Synthesis and characterisation of chiral Cu(I) complexes of substituted pyrrolidine ligands. Efficient catalysts for cyclopropanation reactions

Inorganica Chimica Acta

Volumn 244, Issue 2, 1996, Pages 239-245

  Carmona, A ^a   Corma, A ^b   Iglesias, M ^c   Sanchez F ^a  

^a INSTITUTO DE QUÍMICA ORGÁNICA GENERAL   (Spain)

^b CSIC   (Spain)

^c INSTITUTO DE CIENCIA DE MATERIALES DE MADRID   (Spain)

Author keywords

Bidentate nitrogen ligand complexes; Chiral complexes; Copper complexes; Cyclopropanation; Enantioselectivity

Indexed keywords

CHELATION; CHLORINE COMPOUNDS; COMPLEXATION; ENANTIOSELECTIVITY; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STYRENE; SYNTHESIS (CHEMICAL);

CHIRAL COMPLEXES; COPPER (I) COMPLEXES; COPPER COMPLEXES; CYCLOPROPANATION; CYCLOPROPANATION REACTION; EFFICIENT CATALYSTS; ETHYL DIAZOACETATE; NITROGEN LIGAND;

COPPER COMPOUNDS;

EID: 0001129207     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/0020-1693(95)04773-5     Document Type: Article

References (24)

1. H.B. Kagan, in J.D. Morrison (ed.), Asymmetric Synthesis, Vol. 5, Academic Press, Orlando, FL, USA, 1985, p. 1;
2. (b) J.M. Brown and P.A. Chaloner, in L.H. Pignolet (ed.), Homogeneous Catalysis with Metal Phosphine Complexes, Plenum, New York, 1983, p. 137;
3. (c) R. Noyori, Asymmetric Catalysis in Organic Reactions, Wiley, New York, 1994;
4. (d) M.P. Doyle, in I. Ojima (ed.), Catalytic Asymmetric Synthesis, VCH, New York, 1993, p. 63;
5. (e) H. Brunner and W. Zettimeier, Handbook of Enantioselective Catalysis with Transition Metal, VCH, Weinheim, 1993.
6. H. Brunner, Synthesis (1988) 645.
7. R. Noyori, M. Kitamura, in R. Scheffold (ed.), Modern Synthetic Methods, Vol. 5, Springer, Berlin, 1989, p. 115.
8. S.M. Laurie, in G. Wilkinson, R. Gillard and J.A. McCleverty (eds.), Comprehensive Coordination Chemistry, Vol. 2, Pergamon, Oxford, 1987, p. 739.
9. A. Corma, M. Iglesias, C. del Pino and F. Sánchez, J. Organomet. Chem., 431 (1992) 233.
10. A. Carmona, A. Corma, M. Iglesias, A. San José and F. Sánchez, J. Organomet. Chem., 492 (1995) 11.
11. A. Corma, M. Iglesias, C. del Pino and F. Sánchez, J. Mol. Catal, 70 (1991) 369.
12. A. Corma, M. Iglesias, C. del Pino, and F. Sánchez, J. Chem. Soc., Chem. Commun., (1991) 1253.
13. B.W. Cook, R.G.J. Miller and P.F. Todd, J. Organomet. Chem., 19 (1969) 421.
14. I. Csöregh, P. Kierkegaard and R. Norestam, Acta Crystallogr., Sect. B, 31 (1975) 314.
15. F. Mohino, Doctoral Thesis, Universidad Complutense, Madrid, 1994.
16. R.R. Jacobson, Z. Tyeklár and K.D. Karlin, Inorg. Chim. Acta, 181 (1991) 111.
17. K.D. Karlin, M.S. Haka, R.W. Cruse, G.J. Meyer, A. Farooq, Y. Gultneh, J.C. Hayes and J. Zubieta, J. Am. Chem. Soc., 110 (1988) 1196.
18. (a) T.N. Sorrell and D.J. Jameson, J. Am. Chem. Soc., 104 (1982) 1053;
19. (b) 105 (1983) 6013;
20. (c) T.N. Sorrell and M.R. Mchowski, Inorg. Chem., 22 (1983) 1883;
21. (d) S.M. Nelson, A. Lovery and M.G.B. Drew, J. Chem. Soc., Dalton Trans., (1986) 911;
22. (e) T.N. Sorrell, Inorg. Chem., 21 (1982) 1014.
23. P.G. Eller, D.C. Bradley, M.B. Hursthouse and D.W. Meek, Coord. Chem. Rev., 24 (1977) 1.
24. H. Brunner and K. Wutz, New J. Chem., 16 (1992) 57.