Nanoporous molecular sandwiches: Pillared two-dimensional hydrogen- bonded networks with adjustable porosity

Science

Volumn 276, Issue 5312, 1997, Pages 575-579

  Russell, Victoria A ^a   Evans, Cara C ^a   Li, Wenjie ^a   Ward, Michael D ^a  

^a Amundson Hall ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL LATTICES; HYDROGEN BONDS; IONS; MOLECULAR STRUCTURE; MOLECULES; NANOSTRUCTURED MATERIALS; POROSITY; POROUS MATERIALS;

CRYSTAL ENGINEERING; DISULFONATE IONS; GUANIDINIUM IONS; HYDROGEN BONDED NETWORKS; NANOPOROUS MOLECULAR SANDWICHES;

MOLECULAR CRYSTALS;

GUANIDINE; NANOPARTICLE;

ARTICLE; CHANNEL GATING; CRYSTAL STRUCTURE; HYDROGEN BOND; MOLECULAR BIOLOGY; PHYSICAL PHENOMENA; PRIORITY JOURNAL; STRUCTURE ANALYSIS;

EID: 1842378076     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.276.5312.575     Document Type: Article

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26. p for the continuous single-layer stacking motif.
27. 3CN.
28. 2 are systematically lower, by an average of 1.2%, than Ck values reported by others [see A. I. Kitaigorodskii, Molecular Crystals and Molecules (Academic Press, New York, 1973), and A. Gavezzotti, Nouv. J. Chim. 6, 443 (1982)].
29. 2 are systematically lower, by an average of 1.2%, than Ck values reported by others [see A. I. Kitaigorodskii, Molecular Crystals and Molecules (Academic Press, New York, 1973), and A. Gavezzotti, Nouv. J. Chim. 6, 443 (1982)].
30. 2(propane-1,3-disulfonate) can be crystallized from water. Molecular models indicate that the voids in a propane-1,3-disulfonate bilayer structure would not be large enough to accommodate molecular guests that would be needed to stabilize the lattice. Furthermore, a bilayer structure would require an unfavorable eclipsed conformation along one of the carbon-carbon bonds of this pillar.
31. The twist angles for biphenyl in the solution and gas phases lie in the ranges 20° to 25° and 40° to 45°, respectively [see O. Bastiansen and S. Samdal, J. Mol. Struct. 128, 115 (1985), and G. Casalone, C. Mariani, A. Mugnoli, M. Simonetta, Mol. Phys. 15, 339 (1968)].
32. The twist angles for biphenyl in the solution and gas phases lie in the ranges 20° to 25° and 40° to 45°, respectively [see O. Bastiansen and S. Samdal, J. Mol. Struct. 128, 115 (1985), and G. Casalone, C. Mariani, A. Mugnoli, M. Simonetta, Mol. Phys. 15, 339 (1968)].
33. The twist angle in crystalline biphenyl is 0°, whereas the twist angles in crystalline substituted biphenyls range from 0° to 47.2° [see G.-P. Charbonneau and Y. Delugeard, Acta Crystallogr. B33, 1586 (1977), and C. P. Brock and R. P. Minton, J. Am. Chem. Soc. 111, 4586 (1989)].
34. The twist angle in crystalline biphenyl is 0°, whereas the twist angles in crystalline substituted biphenyls range from 0° to 47.2° [see G.-P. Charbonneau and Y. Delugeard, Acta Crystallogr. B33, 1586 (1977), and C. P. Brock and R. P. Minton, J. Am. Chem. Soc. 111, 4586 (1989)].
35. 2OH, using n = 5 as a basis, were similar, with 1.1 (n = 6), 1.0 (n = 5), 0.71 (n = 4), 0.23 (n = 3), 0.48 (n = 2), and 0.20 (n = 1). The selectivity ratios for 1-alkanenitrile inclusion over 1-alkanol inclusion for equivalent n were 3.0 (n = 6), 6.3 (n = 5), 10.0 (n = 4), and 1.4 (n = 3).
36. M. E. Davis, A. J. Katz, W. R. Ahmad, Chem. Mater. 8, 1820 (1996).
37. We thank V. Young, D. Britton, and W. Ojala (University of Minnesota) for crystallographic services and NSF for financial support. Supplementary material, including crystallographic reports and coordinates, is available on request.