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The success of this reaction likely results from direct photolysis of the diazonium salt with low-wavelength visible light, which is sufficient to initiate an efficient chain. Indeed, quantum yield measurements for this reaction in the absence of photocatalyst by chemical actinometry at 450 nm revealed a value of 70 (see Supporting Information for details). For a relevant discussion on such a direct photolysis pathway of aryldiazonium salts see
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3CN at room temperature indicate that binding of the pyridine to the gold center does not occur without photoredox activation.
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A follow-up by31P NMR in CD2Cl2at room temperature does not show significant decomposition of 4 aa after 12 h. This shows the stability of the metallacycle species towards possible side-reactions such as C−P reductive elimination. For recent examples of such processes see: H. Kawai, W. J. Wolf, A. G. DiPasquale, M. S. Winston, F. D. Toste, J. Am. Chem. Soc. 2016, 138, 587.
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CCDC-1483277 (3 aa), CCDC-1483278 (3 ae), CCDC-1483279 (3 ai), and CCDC-1483280 (5 aa) contain the supplementary crystallographic data for this paper
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CCDC-1483277 (3 aa), CCDC-1483278 (3 ae), CCDC-1483279 (3 ai), and CCDC-1483280 (5 aa) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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These data can be obtained free of charge from The Cambridge Crystallographic Data
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