Polymeric layers catenated by ribbons of rings in a three-dimensional self-assembled architecture: A nanoporous network with spongelike behavior

Angewandte Chemie - International Edition

Volumn 39, Issue 8, 2000, Pages 1506-1510

  Carlucci, Lucia ^b   Ciani, Gianfranco ^a   Moret, Massimo ^a   Proserpio, Davide M ^a   Rizzato, Silvia ^a  

^a UNIVERSITY OF MILAN   (Italy)

^b UNIVERSITY OF INSUBRIA   (Italy)

Author keywords

Coordination polymers; Copper; Layered compounds; N ligands; Nanostructures

Indexed keywords

CATENANE; COPPER SULFATE; POLYMER;

ARTICLE; ATOMIC FORCE MICROSCOPY; CRYSTAL STRUCTURE; POLYMERIZATION;

EID: 0034678767     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(20000417)39:8<1506::AID-ANIE1506>3.0.CO;2-U     Document Type: Article

References (42)

1. a) B. F. Hoskins, R. Robson, J. Am. Chem. Soc. 1990, 112, 1546;
2. b) R. Robson, B. F. Abrahams, S. R. Batten, R. W. Gable, B. F. Hoskins, J. Liu, Supramolecular Architecture, Chap. 19, American Chemical Society, Washington 1992;
3. c) O. M. Yaghi, H. Li, C. Davis, D. Richardson, T. L. Groy, Acc. Chem. Res. 1998, 31, 474;
4. d) M. Munakata, L. P. Wu, T. Kuroda-Sowa, Adv. Inorg. Chem. 1999, 46, 173;
5. e) P. J. Hagrman, D. Hagrman, J. Zubieta, Angew. Chem. 1999, 111, 2798; Angew. Chem. Int. Ed. 1999, 38, 2638.
6. e) P. J. Hagrman, D. Hagrman, J. Zubieta, Angew. Chem. 1999, 111, 2798; Angew. Chem. Int. Ed. 1999, 38, 2638.
7. For examples, see:a) C. Janiak, Angew. Chem. 1997, 109, 1499; Angew. Chem. Int. Ed. Engl. 1997, 36, 1431; b) C. J. Kepert, M. J. Rosseinsky, Chem. Commun. 1998, 31; D. M. L. Goodgame, D. A. Grachvogel, D. J. Williams, Angew. Chem. 1999, 111, 217; Angew. Chem. Int. Ed. 1999, 38, 153.
8. For examples, see:a) C. Janiak, Angew. Chem. 1997, 109, 1499; Angew. Chem. Int. Ed. Engl. 1997, 36, 1431; b) C. J. Kepert, M. J. Rosseinsky, Chem. Commun. 1998, 31; D. M. L. Goodgame, D. A. Grachvogel, D. J. Williams, Angew. Chem. 1999, 111, 217; Angew. Chem. Int. Ed. 1999, 38, 153.
9. For examples, see:a) C. Janiak, Angew. Chem. 1997, 109, 1499; Angew. Chem. Int. Ed. Engl. 1997, 36, 1431; b) C. J. Kepert, M. J. Rosseinsky, Chem. Commun. 1998, 31; D. M. L. Goodgame, D. A. Grachvogel, D. J. Williams, Angew. Chem. 1999, 111, 217; Angew. Chem. Int. Ed. 1999, 38, 153.
10. For examples, see:a) C. Janiak, Angew. Chem. 1997, 109, 1499; Angew. Chem. Int. Ed. Engl. 1997, 36, 1431; b) C. J. Kepert, M. J. Rosseinsky, Chem. Commun. 1998, 31; D. M. L. Goodgame, D. A. Grachvogel, D. J. Williams, Angew. Chem. 1999, 111, 217; Angew. Chem. Int. Ed. 1999, 38, 153.
11. For examples, see:a) C. Janiak, Angew. Chem. 1997, 109, 1499; Angew. Chem. Int. Ed. Engl. 1997, 36, 1431; b) C. J. Kepert, M. J. Rosseinsky, Chem. Commun. 1998, 31; D. M. L. Goodgame, D. A. Grachvogel, D. J. Williams, Angew. Chem. 1999, 111, 217; Angew. Chem. Int. Ed. 1999, 38, 153.
12. S. R. Batten, R. Robson, Angew. Chem. 1998, 110, 1558; Angew. Chem. Int. Ed. 1998 37, 1460.
13. S. R. Batten, R. Robson, Angew. Chem. 1998, 110, 1558; Angew. Chem. Int. Ed. 1998 37, 1460.
14. C. Hamers, O. Kocian, F. M. Raymo, J. F. Stoddard, Adv. Mater. 1998, 10, 1366, and references therein.
15. a) L. Carlucci, G. Ciani, D. W. von Gudenberg, D. M. Proserpio Inorg. Chem. 1997, 36, 3812;
16. b) O. Mamula, A. von Zelewsky, T. Bark, G. Bernardinelli, Angew. Chem. 1999, 111, 3129; Angew. Chem. Int. Ed. 1999, 38, 2945.
17. b) O. Mamula, A. von Zelewsky, T. Bark, G. Bernardinelli, Angew. Chem. 1999, 111, 3129; Angew. Chem. Int. Ed. 1999, 38, 2945.
18. P. M. van Calcar, M. M. Olmstead, A. L. Balch, J. Chem. Soc. Chem. Commun. 1995, 1773.
19. a) L. Carlucci, G. Ciani, D. M. Proserpio, Chem. Commun. 1999, 449;
20. b) C. V. K. Sharma, R. D. Rogers, Chem. Commun. 1999, 83;
21. c) D. Hagrman, R. P. Hammond, R. Haushalter, J. Zubieta, Chem. Mater. 1998, 10, 2091;
