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Otsuka, S.9
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36
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85034153704
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note
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Double bond migration of homoallylamine is not common for the metal catalyzed reaction. However, the coordination by 2-pyridyl group in 9 might provide a directing effect for this isomerization.
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37
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85034137547
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note
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When the reaction was carried out in toluene, a mixture of 4a and 10a was obtained in a 20:80 ratio.
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38
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85034136030
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note
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+) 922.4664, found 922.4694.
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40
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85034152952
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note
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3P.
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