Silver Sulfonates: An Unexplored Class of Layered Solids

Chemistry of Materials

Volumn 10, Issue 11, 1998, Pages 3282-3283

  Shimizu, George K H ^a,b   Enright, Gary D ^a   Ratcliffe, Chris I ^a   Rego, Gabriela S ^a   Reid, Jennifer L ^a   Ripmeester, John A ^a  

^a NATIONAL RESEARCH COUNCIL CANADA   (Canada)

^b UNIVERSITY OF CALGARY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000260266     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm980409b     Document Type: Article

References (23)

1. Occelli, M. A.; Robson, H. Expanded Clays and Other Microporous Solids; Academic Press: New York, 1992.
2. Whittingham, M. S. Prog. Solid State Chem. 1978, 12, 41.
3. Jacobsen, A. J. Solid State Chemistry Compounds; Cheetham, A. K., Day, P. Eds.; Clarendon, Oxford, 1992; pp 182-233.
4. (a) Cao, G.; Hong, H.-G.; Mallouk, T. E. Acc. Chem. Res. 1992, 25, 420.
5. (b) Clearfield, A.; Costantino, U. Comprehensive Supramolecular Chemistry; Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vögtle, F., Eds.; Elsevier Science: New York, 1996; Vol. 7, Chapter 4, pp 107-151.
6. Alberti, G. Comprehensive Supramolecular Chemistry; Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vögtle, F., Eds.; Elsevier Science: New York, 1996; Vol. 7, Chapter 5, pp 151-189.
7. (a) Cao, G.; Garcia, M. E.; Alacá, M.; Burgess, L. F.; Mallouk, T. E. J. Am. Chem. Soc. 1992, 114, 7574.
8. (b) Burwell, D. A.; Thompson, M. E. Chem. Mater. 1991, 3, 730.
9. Carlino, S. Solid State Ionics 1997, 98, 73.
10. Zhang, B.; Clearfield, A. J. Am. Chem. Soc. 1997, 119, 2751.
11. The structure of silver p-chlorobenzenesulfonate (Bernardinelli, G.; Lucken, E. A. C.; Costines, M. Z. Kristallogr. 1991, 195, 145-146) is isomorphous with the structure reported herein. However, in the previous work, no mention of the two-dimensional nature of the compound was made. Only tables of unit cell parameters, atomic coordinates, and data acquisition conditions were presented.
12. (a) For a previous attempt at the generation of a layered sulfonate, see: Kosnic, E. J.; McClymont, E. L.; Hodder, R. A.; Squattrito, P. J. Inorg. Chim. Acta 1992, 201, 143. (b) For a AgOTs-p-aminobenzoic acid complex, see: Smith, G. E.; Lynch, D. E.; Kennard, C. H. L. Inorg. Chem. 1996, 35, 2711-2712.
13. (a) For a previous attempt at the generation of a layered sulfonate, see: Kosnic, E. J.; McClymont, E. L.; Hodder, R. A.; Squattrito, P. J. Inorg. Chim. Acta 1992, 201, 143. (b) For a AgOTs-p-aminobenzoic acid complex, see: Smith, G. E.; Lynch, D. E.; Kennard, C. H. L. Inorg. Chem. 1996, 35, 2711-2712.
14. Obtained from Aldrich Chemical Co. and used as received.
15. -1. Data collection temperature = -100°C. The structure was collected on a Siemens SMART CCD diffractometer using the 01 scan mode (3° < 2θ < 57.4°) and solved using the NRCVAX suite of programs. Gabe, E. J.; Charland, J.-P.; Lee, F. L.; White, P. S. J. Appl. Cryst. 1989, 22, 384.
16. Moore and co-workers have recently performed a comprehensive search of the Cambridge Structural Database to quantify occurrences of metal ion geometries; see: Venkataraman, D.; Du, Y.; Wilson, S. R.; Zhang, P.; Hirsch, K.; Moore, J. S. J. Chem. Ed. 1997, 74, 915. Their results, available at http://sulfur.scs.uiuc.edu, indicate quantitatively that silver(I) most commonly adopts three- and four-coordinate geometries.
17. Van der Waal's contacts for Ag-Ag and Ag-O are 3.42 and 3.52 Å, respectively.
18. Muetterties, E. L.; Wright, C. M. Quart. Rev. 1967, 21, 109.
19. 3 anion: Lawrance, G. A. Chem. Rev. 1986, 86, 17.
20. 3. Indexing of the PXRD pattern, using 31 lines, gave a matching unit cell.
21. -1), with an onset temperature of 298.2°C, was then observed prior to a large exothermic process at ca. 325°C associated with a mass loss of 43.4%.
22. 3. Elemental analyses confirmed a 2:1 stoichiometry of amine to AgOTs for both 25 and 70°C samples.
23. Ag benzenesulfonate also forms a layered network: Shimizu, G. K. H.; Enright, G. D.; Ratcliffe, C. I.; Ripmeester, J. A. Unpublished results.