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Volumn 1, Issue 6, 1999, Pages 887-889

Catalytic transformation of aldimine to ketimine by Wilkinson's complex through transimination

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EID: 0000410498     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol990158s     Document Type: Article
Times cited : (46)

References (33)
  • 1
    • 0042728760 scopus 로고
    • For recent reviews, see: (a) Ryabov, A. D. Chem. Rev. 1990, 90, 403-424.
    • (1990) Chem. Rev. , vol.90 , pp. 403-424
    • Ryabov, A.D.1
  • 15
    • 33845559830 scopus 로고
    • For C-H bond activation, see: (a) Suggs, J. W. J. Am. Chem. Soc. 1979, 101, 489.
    • (1979) J. Am. Chem. Soc. , vol.101 , pp. 489
    • Suggs, J.W.1
  • 19
    • 85034131514 scopus 로고    scopus 로고
    • note
    • +) 265.183 050, found 265.183 044.
  • 23
    • 85034133683 scopus 로고    scopus 로고
    • note
    • P-H = 12.4 Hz, 1H, Rh-H).
  • 24
    • 0041466770 scopus 로고
    • Kende, A. S., Ed.; John Wiley & Sons: New York
    • The oxime 1g was completely converted to phenylamide by a rhodium(I)-catalyzed Beckmann rearrangement: Gawley, R. E. In Organic Synthesis; Kende, A. S., Ed.; John Wiley & Sons: New York, 1988; Vol. 35, pp 14-43.
    • (1988) Organic Synthesis , vol.35 , pp. 14-43
    • Gawley, R.E.1
  • 26
    • 85034138764 scopus 로고    scopus 로고
    • note
    • 3).
  • 27
    • 0000685510 scopus 로고    scopus 로고
    • While 5-10 mol % of Rh catalyst has been used in a previously reported reaction, this system requires only 0.5 mol % of Rh catalyst. The hydroacylation of 1-hexene (2a) with benzaldehyde in the presence of 4 produced only a 9% yield of 11a under the reaction conditions of 0.5 mol % of Rh catalyst. The improvement of efficiency for this catalytic reaction is probably due to the adequate ratio of 6 to 3: (a) Jun, C.-H.; Lee, H.; Hong, J.-B. J. Org. Chem. 1997, 62, 1200-1201.
    • (1997) J. Org. Chem. , vol.62 , pp. 1200-1201
    • Jun, C.-H.1    Lee, H.2    Hong, J.-B.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.