a   Enright, Gary D ^a   Ratcliffe, Chris I ^a   Ripmeester, John A ^a   Wayner, Danial D M ^a  

^a NATIONAL RESEARCH COUNCIL CANADA   (Canada)

Author keywords

Coordination modes; Layered compounds; S ligands; Self assembly; Silver

Indexed keywords

EID: 0032486332     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980605)37:10<1407::AID-ANIE1407>3.0.CO;2-D     Document Type: Article

References (44)

1. a) B. F. Abrahams, B. F. Hoskins, D. M. Michail, R. Robson, Nature 1994, 369, 727-729;
2. b) G. B. Gardner, D. Venkataraman, J. S. Moore, S. Lee, ibid. 1995, 374, 792-795;
3. c) O. M. Yaghi, G. Li, H. Li, ibid. 1995, 378, 703-706;
4. d) M. Fujita, Y. J. Kwon, S. Washizu, K. Ogura, J. Am. Chem. Soc. 1994, 116, 1151-1152;
5. e) T. Soma, H. Yuge, T. Iwamoto, Angew. Chem. 1994, 106, 1746-1747; Angew. Chem. Int. Ed. Engl. 1994, 33, 1665-1666;
6. e) T. Soma, H. Yuge, T. Iwamoto, Angew. Chem. 1994, 106, 1746-1747; Angew. Chem. Int. Ed. Engl. 1994, 33, 1665-1666;
7. f) M. J. Zaworotko, Chem. Soc. Rev. 1994, 283-288;
8. g) L. Carlucci, G. Ciani, D. M. Proserpio, A. Sironi, J. Am. Chem. Soc. 1995, 117, 12861-12862;
9. h) J. R. Black, N. R. Champness, W. Levason, G. Reid, J. Chem. Soc. Chem. Commun. 1995, 1277-1278;
10. i) J. Lu, T. Paliwala, S. C. Lim, C. Yu, T. Niu, A. J. Jacobsen, Inorg. Chem. 1997, 36, 923-929;
11. j) A. J. Blake, N. R. Champness, S. S. M. Chung, W.-S. Li, M. Schröder, Chem. Commun. 1997, 1005-1006.
12. k) D. M. L. Goodgame, S. Menzer, A. M. Smith, D. J. Williams, J. Chem. Soc. Chem. Commun. 1995, 1975-1978;
13. l) H. Zhang, X. Wang, B. K. Teo, J. Am. Chem. Soc. 1996, 118, 11813-11821.
14. J. L. Atwood, J. E. Davies, D. D. MacNicol, Inclusion Compounds, Vols. 1 and 2, Academic Press, New York, 1984.
15. R. T. K. Baker, L. L. Murrell, Novel Materials in Heterogeneous Catalysis, ACS Symp. Ser. 437, American Chemical Society, Washington, DC, 1990.
16. G. A. Ozin, A. Kuperman, A. Stein, Angew. Chem. 1989, 101, 373-390; Angew. Chem. Int. Ed. Engl. 1989, 28, 359-376.
17. G. A. Ozin, A. Kuperman, A. Stein, Angew. Chem. 1989, 101, 373-390; Angew. Chem. Int. Ed. Engl. 1989, 28, 359-376.
18. a) O. M. Yaghi, H. Li, J. Am. Chem. Soc. 1995, 117, 10401-10402;
19. b) S. Suhramanian, M. J. Zaworotko, Angew. Chem. 1995, 107, 2295-2297; Angew. Chem. Int. Ed. Engl. 1995, 34, 2127-2129;
20. b) S. Suhramanian, M. J. Zaworotko, Angew. Chem. 1995, 107, 2295-2297; Angew. Chem. Int. Ed. Engl. 1995, 34, 2127-2129;
21. c) M. Fujita, Y. J. Kwon, O. Sasaki, K. Yamaguchi, K. Ogura, J. Am. Chem. Soc. 1995, 117, 7287-7288.
22. a) T. Iwamoto, J. Inclusion Phenom. Mol. Recognit. Chem. 1996, 24, 61-132;
23. b) H. Zhao, R. A. Heintz, K. B. Dunbar, R. D. Rogers, J. Am. Chem. Soc. 1996, 118, 12844-12845;
24. c) D. Venkataraman, G. B. Gardner, S. Lee, J. S. Moore, ibid. 1995, 117, 11600-11601.
25. A few examples employing thioethers have recently appeared in the literature, in addition to ref. [1h], a) J. R. Black, N. R. Champness, W. Levason, G. Reid, Inorg. Chem. 1997, 36, 4432-4438; b) ibid. 1996, 35, 1820-1824.
26. A few examples employing thioethers have recently appeared in the literature, in addition to ref. [1h], a) J. R. Black, N. R. Champness, W. Levason, G. Reid, Inorg. Chem. 1997, 36, 4432-4438; b) ibid. 1996, 35, 1820-1824.
