Thermodynamic vs kinetic aspects in the formation and morphological transitions of crew-cut aggregates produced by self-assembly of polystyrene-b-poly(acrylic acid) block copolymers in dilute solution

Macromolecules

Volumn 32, Issue 7, 1999, Pages 2239-2249

  Zhang, Lifeng ^a,b   Eisenberg, Adi ^a  

^a MCGILL UNIVERSITY   (Canada)

^b ROHM AND HAAS COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADHESION; AGGLOMERATION; CARBOXYLIC ACIDS; COMPOSITION EFFECTS; DISSOLUTION; MICELLES; MORPHOLOGY; POLYSTYRENES; THERMODYNAMICS; WATER;

MICELLIZATION; POLYACRYLIC ACIDS;

BLOCK COPOLYMERS;

EID: 0033528605     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma981039f     Document Type: Article

References (35)

1. Price, C. In Developments in Block Copolymers; Goodman, I., Ed.; Applied Science Publishers: London, 1982; Vol. 1, p 39. Selb. J. ; Gallot, Y. In Developments in Block Copolymers; Goodman, I., Ed.; Applied Science Publishers: London, 1985; Vol. 2, p 27; Halperin, A.; Tirrell, M.; Lodge, T. P. Adv. Polym. Sci. 1992, 100, 31. Tuzar, Z.; Kratochvil, P. In Surface and Colloid Science; Matijevic, E.; Ed.; Plenum Press: New York, 1993; Vol. 15, p 1.
2. Price, C. In Developments in Block Copolymers; Goodman, I., Ed.; Applied Science Publishers: London, 1982; Vol. 1, p 39. Selb. J. ; Gallot, Y. In Developments in Block Copolymers; Goodman, I., Ed.; Applied Science Publishers: London, 1985; Vol. 2, p 27; Halperin, A.; Tirrell, M.; Lodge, T. P. Adv. Polym. Sci. 1992, 100, 31. Tuzar, Z.; Kratochvil, P. In Surface and Colloid Science; Matijevic, E.; Ed.; Plenum Press: New York, 1993; Vol. 15, p 1.
3. Price, C. In Developments in Block Copolymers; Goodman, I., Ed.; Applied Science Publishers: London, 1982; Vol. 1, p 39. Selb. J. ; Gallot, Y. In Developments in Block Copolymers; Goodman, I., Ed.; Applied Science Publishers: London, 1985; Vol. 2, p 27; Halperin, A.; Tirrell, M.; Lodge, T. P. Adv. Polym. Sci. 1992, 100, 31. Tuzar, Z.; Kratochvil, P. In Surface and Colloid Science; Matijevic, E.; Ed.; Plenum Press: New York, 1993; Vol. 15, p 1.
4. Price, C. In Developments in Block Copolymers; Goodman, I., Ed.; Applied Science Publishers: London, 1982; Vol. 1, p 39. Selb. J. ; Gallot, Y. In Developments in Block Copolymers; Goodman, I., Ed.; Applied Science Publishers: London, 1985; Vol. 2, p 27; Halperin, A.; Tirrell, M.; Lodge, T. P. Adv. Polym. Sci. 1992, 100, 31. Tuzar, Z.; Kratochvil, P. In Surface and Colloid Science; Matijevic, E.; Ed.; Plenum Press: New York, 1993; Vol. 15, p 1.
5. For star micelles, the curvature of the micelle core surface is very large and the dimension of the corona shell is usually larger than the core. When the curvature is taken into consideration, the actually occupied area per corona chain on a spherical surface drawn through the middle of the corona shell (or a distance from the core surface equivalent to the radius of gyration of the corona-forming blocks) is considered to be at least more reasonable than the area on the surface of micelle core for the comparison.
6. Gao, Z.; Varshney, S. K.; Wong, S.; Eisenberg, A. Macromolecules 1994, 27, 7923. Zhang, L.; Barlow, R. J.; Eisenberg, A. Macromolecules 1995, 28, 6055.
