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11
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9644275859
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note
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We modified simultaneously a "mechanical" parameter (substrate roughness) and a "physical" parameter (deposition growth) to ensure a large molecular order difference between the two samples. Further experiments are in progress to determine precisely the respective effect of each parameter on the reported results.
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12
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9644260972
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All images were processed and analyzed using the WS×M software by Nanotec Electronica S. L. (Spain)
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All images were processed and analyzed using the WS×M software by Nanotec Electronica S. L. (Spain).
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13
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9644289864
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Since the roughness has to be measured on a small area on the island, the roughness values are less accurate than on the bare substrate where larger surface areas can be used to determine the roughness data
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Since the roughness has to be measured on a small area on the island, the roughness values are less accurate than on the bare substrate where larger surface areas can be used to determine the roughness data.
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14
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1442337274
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Stievenard, D.4
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15
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9644301453
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note
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A correction is required because we used a semiconductor substrate instead of a metal. However, this correction can be neglected when using the ratio method, because almost the same correction factor applies in the capacitive and charge gradient forces. See ref 14.
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16
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9644269415
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note
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According to the calculation of the factor g given in ref 14, the increase in the factor g reflects the decrease in the island charge screening when a thin insulating layer is inserted between the pentacene island and the silicon.
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17
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1842607461
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20
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0011336568
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and references therein
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To our knowledge, the interfacial dipole at the pentacene-Pt/Ir interface has not been measured by photoemission spectroscopy as in other metal/organic systems. However, such a value of about 1 eV is not unreasonable and it has been observed for various interfaces: Au/Alq3, Au/NPD, Au/TPD, and Au/DPNTCI, for example. Alq3 = tri(8-hydroxyquinolino)aluminium, NPD = N,N'-diphenyl-N.N'- bis(1-naphthyl)-l,1'-biphenyl-4,4'-diamine, TPD = N,N'-diphenyl-N,N'-(3- methylphenyl)-1,1'-biphenyl-4,4'-diamine, DP-NTCI = N,N'-diphenyl-1,4,5,8- naphthyltetracarboxilicimide. See a review in Ishii, H.; Sugiyama, K.; Ito, E.; Seki, K. Adv. Mater. 1999, 11, 605-625, and references therein.
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Ishii, H.1
Sugiyama, K.2
Ito, E.3
Seki, K.4
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21
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9644254682
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This may be due to a lower chemical quality of the pentacene batch used for sample II, Chemicals were used as received
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This may be due to a lower chemical quality of the pentacene batch used for sample II, Chemicals were used as received.
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22
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9644292012
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Sample II, we used a native oxide, 1.5 to 2 nm thick. In sample I, to have a better controlled quality of the oxide surface (smoother surface), we used a microelectronics grade thermal oxide with a thickness of 4 nm
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In sample II, we used a native oxide, 1.5 to 2 nm thick. In sample I, to have a better controlled quality of the oxide surface (smoother surface), we used a microelectronics grade thermal oxide with a thickness of 4 nm.
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23
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0037164844
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Melin, T.; Deresmes, D.; Stievenard, D. Appl. Phys. Lett. 2002, 81, 5054-5056.
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Melin, T.1
Deresmes, D.2
Stievenard, D.3
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24
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2942534980
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The lateral resolution is proportional to the tip - substrate distance. Its value can be inferred from the comparison of a topographic profile and the EFM profile of charged silicon small nanoparticles using similar equipment and measurement conditions; see Melin, T. et al., Phys. Rev. Lett. 2004, 92, 166101.
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Phys. Rev. Lett.
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Melin, T.1
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0037197928
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7544245852
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Heim, T.; Melin, T.; Deresmes, D.; Vuillaume, D. Appl. Phys. Lett. 2004, 85, 2637-2639.
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