Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000

Nature Protocols

Volumn 11, Issue 1, 2016, Pages 149-162

  Wang, Timothy C ^a   Vermeulen, Nicolaas A ^a   Kim, In Soo ^b   Martinson, Alex B F ^b   Fraser Stoddart, J ^a   Hupp, Joseph T ^a   Farha, Omar K ^a,c  

^a NORTHWESTERN UNIVERSITY   (United States)

^b ARGONNE NATIONAL LABORATORY   (United States)

^c KING ABDULAZIZ UNIVERSITY   (Saudi Arabia)

Author keywords

[No Author keywords available]

Indexed keywords

4,4',4'',4''' (PYRENE 1,3,6,8 TETRAYL)TETRABENZOIC ACID; CARBOXYLIC ACID; CHEMICAL COMPOUND; METAL ORGANIC FRAMEWORK; TETRABROMOPYRENE; TETRAETHYL 4,4',4'',4''' (PYRENE 1,3,6,8 TETRAYL)TETRABENZOATE; UNCLASSIFIED DRUG; ZIRCONYL CHLORIDE OCTAHYDRATE; [4 (ETHOXYCARBONYL)PHENYL]BORONIC ACID; ORGANOMETALLIC COMPOUND;

ARTICLE; BINDING SITE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL MODIFICATION; CHEMICAL PROCEDURES; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; COLUMN CHROMATOGRAPHY; PHYSICAL CHEMISTRY; PHYSICAL PARAMETERS; PRIORITY JOURNAL; SYNTHESIS; CHEMISTRY; CONFORMATION; DEVICES; POROSITY; PROCEDURES;

CATALYSIS; CHEMISTRY TECHNIQUES, SYNTHETIC; MODELS, MOLECULAR; MOLECULAR CONFORMATION; ORGANOMETALLIC COMPOUNDS; POROSITY;

EID: 84979865078     PISSN: 17542189     EISSN: 17502799     Source Type: Journal    
DOI: 10.1038/nprot.2016.001     Document Type: Article

References (28)

1. Ferey, G. Hybrid porous solids: past, present, future. Chem. Soc. Rev. 37, 191-214 (2008).
2. Horike, S., Shimomura, S. & Kitagawa, S. Soft porous crystals. Nat. Chem. 1, 695-704 (2009).
3. Furukawa, H., Cordova, K.E., O'Keeffe, M. & Yaghi, O.M. The chemistry and applications of metal-organic frameworks. Science 341, 974 (2013).
4. Farha, O.K. & Hupp, J.T. Rational design, synthesis, purification, and activation of metal-organic framework materials. Acc. Chem. Res. 43, 1166-1175 (2010).
5. Murray, L.J., Dinca, M. & Long, J.R. Hydrogen storage in metal-organic frameworks. Chem. Soc. Rev. 38, 1294-1314 (2009).
6. Farha, O.K. et al. De novo synthesis of a metal-organic framework material featuring ultrahigh surface area and gas storage capacities. Nat. Chem. 2, 944-948 (2010).
7. Suh, M.P., Park, H.J., Prasad, T.K. & Lim, D.-W. Hydrogen storage in metal-organic frameworks. Chem. Rev. 112, 782-835 (2012).
8. Farha, O.K. et al. Metal-organic framework materials with ultrahigh surface areas: is the sky the limit? J. Am. Chem. Soc. 134, 15016-15021 (2012).
9. Li, J.-R., Sculley, J. & Zhou, H.-C. Metal-organic frameworks for separations. Chem. Rev. 112, 869-932 (2011).
10. Deria, P. et al. Perfluoroalkane functionalization of NU-1000 via solvent-Assisted ligand incorporation: synthesis and CO2 adsorption studies. J. Am. Chem. Soc. 135, 16801-16804 (2013).
11. Lee, J. et al. Metal-organic framework materials as catalysts. Chem. Soc. Rev. 38, 1450-1459 (2009).
12. Kreno, L.E. et al. Metal-organic framework materials as chemical sensors. Chem. Rev. 112, 1105-1125 (2011).
13. So, M.C., Wiederrecht, G.P., Mondloch, J.E., Hupp, J.T. & Farha, O.K. Metal-organic framework materials for light-harvesting and energy transfer. Chem. Commun. 51, 3501-3510 (2015).
14. He, C., Lu, K., Liu, D. & Lin, W. Nanoscale metal-organic frameworks for the co-delivery of cisplatin and pooled siRNAs to enhance therapeutic efficacy in drug-resistant ovarian cancer cells. J. Am. Chem. Soc. 136, 5181-5184 (2014).
15. McKinlay, A.C. et al. Multirate delivery of multiple therapeutic agents from metal-organic frameworks. APL Mater. 2, 124108 (2014).
16. Mondloch, J.E. et al. Vapor-phase metalation by atomic layer deposition in a metal-organic framework. J. Am. Chem. Soc. 135, 10294-10297 (2013).
17. Deria, P., Bury, W., Hupp, J.T. & Farha, O.K. Versatile functionalization of the NU-1000 platform by solvent-Assisted ligand incorporation. Chem. Commun. 50, 1965-1968 (2014).
18. Deria, P. et al. MOF functionalization via solvent-Assisted ligand incorporation: phosphonates vs. carboxylates. Inorg. Chem. 54, 2185-2192 (2015).
19. Johnston, R.L. & Hoffmann, R. The kagomé net: band theoretical and topological aspects. Polyhedron 9, 1901-1911 (1990).
20. Planas, N. et al. Defining the proton topology of the Zr6-based metal-organic framework NU-1000. J. Phys. Chem. Lett. 5, 3716-3723 (2014).
21. Mondloch, J.E. et al. Are Zr6-based MOFs water stable? Linker hydrolysis vs. capillary-force-driven channel collapse. Chem. Commun. 50, 8944-8946 (2014).
22. Beyzavi, M.H. et al. A Hafnium-based metal-organic framework as an efficient and multifunctional catalyst for facile CO2 fixation and regioselective and enantioretentive epoxide activation. J. Am. Chem. Soc. 136, 15861-15864 (2014).
23. Katz, M.J. et al. Simple and compelling biomimetic metal-organic framework catalyst for the degradation of nerve agent simulants. Angew. Chem. Int. Ed. Engl. 53, 497-501 (2013).
24. Mondloch, J.E. et al. Destruction of chemical warfare agents using metal-organic frameworks. Nat. Mater. 14, 512-516 (2015).
25. Hod, I. et al. Directed growth of electroactive metal-organic framework thin films using electrophoretic deposition. Adv. Mater. 26, 6295-6300 (2014).
26. Deria, P. et al. A MOF platform for incorporation of complementary organic motifs for CO2 binding. Chem. Commun. 51, 12478-12481 (2015).
27. Hod, I. et al. Bias-switchable permselectivity and redox catalytic activity of a ferrocene-functionalized, thin-film metal-organic framework compound. J. Phys. Chem. Lett. 6, 586-591 (2015).
28. Karagiaridi, O., Bury, W., Sarjeant, A.A., Hupp, J.T. & Farha, O.K. Synthesis and characterization of functionalized metal-organic frameworks. J. Vis. Exp. 91, e52094 (2014).