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10644289464
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When 2,2′-dilithium-1,1′-biphenyl was quenched with elemental sulfur, dibenzo[c,e][1,2]-dithiin was recovered in 50% yield: Delogu, G.; Cossu, S.; Fabbri, D.; Maglioli, P. Org. Prep. Proc. Int. 1991, 23, 455.
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note
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(a) HPLC analysis was performed at rt using a Chiracel OD column (10 μm, 25 cm×0.46 I.D.) at flow rate of 0.6 mL/min, 254 UV detection, using different mixtures (w:w) of n-hexane:propan-2-ol as mobile phase (b) Separation of biphenyl 6 in two enantiomers was performed by chiral HPLC using a Chiracel OD column with 98:2 hexane:propan-2-ol as mobile phase, at a flow rate of 0.6 mL/min and with UV detector at 254 nm.
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We applied conditions that were developed successfully by us for resolution of BINOL and biphenols: Fabbri, D.; Delogu, G.; De Lucchi, O. J. Org. Chem. 1993, 58, 1748.
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