22. d) M. Kondo, T. Joshitomi, K. Seki, H. Matsuzaka, S. Kitagawa, Angew. Chem. 1997, 109, 1844; Angew. Chem. Int. Ed. Engl. 1997, 36, 1725;
23. d) M. Kondo, T. Joshitomi, K. Seki, H. Matsuzaka, S. Kitagawa, Angew. Chem. 1997, 109, 1844; Angew. Chem. Int. Ed. Engl. 1997, 36, 1725;
24. e) K. N. Power, T. L. Hennigar, M. J. Zaworotko, New J. Chem. 1998, 177.
25. J.-L. Weidmann, J.-M. Kern, J.-P. Sauvage, D. Muscat, S. Mullins, W. Köhler, C. Rosenauer, H. J. Räder, K. Martin, Y. Geerts, Chem. Eur. J. 1999, 5, 1841, and references therein.
26. A. J. Blake, N. R. Champness, A. Khlobystow, D. A. Lenenovkii, W.-S. Li, M. Schröder, Chem. Commun. 1997, 2027.
27. a) M. Fujita, Y. J. Kwon, O. Sasaki, K. Yamaguchi, K. Ogura, J. Am. Chem. Soc. 1995, 117, 7287;
28. b) L. Carlucci, G. Ciani, D. M. Proserpio, J. Chem. Soc. Dalton Trans. 1999, 1799;
29. c) Y.-B. Dong, R. C. Layland, M. D. Smith, N. G. Pschirer, U. H. F. Bunz, H.-C. zur Loye, Inorg. Chem. 1999, 38, 3056.
30. M.-L. Tong, X.-M. Chen, B.-H. Ye, L.-N. Ji, Angew. Chem. 1999, 111, 2376; Angew. Chem. Int. Ed. 1999, 38, 2237.
31. M.-L. Tong, X.-M. Chen, B.-H. Ye, L.-N. Ji, Angew. Chem. 1999, 111, 2376; Angew. Chem. Int. Ed. 1999, 38, 2237.
32. a) F.-Q. Liu, T. D. Tilley, Inorg. Chem. 1997, 36, 5090;
33. b) L. Carlucci, G. Ciani, P. Macchi, D. M. Proserpio, S. Rizzato, Chem. Eur. J. 1999, 5, 237.
34. These topological properties apply also to systems based on the inclined interpenetration of 2D layers (examples are given in ref. [3], sect. 3.2) and even to the remarkable polyrotaxane reported in: B. F. Hoskins, R. Robson, D. A. Slizys, J. Am. Chem. Soc. 1997 119, 2952.
35. 2 (SHELX-97). Anisotropic thermal factors were assigned to all the nonhydrogen atoms except the water molecules with half occupancy. All diagrams were generated using the SCHAKAL 97. Crystallographic data (excluding structure factors) for the structure reported in this paper has been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-136800. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+ 44) 1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
36. Analysis of the holes was performed with the PLATON program (A. L. Spek, PLATON, Utrecht University, 1999). The representation of the surfaces of the cavities was obtained with SURFNET; R. A. Laskowski, J. Mol. Graph. 1995, 13, 323.
37. 3. The increased dimensions with respect to the single crystal data at 223 K can be attributed mainly to thermal expansion.
38. Differential scanning calorimetry (DSC) analysis shows a broad exothermic peak (40-120 C) with its maximum at 90 C and a minor complex event at 160-190 C..
39. Exchange with other polar solvents (methanol, acetonitrile) has also been successful. Samples of 1 dried at 100 C and left in the presence of vapors of the polar solvent gave rather different XRPD spectra but after desolvation and rehydration with water vapors again show the original spectrum.
40. This contrasts with that observed in the (reversible) desolvation of a recently reported hydrogen-bonded framework compound of remarkable flexibility that transforms into a second (dehydrated) monocrystalline form:C. J. Kepert, D. Hesek, P.D. Beer, M. J. Rosseinsky, Angew. Chem. 1998, 111, 3335; Angew. Chem. Int. Ed. 1998, 37, 3158.
41. This contrasts with that observed in the (reversible) desolvation of a recently reported hydrogen-bonded framework compound of remarkable flexibility that transforms into a second (dehydrated) monocrystalline form:C. J. Kepert, D. Hesek, P.D. Beer, M. J. Rosseinsky, Angew. Chem. 1998, 111, 3335; Angew. Chem. Int. Ed. 1998, 37, 3158.
42. The nonrigidity of catenated networks with flexible ligands is confirmed by a 3D array of interpenetrated ladders that expands by enclathration of p-dibromobenzene while maintaining the same topology: M. Fujita, O. Sasaki, K.-Y. Watanabe, K. Ogura, K. Yamaguki, New J. Chem. 1998, 189.