Torque-Induced Change in Configuration of a Single NO Molecule on Cu(110)

Physical Review Letters

Volumn 121, Issue 11, 2018, Pages

  Shiotari, Akitoshi ^a   Odani, Takafumi ^a   Sugimoto, Yoshiaki ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORBATES; ATOMIC FORCE MICROSCOPY; ELECTRON TUNNELING; MOLECULES; NITRIC OXIDE; SCANNING TUNNELING MICROSCOPY;

CU(1 1 0); FUNCTIONALIZED; INELASTIC ELECTRON TUNNELING SPECTROSCOPY; NO MOLECULE; NON-VOLATILE; REPULSIVE FORCES; TOGGLE SWITCH;

COPPER COMPOUNDS;

EID: 85053350274     PISSN: 00319007     EISSN: 10797114     Source Type: Journal    
DOI: 10.1103/PhysRevLett.121.116101     Document Type: Article

References (48)

1. S. J. van der Molen and P. Liljeroth, J. Phys. Condens. Matter 22, 133001 (2010). JCOMEL 0953-8984 10.1088/0953-8984/22/13/133001
2. J. L. Zhang, J. Q. Zhong, J. D. Lin, W. P. Hu, K. Wu, G. Q. Xu, A. T. Wee, and W. Chen, Chem. Soc. Rev. 44, 2998 (2015). CSRVBR 0306-0012 10.1039/C4CS00377B
3. B. C. Stipe, M. A. Rezaei, and W. Ho, Phys. Rev. Lett. 81, 1263 (1998). PRLTAO 0031-9007 10.1103/PhysRevLett.81.1263
4. C. Loppacher, M. Guggisberg, O. Pfeiffer, E. Meyer, M. Bammerlin, R. Lüthi, R. Schlittler, J. K. Gimzewski, H. Tang, and C. Joachim, Phys. Rev. Lett. 90, 066107 (2003). PRLTAO 0031-9007 10.1103/PhysRevLett.90.066107
5. A. Sweetman, S. Jarvis, R. Danza, J. Bamidele, S. Gangopadhyay, G. A. Shaw, L. Kantorovich, and P. Moriarty, Phys. Rev. Lett. 106, 136101 (2011). PRLTAO 0031-9007 10.1103/PhysRevLett.106.136101
6. R. Pawlak, S. Fremy, S. Kawai, T. Glatzel, H. Fang, L.-A. Fendt, F. Diederich, and E. Meyer, ACS Nano 6, 6318 (2012). ANCAC3 1936-0851 10.1021/nn301774d
7. S. Yamazaki, K. Maeda, Y. Sugimoto, M. Abe, V. Zobač, P. Pou, L. Rodrigo, P. Mutombo, R. Pérez, P. Jelínek, and S. Morita, Nano Lett. 15, 4356 (2015). NALEFD 1530-6984 10.1021/acs.nanolett.5b00448
8. W. Steurer, B. Schuler, N. Pavlicek, L. Gross, I. Scivetti, M. Persson, and G. Meyer, Nano Lett. 15, 5564 (2015). NALEFD 1530-6984 10.1021/acs.nanolett.5b02145
9. J. N. Ladenthin, T. Frederiksen, M. Persson, J. C. Sharp, S. Gawinkowski, J. Waluk, and T. Kumagai, Nat. Chem. 8, 935 (2016). NCAHBB 1755-4330 10.1038/nchem.2552
10. Y. Zhang, Y. Wang, J.-T. Lü, M. Brandbyge, and R. Berndt, Angew. Chem. 56, 11769 (2017). ANCEAD 0044-8249 10.1002/anie.201704940
11. O. Stetsovych, P. Mutombo, M. Švec, M. Šámal, J. Nejedlý, I. Císařová, H. Vázquez, M. Moro-Lagares, J. Berger, J. Vacek, I. G. Stará, I. Starý, and P. Jelínek, J. Am. Chem. Soc. 140, 940 (2018). JACSAT 0002-7863 10.1021/jacs.7b08729
12. O. Custance, R. Perez, and S. Morita, Nat. Nanotechnol. 4, 803 (2009). NNAABX 1748-3387 10.1038/nnano.2009.347
13. M. Ternes, C. P. Lutz, C. F. Hirjibehedin, F. J. Giessibl, and A. J. Heinrich, Science 319, 1066 (2008). SCIEAS 0036-8075 10.1126/science.1150288
