Copper-mediated regio- and stereoselective 12β-hydroxylation of steroids with molecular oxygen and an unexpected 12β-chlorination

Tetrahedron

Volumn 61, Issue 1, 2005, Pages 103-114

  Schönecker, Bruno ^a   Lange, Corinna ^a,b   Zheldakova, Tatjana ^c   Günther, Wolfgang ^a   Görls, Helmar ^d   Vaughan, Gavin ^e  

^a Inst F Org Chem M   (Germany)

^b HANS KNÖLL INSTITUTE   (Germany)

^c INSTITUTE OF BIOORGANIC CHEMISTRY   (Belarus)

^d D 07743 Jena Germany   (Germany)

^e EUROPEAN SYNCHROTRON RADIATION FACILITY   (France)

Author keywords

C H activation; Chlorination; Copper; Hydroxylation; Steroids

Indexed keywords

ACETONE; BENZOIN; COPPER COMPLEX; DICHLOROMETHANE; OXYGEN; PYRIDINE; SOLVENT; STEROID; TRIETHYLAMINE;

ARTICLE; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CHLORINATION; COMPLEX FORMATION; HYDROLYSIS KINETICS; HYDROXYLATION; OPPENAUER OXIDATION; OXIDATION KINETICS; POLYMERIZATION; PRIORITY JOURNAL; REDUCTION KINETICS; STEREOCHEMISTRY;

EID: 9744285755     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2004.10.055     Document Type: Article

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