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Volumn 129, Issue 8, 1996, Pages 937-944

Synthesis, spectroscopic characterization, and crystal structure determination of cationic [(cyclopentadienyl)dicarbonyliron](alkynyl)-aminocarbene complexes

Author keywords

(alkynyl)carbene ligand; Cationic aminocarbene complexes; Iron (2 methoxyvinyl)ammocarbene complexes; Iron acyl complexes

Indexed keywords


EID: 0008721304     PISSN: 00092940     EISSN: None     Source Type: Journal    
DOI: 10.1002/cber.19961290810     Document Type: Article
Times cited : (13)

References (68)
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    • (1990) Comprehensive Organic Synthesis , vol.5
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    • i Ed.: L. S. Liebeskind, JA l Press LTD
    • Reviews: [6a] P. Helquist in Advances in Metal-Organic Chemistry i Ed.: L. S. Liebeskind), JA l Press LTD, 1991, vol. 2, pp. 143-194.
    • (1991) Advances in Metal-Organic Chemistry , vol.2 , pp. 143-194
    • Helquist, P.1
  • 31
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    • (Ed.: Gmelin-Institut), Springer-Verlag, Berlin
    • [6b] W. Petz in Iron-Carhene Complexes (Ed.: Gmelin-Institut), Springer-Verlag, Berlin, 1993.
    • (1993) Iron-Carhene Complexes
    • Petz, W.1
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    • and references cited.
    • [6c] V. Guerchais, Bull. Soc. Chim. Fr. 1994, 131, 803-811. and references cited.
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    • Guerchais, V.1
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    • For a discussion of similar results observed in NMR spectroscopy of related chromium carbene complexes, see ref.[5b]
    • For a discussion of similar results observed in NMR spectroscopy of related chromium carbene complexes, see ref.[5b]
  • 47
    • 33747574887 scopus 로고
    • The presence of related deprotonated n'-iminoacyl complexes can be ruled out on the basis of NMR and IR spectroscopy. For some examples of imidoyl complexes, see ré[9] and [14a] H. Brunner, G. Kerkien, I Wächter, J. Organomet. Chem. 1982, 22, 295-300.
    • (1982) J. Organomet. Chem. , vol.22 , pp. 295-300
    • Brunner, H.1    Kerkien, G.2    Wächter, I.3
  • 51
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    • For related observations in chromium carbene chemistry, see ref. [5e]
    • For related observations in chromium carbene chemistry, see ref. [5e]
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    • [17d] R. Aumann, Chem. Ber. 1993, 126, 2325-2330.
    • (1993) Chem. Ber. , vol.126 , pp. 2325-2330
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    • [18c] R. Aumann, Chem. Ber. 1993, 126, 1867-1872.
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    • Aumann, R.1
  • 62
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    • note
    • For compound 3e a comparable hydrogen bond length is observed: H9-F2a 2.091(18), N9-F2a 2.96(2). However, the [PF(f] counterion is disordered. The position of the fluorine atomes were determined by difference Fourier syntheses.
  • 68
    • 33747524755 scopus 로고    scopus 로고
    • note
    • Further details of the crystal structure determination may be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen. Any request for this material should quote the full literature citation and the reference numbers CSD-405157 for 3e and -405156 for 3f.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.