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Volumn 23, Issue 1, 2017, Pages 214-218

Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal–Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard

Author keywords

fullerene; metal organic frameworks; pyrene; singlet oxygen; sulfur mustard

Indexed keywords

DETOXIFICATION; FULLERENES; IRRADIATION; OXYGEN; PYRENE; SULFUR;

EID: 85006063449     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201604972     Document Type: Article
Times cited : (99)

References (66)
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    • Oxidation of CEES to CEESO was also tested using 1.5 mol % pyrene as NU-1000 (3.1 mg). 1.5 mol % corresponds to the total mol % of chromophores in NU-1000-PCBA (0.8 mol % pyrene and 0.7 mol % PCBA). The half-life for CEES oxidation was nearly identical to that observed using 0.8 mol % pyrene as NU-1000
    • Oxidation of CEES to CEESO was also tested using 1.5 mol % pyrene as NU-1000 (3.1 mg). 1.5 mol % corresponds to the total mol % of chromophores in NU-1000-PCBA (0.8 mol % pyrene and 0.7 mol % PCBA). The half-life for CEES oxidation was nearly identical to that observed using 0.8 mol % pyrene as NU-1000.
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    • When using either NU-1000 or NU-1000-PCBA as a photosensitizer for HD oxidation, two non-toxic products are observed after 120 min of reaction: 60 % bis(2-chloroethyl)sulfoxide and 40 % 2-chloroethyl vinyl sulfoxide
    • When using either NU-1000 or NU-1000-PCBA as a photosensitizer for HD oxidation, two non-toxic products are observed after 120 min of reaction: 60 % bis(2-chloroethyl)sulfoxide and 40 % 2-chloroethyl vinyl sulfoxide.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.