7. Gao, Z.; Varshney, S. K.; Wong, S.; Eisenberg, A. Macromolecules 1994, 27, 7923. Zhang, L.; Barlow, R. J.; Eisenberg, A. Macromolecules 1995, 28, 6055.
8. Zhang, L.; Eisenberg, A. Science 1995, 268, 1728; J. Am. Chem. Soc. 1996, 118, 3168.
9. Zhang, L.; Eisenberg, A. Science 1995, 268, 1728; J. Am. Chem. Soc. 1996, 118, 3168.
10. Zhang, L.; Yu, K.; Eisenberg, A. Science 1996, 272, 1777. Zhang, L.; Eisenberg, A. Macromolecules 1996, 29, 8805.
11. Zhang, L.; Yu, K.; Eisenberg, A. Science 1996, 272, 1777. Zhang, L.; Eisenberg, A. Macromolecules 1996, 29, 8805.
12. Izzo, D.; Marques, C. M. Macromolecules 1997, 30, 6544.
13. Honda, C.; Sakaki, K.; Nose, T. Polymer 1994, 35, 5309. Iyama, K.; Nose, T. Polymer 1998, 39, 651.
14. Honda, C.; Sakaki, K.; Nose, T. Polymer 1994, 35, 5309. Iyama, K.; Nose, T. Polymer 1998, 39, 651.
15. Guo, A.; Liu, G.; Tao, J. Macromolecules 1996, 29, 2487. Ding, J.; Liu, G. Macromolecules 1997, 30, 655. Tao, J.; Stewart, S.; Liu, G.; Yang, M. Macromolecules 1997, 30, 2738.
16. Guo, A.; Liu, G.; Tao, J. Macromolecules 1996, 29, 2487. Ding, J.; Liu, G. Macromolecules 1997, 30, 655. Tao, J.; Stewart, S.; Liu, G.; Yang, M. Macromolecules 1997, 30, 2738.
17. Guo, A.; Liu, G.; Tao, J. Macromolecules 1996, 29, 2487. Ding, J.; Liu, G. Macromolecules 1997, 30, 655. Tao, J.; Stewart, S.; Liu, G.; Yang, M. Macromolecules 1997, 30, 2738.
18. Yu, K.; Zhang, L.; Eisenberg, A. Langmuir 1996, 12, 5984. Yu, K.; Eisenberg, A. Macromolecules 1998, 29, 6359.
19. Yu, K.; Zhang, L.; Eisenberg, A. Langmuir 1996, 12, 5984. Yu, K.; Eisenberg, A. Macromolecules 1998, 29, 6359.
20. Zhang, L.; Bartels, C.; Yu, Y.; Shen, H.; Eisenberg, A. Phys. Rev. Lett. 1997, 79, 5034.
21. Zhang, L.; Eisenberg, A. Macromol. Symp. 1997, 113, 221.
22. Zhang, L.; Eisenberg, A. J. Polym. Sci., in press. Shen, H.; Eisenberg, A. Manuscript in preparation.
23. Yu, Y.; Eisenberg, A. J. Am. Chem. Soc. 1997, 119, 8383. Yu, Y.; Zhang, L.; Eisenberg, A. Macromolecules 1998, 31, 1144.
24. Yu, Y.; Eisenberg, A. J. Am. Chem. Soc. 1997, 119, 8383. Yu, Y.; Zhang, L.; Eisenberg, A. Macromolecules 1998, 31, 1144.
25. Zhang, L.; Eisenberg, A. Polym. Adv. Technol. 1998, 9, 677.
26. Zhang, L.; Shen, H.; Eisenberg, A. Macromolecules 1997, 30, 1011.
27. Tian, M.; Qin, A.; Ramireddy, C.; Webber, S. E.; Munk, P.; Tuzar, Z.; Prochazka, K. Langmuir 1993, 9, 1741.
28. Pacovska, M.; Prochazka, K.; Tuzar, Z.; Munk, P. Polymer 1993, 34, 4585.
29. Wang, Y.; Kausch, C. M.; Chun, M.; Quirk, R. P.; Mattice, W. L. Macromolecules 1995, 28, 904.
30. Prochazka, K.; Bednar, B.; Mukhtar, E.; Svoboda, P.; Trnena, J.; Almgren, M. J. Phys. Chem. 1991, 95, 4563.
31. Sens, P.; Marques, C. M.; Joanny, J.-F. Macromolecules 1996, 29, 4880.
32. Haliloglu, T.; Bahar, I.; Erman, B.; Mattice, W. L. Macromolecules 1996, 29, 4764.
33. Hamley, I. W.: Koppi, K.; Rosedale, J. H.; Bates, F. S.; Almdal, K.; Mortensen, K. Macromolecules 1993, 26, 5959.
34. Hillmyer, M. A.; Bates, F. S.; Almdal, K.; Mortensen, K.; Ryan, A. J.; Fairclough, P. A. Science 1996, 271, 976.
35. Funari, S. S.; Holmes, M. C.; Tiddy, G. J. T. J. Phys. Chem. 1994, 98, 3015.