Carbon powder and fiber-supported polyoxometalate catalytic materials. Preparation, characterization, and catalytic oxidation of dialkyl sulfides as mustard (HD) analogues

Chemistry of Materials

Volumn 8, Issue 10, 1996, Pages 2523-2527

  Gall, Robin Damico ^a   Hill, Craig L ^a   Walker, John E ^a,b  

^a EMORY UNIVERSITY   (United States)

^b US Army Natick RD and E Center   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC CONDITIONS; CATALYTIC MATERIALS; ELECTRONIC CHARACTERISTICS; POLYOXOMETALATES; SELF-DECONTAMINATING; TERT-BUTYL ALCOHOLS; TERT-BUTYLHYDROPEROXIDE; TETRAHYDROTHIOPHENE;

ALCOHOLS; CARBON; CATALYST ACTIVITY; CHARACTERIZATION; DECONTAMINATION; DESORPTION; HYDROPHOBICITY; OXIDATION; POWDERS;

CATALYTIC OXIDATION;

EID: 0001665084     PISSN: 08974756     EISSN: 15205002     Source Type: Journal    
DOI: 10.1021/cm9602757     Document Type: Article

References (36)

1. Pope, M. T.; Müller, A. Angew. Chem., Int. Ed. Engl. 1991, 30, 34.
2. Jansen, R. J. J.; Vanveldhuizen, H. M.; Schwegler, M. A.; van Bekkum, H. Recl. Trav. Chim. Pays-Bas 1994, 113, 115.
3. Hill, C. L.; Prosser-McCartha, C. M. Coord. Chem. Rev. 1995, 143, 407.
4. Mizuno, N.; Misono, M. J. Mol. Catal. 1994, 86, 319.
5. Misono, M.; Okuhara, T. Mater. Res. Soc. Symp. Proc. 1995, 368, 215.
6. Misono, M.; Nojiri, N. Appl. Catal. 1990, 64, 1.
7. Izumi, Y.; Ogawa, M.; Nohara, W.; Urabe, K. Chem. Lett. 1992, 1987.
8. Izumi, Y.; Ono, M.; Ogawa, M.; Urabe, K. Chem. Lett. 1993, 5, 825.
9. Brückman, K.; Tatibouet, J. M.; Che, M.; Serwicka, E.; Haber, J. J. Catal. 1993, 139, 455.
10. Izumi, Y.; Hasebe, R.; Urabe, K. J. Catal. 1983, 84, 402.
11. Casarini, D.; Centi, G.; Jiru, P.; Lena, V.; Tvaruzkova, Z. J. Catal. 1993, 143, 325.
12. Misono, M. Catal. Rev.-Sci. Eng. 1987, 29, 269.
13. Izumi, Y.; Urabe, K. Chem. Lett. 1981, 663.
14. Neumann, R.; Levin, M. J. Org. Chem. 1991, 56, 5707.
15. Fujibayashi, S.; Nakayama, K.; Nishiyama, Y.; Ishii, Y. Chem. Lett. 1994, 1345.
16. Dupont, P.; Vedrine, J. C.; Paumard, E.; Hecquet, G.; Lefebvre, F. Appl. Catal. A - General 1995, 129, 217.
17. Kozhevnikov, I. V.; Sinnema, A.; Jansen, R. J. J.; Vanbekkum, H. Catal. Lett. 1994, 27, 187.
18. Lefebvre, F.; PPAN, P.; Auroux, A. React. Kinet. Catal. Lett. 1995, 55, 3.
19. 33-36 These systems, however, employ high temperatures and pressures. Current work in our laboratory is geared toward developing polyoxometalate catalysts that will oxidize thioethers under ambient conditions.
20. 24
21. Tsigdinos, G. A.; Hallada, J. C. Inorg. Chem. 1968, 7, 437.
22. Keana, J. F. W.; Ogan, M. D.; Lü, Y.; Beer, M.; Varkey, J. J. Am. Chem. Soc. 1985, 107, 6714.
23. Walker, J. E.; Rivin, D.; Kendrick, C. E. Proceedings of the 1994 ERDEC Conference on Chemical and Biological Defense Research, 1994.
24. Gall, R. D.; Hill, C. L.; Walker, J. E. J. Catal. 1995, 159, 473.
25. Rohm and Haas Co., "Ambersorb Carbonaceous Adsorbents. Specialty Purifications", Technical Notes.
26. Yang, Y.-C.; Baker, J. A.; Ward, J. R. Chem. Rev. 1992, 92, 1729.
27. Hirade, J.; Ninomiya, A. J. Biochem. 1950, 37, 19.
28. Menger, F. M.; Elrington, A. R. J. Am. Chem. Soc. 1990, 112, 8201.
29. Menger, F. M.; Elrington, A. R. J. Am. Chem. Soc. 1991, 113, 9621.
30. Ramsden, J. H.; Drago, R. S.; Riley, R. J. Am. Chem. Soc. 1989, 111, 3958.
31. Sattari, D.; Hill, C. L. J. Am. Chem. Soc. 1993, 115, 4649.
32. Chambers, R. C.; Hill, C. L. J. Am. Chem. Soc. 1990, 112, 8427.
33. Kozhevnikov, I. V.; Simagina, V. I.; Varnakova, G. V.; Matveev, K. I. Kinet. Katal. 1979, 20, 416-419.
34. Kozhevnikov, I. V.; Matveev, K. I. Appl. Catal. 1983, 5, 135-150.
35. Riley, D. P. Inorg. Chem. 1983, 22, 1965-1967.
36. Riley, D. P.; Smith, M. R.; Correa, P. E. J. Am. Chem. Soc. 1988, 110, 177-180.