14. Z. Sun, M. P. Boneschanscher, I. Swart, D. Vanmaekelbergh, and P. Liljeroth, Phys. Rev. Lett. 106, 046104 (2011). PRLTAO 0031-9007 10.1103/PhysRevLett.106.046104
15. A. J. Weymouth, T. Hofmann, and F. J. Giessibl, Science 343, 1120 (2014). SCIEAS 0036-8075 10.1126/science.1249502
16. M. Emmrich, M. Schneiderbauer, F. Huber, A. J. Weymouth, N. Okabayashi, and F. J. Giessibl, Phys. Rev. Lett. 114, 146101 (2015). PRLTAO 0031-9007 10.1103/PhysRevLett.114.146101
17. Z. Han, G. Czap, C. Xu, C. L. Chiang, D. Yuan, R. Wu, and W. Ho, Phys. Rev. Lett. 118, 036801 (2017). PRLTAO 0031-9007 10.1103/PhysRevLett.118.036801
18. N. Okabayashi, A. Gustafsson, A. Peronio, M. Paulsson, T. Arai, and F. J. Giessibl, Phys. Rev. B 93, 165415 (2016). PRBMDO 2469-9950 10.1103/PhysRevB.93.165415
19. A. Gustafsson, N. Okabayashi, A. Peronio, F. J. Giessibl, and M. Paulsson, Phys. Rev. B 96, 085415 (2017). PRBMDO 2469-9950 10.1103/PhysRevB.96.085415
20. N. Okabayashi, A. Peronio, M. Paulsson, T. Arai, and F. J. Giessibl, Proc. Natl. Acad. Sci. U.S.A. 115, 4571 (2018). PNASA6 0027-8424 10.1073/pnas.1721498115
21. A. Shiotari, Y. Kitaguchi, H. Okuyama, S. Hatta, and T. Aruga, Phys. Rev. Lett. 106, 156104 (2011). PRLTAO 0031-9007 10.1103/PhysRevLett.106.156104
22. A. Shiotari, T. Mitsui, H. Okuyama, S. Hatta, T. Aruga, T. Koitaya, and J. Yoshinobu, J. Chem. Phys. 140, 214706 (2014). JCPSA6 0021-9606 10.1063/1.4881262
23. A. Shiotari, Reactivity of Nitric Oxide on Copper Surfaces: Elucidated by Direct Observation of Valence Orbitals (Springer, Singapore, 2017).
24. See Supplemental Material at http://link.aps.org/supplemental/10.1103/PhysRevLett.121.116101 for details of experimental methods, STM and AFM images of (Equation presented) with Cu and NO tips, fabrication of the NO tip, IETS of (Equation presented) with Cu and NO tips, reversible switching of (Equation presented) with the tNO tip, configurational changes with uNO and O tips, and additional information for the experimental and simulated potential maps, which includes Refs. [25-27].
25. R. Requist, S. Modesti, P. P. Baruselli, A. Smogunov, M. Fabrizio, and E. Tosatti, Proc. Natl. Acad. Sci. U.S.A. 111, 69 (2014). PNASA6 0027-8424 10.1073/pnas.1322239111
26. V. Madhavan, W. Chen, T. Jamneala, M. F. Crommie, and N. S. Wingreen, Phys. Rev. B 64, 165412 (2001). PRBMDO 0163-1829 10.1103/PhysRevB.64.165412
27. S. Liu, A. Shiotari, D. Baugh, M. Wolf, and T. Kumagai, Phys. Rev. B 97, 195417 (2018). PRBMDO 2469-9950 10.1103/PhysRevB.97.195417
28. F. J. Giessibl, Rev. Mod. Phys. 75, 949 (2003). RMPHAT 0034-6861 10.1103/RevModPhys.75.949
29. J. E. Sader and S. P. Jarvis, Appl. Phys. Lett. 84, 1801 (2004). APPLAB 0003-6951 10.1063/1.1667267
30. A. Shiotari, H. Okuyama, S. Hatta, T. Aruga, M. Alducin, and T. Frederiksen, Phys. Rev. B 94, 075442 (2016). PRBMDO 2469-9950 10.1103/PhysRevB.94.075442
31. G. Kichin, C. Wagner, F. S. Tautz, and R. Temirov, Phys. Rev. B 87, 081408 (2013). PRBMDO 1098-0121 10.1103/PhysRevB.87.081408
