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It is of interest to consider our observation from the perspective of Sinniah et al.'s recent study. They carried out a systematic examination of the adhesive forces between tips and samples coated with alkanethiolate monolayers with different terminal groups in various solvents. In water the highest adhesion forces are found for the most Hydrophobic combination of interfaces. See: Sinniah, S. K.; Steel, A. B.; Miller, C. J.; Reutt-Robey, J. E. J. Am. Chem. Soc. 1996, 118, 8925.
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