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Volumn 2015, Issue 7, 2015, Pages 1606-1612

Copper-Catalysed Alkylarylation of Activated Alkenes Using AIBN and Beyond: An Access to Cyano-Containing Oxindoles

Author keywords

Azo compounds; Copper; Cyanides; Cyclization; Homogeneous catalysis; Radical reactions

Indexed keywords


EID: 85027951558     PISSN: 1434193X     EISSN: 10990690     Source Type: Journal    
DOI: 10.1002/ejoc.201403499     Document Type: Article
Times cited : (56)

References (64)
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    • For the unpredictable addition polymerization of styrene with AIBN in polymer Synthesis see:
    • For the unpredictable addition polymerization of styrene with AIBN in polymer Synthesis see:.
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    • For selected reviews, see:
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    • In general, metal-catalysed C–H functionalization of acetonitrile [pKa (CH3CN) ≈ 31.3 in DMSO] requires a strong base for deprotonation. Pd/NaN(SiMe3)2:
    • In general, metal-catalysed C–H functionalization of acetonitrile [pKa (CH3CN) ≈ 31.3 in DMSO] requires a strong base for deprotonation. Pd/NaN(SiMe3)2:.
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    • Although the catalytic combination of CuCl and tBuOOtBu reported by You and coworkers could lead to oxindole 3a efficiently at 120 °C, the comparable combination of CuI and tBuOOtBu turned out to be less efficient under the current temperature conditions (95 °C) in the absence of DIAD, and gave a product yield of <5 %.
    • Although the catalytic combination of CuCl and tBuOOtBu reported by You and coworkers could lead to oxindole 3a efficiently at 120 °C, the comparable combination of CuI and tBuOOtBu turned out to be less efficient under the current temperature conditions (95 °C) in the absence of DIAD, and gave a product yield of <5 %.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.