32. H. Koshida, S. Hatta, H. Okuyama, A. Shiotari, Y. Sugimoto, and T. Aruga, J. Phys. Chem. C 122, 8894 (2018). JPCCCK 1932-7447 10.1021/acs.jpcc.7b12447
33. L. Gross, N. Moll, F. Mohn, A. Curioni, G. Meyer, F. Hanke, and M. Persson, Phys. Rev. Lett. 107, 086101 (2011). PRLTAO 0031-9007 10.1103/PhysRevLett.107.086101
34. M. Corso, M. Ondráček, C. Lotze, P. Hapala, K. J. Franke, P. Jelínek, and J. I. Pascual, Phys. Rev. Lett. 115, 136101 (2015). PRLTAO 0031-9007 10.1103/PhysRevLett.115.136101
35. C. J. Chen, Phys. Rev. B 42, 8841 (1990). PRBMDO 0163-1829 10.1103/PhysRevB.42.8841
36. C. J. Chen, Introduction to Scanning Tunneling Microscopy (Oxford University Press on Demand, Oxford, England, 1993).
37. With a Cu tip, the dimer is imaged as a shallow dumbbell-shaped protrusion along the [001] direction together with a central depression [Fig. 1(d), middle]; the highest occupied molecular orbital is mainly responsible for the shape of this protrusion. Therefore, an (Equation presented)-wave ((Equation presented)-wave) tip should provide an antinode (node) at the center of the dimer, which is in agreement with the STM appearance of (Equation presented) in Fig. 1(b) [1(c)].
38. A. Shiotari, S. Hatta, H. Okuyama, and T. Aruga, J. Chem. Phys. 141, 134705 (2014). JCPSA6 0021-9606 10.1063/1.4896558
39. J. Welker and F. J. Giessibl, Science 336, 444 (2012). SCIEAS 0036-8075 10.1126/science.1219850
40. M. Emmrich, F. Huber, F. Pielmeier, J. Welker, T. Hofmann, M. Schneiderbauer, D. Meuer, S. Polesya, S. Mankovsky, D. Ködderitzsch, H. Ebert, and F. J. Giessibl, Science 348, 308 (2015). SCIEAS 0036-8075 10.1126/science.aaa5329
41. W. Schneider, K. Hass, R. Ramprasad, and J. Adams, J. Phys. Chem. 100, 6032 (1996). JPCHAX 0022-3654 10.1021/jp9521924
42. O. M. Usov, Y. Sun, V. M. Grigoryants, J. P. Shapleigh, and C. P. Scholes, J. Am. Chem. Soc. 128, 13102 (2006). JACSAT 0002-7863 10.1021/ja056166n
43. L. Wang, G. Wang, H. Qu, Z. H. Li, and M. Zhou, Phys. Chem. Chem. Phys. 16, 10788 (2014). PPCPFQ 1463-9076 10.1039/c4cp00557k
44. H. Mönig, D. R. Hermoso, O. Díaz Arado, M. Todorović, A. Timmer, S. Schüer, G. Langewisch, R. Pérez, and H. Fuchs, ACS Nano 10, 1201 (2016). ANCAC3 1936-0851 10.1021/acsnano.5b06513
45. P. Hapala, G. Kichin, C. Wagner, F. S. Tautz, R. Temirov, and P. Jelínek, Phys. Rev. B 90, 085421 (2014). PRBMDO 1098-0121 10.1103/PhysRevB.90.085421
46. P. Hapala, R. Temirov, F. S. Tautz, and P. Jelínek, Phys. Rev. Lett. 113, 226101 (2014). PRLTAO 0031-9007 10.1103/PhysRevLett.113.226101
47. A. L. Black, J. M. Lenhardt, and S. L. Craig, J. Mater. Chem. 21, 1655 (2011). JMACEP 0959-9428 10.1039/C0JM02636K
48. L. Gerhard, K. Edelmann, J. Homberg, M. Valášek, S. G. Bahoosh, M. Lukas, F. Pauly, M. Mayor, and W. Wulfhekel, Nat. Commun. 8, 14672 (2017). NCAOBW 2041-1723 10.1038/ncomms14672