Bioorganometallic chemistry-transition metal complexes with α-amino acids and peptides

Angewandte Chemie - International Edition

Volumn 37, Issue 12, 1998, Pages 1634-1654

  Severin, Kay ^a   Bergs, Ralph ^b   Beck, Wolfgang ^a  

^a Institut fur Anorganische Chemie der Universitat   (Germany)

^b Conica Technik AG ^*  (Switzerland)

Author keywords

amino acids; Bioorganometallic chemistry; Coordination modes; Peptides; Transition metals

Indexed keywords

AMINO ACID ANALYSIS; CARBONYL COMPLEX; CATALYST; DNA; ENANTIOSELECTIVITY; IMMUNOASSAY; LIGAND; METAL COMPLEX; PEPTIDE ANALYSIS; RIBOSOME; STEROID; SUGAR;

EID: 0032479389     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980703)37:12<1634::AID-ANIE1634>3.0.CO;2-C     Document Type: Review

References (466)

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2. Examples of organometallic complexes with other biologically relevant ligands: a) Nucleoside bases: H. Chen, S. Ogo, R. H. Fish, J. Am. Chem. Soc. 1996, 118, 4993-5001; b) enzymes: A. D. Ryabov, Angew. Chem. 1991, 103, 945-955; Angew. Chem. Int. Ed. Engl. 1991, 30, 931; c) steroids: G. Jaouen, A. Vessières, I. S. Butler, Acc. Chem. Res. 1993, 26, 361-369; d) Sugars: S. Krawielitzki, W. Beck, Chem. Ber. 1997, 130, 1659-1662; K. H. Dötz, R. Ehlenz, Chem. Eur. J. 1997, 3, 1751-1756, and references therein.
3. Examples of organometallic complexes with other biologically relevant ligands: a) Nucleoside bases: H. Chen, S. Ogo, R. H. Fish, J. Am. Chem. Soc. 1996, 118, 4993-5001; b) enzymes: A. D. Ryabov, Angew. Chem. 1991, 103, 945-955; Angew. Chem. Int. Ed. Engl. 1991, 30, 931; c) steroids: G. Jaouen, A. Vessières, I. S. Butler, Acc. Chem. Res. 1993, 26, 361-369; d) Sugars: S. Krawielitzki, W. Beck, Chem. Ber. 1997, 130, 1659-1662; K. H. Dötz, R. Ehlenz, Chem. Eur. J. 1997, 3, 1751-1756, and references therein.
4. Examples of organometallic complexes with other biologically relevant ligands: a) Nucleoside bases: H. Chen, S. Ogo, R. H. Fish, J. Am. Chem. Soc. 1996, 118, 4993-5001; b) enzymes: A. D. Ryabov, Angew. Chem. 1991, 103, 945-955; Angew. Chem. Int. Ed. Engl. 1991, 30, 931; c) steroids: G. Jaouen, A. Vessières, I. S. Butler, Acc. Chem. Res. 1993, 26, 361-369; d) Sugars: S. Krawielitzki, W. Beck, Chem. Ber. 1997, 130, 1659-1662; K. H. Dötz, R. Ehlenz, Chem. Eur. J. 1997, 3, 1751-1756, and references therein.
5. Examples of organometallic complexes with other biologically relevant ligands: a) Nucleoside bases: H. Chen, S. Ogo, R. H. Fish, J. Am. Chem. Soc. 1996, 118, 4993-5001; b) enzymes: A. D. Ryabov, Angew. Chem. 1991, 103, 945-955; Angew. Chem. Int. Ed. Engl. 1991, 30, 931; c) steroids: G. Jaouen, A. Vessières, I. S. Butler, Acc. Chem. Res. 1993, 26, 361-369; d) Sugars: S. Krawielitzki, W. Beck, Chem. Ber. 1997, 130, 1659-1662; K. H. Dötz, R. Ehlenz, Chem. Eur. J. 1997, 3, 1751-1756, and references therein.
6. Examples of organometallic complexes with other biologically relevant ligands: a) Nucleoside bases: H. Chen, S. Ogo, R. H. Fish, J. Am. Chem. Soc. 1996, 118, 4993-5001; b) enzymes: A. D. Ryabov, Angew. Chem. 1991, 103, 945-955; Angew. Chem. Int. Ed. Engl. 1991, 30, 931; c) steroids: G. Jaouen, A. Vessières, I. S. Butler, Acc. Chem. Res. 1993, 26, 361-369; d) Sugars: S. Krawielitzki, W. Beck, Chem. Ber. 1997, 130, 1659-1662; K. H. Dötz, R. Ehlenz, Chem. Eur. J. 1997, 3, 1751-1756, and references therein.
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168. e) E. Cuingnet, C. Sergheraert, A. Tartar, M. Dautrevaux, J. Organomet. Chem. 1980, 195, 325-329. The use of 89 in solution-phase peptide syntheses has also been described: J. Pospišek, Š. Thoma, I. Fric, K. Bláha, Collect. Czech. Chem. Commun. 1980, 45, 435-441.
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172. I. Zahn, B. Wagner, K. Polborn, W. Beck, J. Organomet. Chem. 1990, 394, 601-614; comparable reactions have been reported for the first time by Krafft et al.: M. E. Krafft, X. Y. Yu, S. E. Milczanowski, K. D. Donnelly, J. Am. Chem. Soc. 1992, 114, 9215-9217, and references therein.
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192. b) H. Eckert, C. Seidel, Angew. Chem. 1986, 98, 168-170; Angew. Chem. Int. Ed. Engl. 1986, 25, 159-160. The Fem group has also been used as an S-protecting group for cysteine: A. S. J. Stewart, C. N. C. Drey, J. Chem. Soc. Perkin Trans. 1 1990, 1753-1756. S-Femcysteinate has been used as a multidentate ligand: ref.[1c] and: D. Freiesleben, T. Hauck, R. Lampeka, W. Beck, unpublished results.
193. b) H. Eckert, C. Seidel, Angew. Chem. 1986, 98, 168-170; Angew. Chem. Int. Ed. Engl. 1986, 25, 159-160. The Fem group has also been used as an S-protecting group for cysteine: A. S. J. Stewart, C. N. C. Drey, J. Chem. Soc. Perkin Trans. 1 1990, 1753-1756. S-Femcysteinate has been used as a multidentate ligand: ref.[1c] and: D. Freiesleben, T. Hauck, R. Lampeka, W. Beck, unpublished results.
194. b) H. Eckert, C. Seidel, Angew. Chem. 1986, 98, 168-170; Angew. Chem. Int. Ed. Engl. 1986, 25, 159-160. The Fem group has also been used as an S-protecting group for cysteine: A. S. J. Stewart, C. N. C. Drey, J. Chem. Soc. Perkin Trans. 1 1990, 1753-1756. S-Femcysteinate has been used as a multidentate ligand: ref.[1c] and: D. Freiesleben, T. Hauck, R. Lampeka, W. Beck, unpublished results.
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