27. S. G. Murray, F. R. Hartley, Chem. Rev. 1981, 81, 365-414.
28. F. Cavani, F. Triferò, A. Vaccari, Catal. Today 1991, 11, 173-301.
29. In both crystal structures, the interlayer separation was defined as the perpendicular distance between planes of silver ions since the metals are on special positions.
30. c is the formula weight of the unit cell: G. Alberti, U. Costantino in Comprehensive Supramolecular Chemistry, Vol. 7 (Eds.: J. L. Atwood, J. E. D. Davies, D. D. MacNicol, F. Vögtle), Elsevier, New York, 1996, pp. 1-24.
31. -1, where n′ is the number of charges, a, b and n are defined as in ref. [11].
32. [11]
33. a) M. A. Occelli, H. Robson, Expanded Clays and Other Microporous Solids, Academic Press, New York, 1992;
34. b) A. Clearfield, M. Kuchenmeister in Supramolecular Architecture: Synthetic Control in Thin Films and Solids (Ed.: T. Bein), ACS Symp. Ser. 499, American Chemical Society, Washington, DC, 1992, pp. 128-144.
35. In both structures 2 and 3, the interlayer spacing corresponds to exactly half the length of one of the principal axes: the c axis for 2 and the b axis for 3.
36. Upon loss of solvent or attempts to exchange the PhCN for benzene, the crystals become opaque and no longer diffract.
37. For 2, a steady loss of MeCN is observed between room temperature and 95°C. For 3, loss of PhCN occurs, as expected, in two stages. The first, steady loss from room temperature to 52°C corresponds to the unbound PhCN, followed by a second mass change from 62-97°C for the Ag-bound PhCN. No further changes in the DSC or TG are observed for both 2 and 3 until a transition with an onset temperature of 188±1°C occurs. All mass changes are within reasonable limits (5%) of the expected values given that the room temperature desolvation of 2 and 3 made an accurate determination of the initial mass impossible. The value of 188°C is comparable to other Ag coordination arrays with ligands generally accepted to be better donors than thioethers. See: F-Q. Liu, T. D. Tilley, Inorg. Chem. 1997, 36, 5090-5096.
38. S. R. Cooper, Acc. Chem. Res. 1988, 21, 141-146.
39. G. K. H. Shimizu, G. D. Enright, C. I. Ratcliffe, J. A. Ripmeester, D. D. M. Wayner, unpublished results.
40. Compound 1 has twice been observed as a synthesis by-product: a) S. J. Loeb, G. K. H. Shimizu, Synlett 1992, 823-825; b) F. Vögtle, B. Kleiser, Angew. Chem. Suppl. 1982, 1392-1397.
41. Compound 1 has twice been observed as a synthesis by-product: a) S. J. Loeb, G. K. H. Shimizu, Synlett 1992, 823-825; b) F. Vögtle, B. Kleiser, Angew. Chem. Suppl. 1982, 1392-1397.
42. Elemental analyses were performed on single crystals of both 2 and 3 as expeditiously as possible. However, some loss of the nitrile solvent was unavoidable resulting in the slightly low observed C, H values.
43. [23] Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-101137. Copies of the data can be obtained free of charge on application to: CCDC, 12 Union Road, Cambridge CB21EZ, UK (Fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
44. F. J. Gabe, Y. LcPage, J.-P. Charland, F. L. Lee, P. S. White, J. Appl. Crystallogr. 1989, 32, 384-387.