Insights into the influence of solvent polarity on the crystallization of poly(ethylene oxide) spin-coated thin films via in situ grazing incidence wide-angle X-ray scattering

Macromolecules

Volumn 49, Issue 12, 2016, Pages 4579-4586

  Toolan, Daniel T W ^a   Isakova, Anna ^b   Hodgkinson, Richard ^a   Reeves Mclaren, Nik ^a   Hammond, Oliver S ^c   Edler, Karen J ^c   Briscoe, Wuge H ^d   Arnold, Thomas ^e   Gough, Tim ^f   Topham, Paul D ^b   Howse, Jonathan R ^a  

^a UNIVERSITY OF SHEFFIELD   (United Kingdom)

^b ASTON UNIVERSITY   (United Kingdom)

^c University of Bath   (United Kingdom)

^d UNIVERSITY OF BRISTOL   (United Kingdom)

^e DIAMOND LIGHT SOURCE LTD   (United Kingdom)

^f UNIVERSITY OF BRADFORD   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINE COMPOUNDS; CRYSTALLINE MATERIALS; CRYSTALLIZATION; ETHYLENE; METHANOL; MORPHOLOGY; OXIDE FILMS; PLASTIC COATINGS; POLYETHYLENE OXIDES; POLYMERS; SOLUBILITY; SOLVENTS; THIN FILMS; X RAY SCATTERING;

CRYSTALLINE MORPHOLOGIES; CRYSTALLIZATION BEHAVIOR; INDIVIDUAL COMPONENTS; MORPHOLOGICAL DEVELOPMENT; ORGANIC ELECTRONIC DEVICES; POLY (ETHYLENE OXIDE) (PEO); POLYMER CRYSTALLIZATION; SPIN-COATED THIN FILMS;

ORGANIC SOLVENTS;

EID: 84976562963     PISSN: 00249297     EISSN: 15205835     Source Type: Journal    
DOI: 10.1021/acs.macromol.6b00312     Document Type: Article

References (62)

1. Armand, M.; Endres, F.; MacFarlane, D. R.; Ohno, H.; Scrosati, B. Ionic-liquid materials for the electrochemical challenges of the future Nat. Mater. 2009, 8 (8) 621-629 10.1038/nmat2448
2. Jeon, S. I.; Lee, J. H.; Andrade, J. D.; De Gennes, P. G. Protein-surface interactions in the presence of polyethylene oxide J. Colloid Interface Sci. 1991, 142 (1) 149-158 10.1016/0021-9797(91)90043-8
3. Lee, J. H.; Lee, H. B.; Andrade, J. D. Blood compatibility of polyethylene oxide surfaces Prog. Polym. Sci. 1995, 20 (6) 1043-1079 10.1016/0079-6700(95)00011-4
4. Desai, N. P.; Hossainy, S. F. A.; Hubbell, J. A. Surface-immobilized polyethylene oxide for bacterial repellence Biomaterials 1992, 13 (7) 417-420 10.1016/0142-9612(92)90160-P
5. Fuertges, F.; Abuchowski, A. The clinical efficacy of poly(ethylene glycol)-modified proteins J. Controlled Release 1990, 11 (1-3) 139-148 10.1016/0168-3659(90)90127-F
6. Meyerhofer, D. Characteristics of resist films produced by spinning. AIP: 1978; Vol. 49, p 3993-3997.
7. Emslie, A. G.; Bonner, F. T.; Peck, L. G. Flow of a Viscous Liquid on a Rotating Disk J. Appl. Phys. 1958, 29 (5) 858-862 10.1063/1.1723300
8. Birnie, D., III; Hau, S.; Kamber, D.; Kaz, D. Effect of ramping-up rate on film thickness for spin-on processing J. Mater. Sci.: Mater. Electron. 2005, 16 (11-12) 715-720 10.1007/s10854-005-4973-6
9. Birnie, D. P. Rational solvent selection strategies to combat striation formation during spin coating of thin films J. Mater. Res. 2001, 16 (4) 1145-1154 10.1557/JMR.2001.0158
10. Walheim, S.; Boltau, M.; Steiner, U.; Krausch, G. Phase separation in thin films of strongly incompatible polymer blends. Polymer Surfaces and Interfaces III; Wiley: 1999; pp 75-99
11. Dalnoki-Veress, K.; Forrest, J. A.; Stevens, J. R.; Dutcher, J. R. Phase separation morphology of spin-coated polymer blend thin films Phys. A 1997, 239 (1-3) 87-94 10.1016/S0378-4371(96)00471-2
12. Dalnoki-Veress, K.; Forrest, J. A.; Stevens, J. R.; Dutcher, J. R. Phase separation morphology of thin films of polystyrene/polyisoprene blends J. Polym. Sci., Part B: Polym. Phys. 1996, 34 (17) 3017-3024 10.1002/(SICI)1099-0488(199612)34:17<3017::AID-POLB14>3.3.CO;2-4
13. Lisowski, M. S.; Liu, Q.; Cho, J.; Runt, J.; Yeh, F.; Hsiao, B. S. Crystallization behavior of poly (ethylene oxide) and its blends using time-resolved wide-and small-angle X-ray scattering Macromolecules 2000, 33 (13) 4842-4849 10.1021/ma000207c
14. Huang, C.-I.; Chen, J.-R. Crystallization and chain conformation of semicrystalline and amorphous polymer blends studied by wide-angle and small-angle scattering J. Polym. Sci., Part B: Polym. Phys. 2001, 39 (21) 2705-2715 10.1002/polb.10036
15. Schönherr, H.; Frank, C. W. Ultrathin films of poly (ethylene oxides) on oxidized silicon. 2. In situ study of crystallization and melting by hot stage AFM Macromolecules 2003, 36 (4) 1199-1208 10.1021/ma020686a
16. Hobbs, J. K.; Vasilev, C.; Humphris, A. D. Real time observation of crystallization in polyethylene oxide with video rate atomic force microscopy Polymer 2005, 46 (23) 10226-10236 10.1016/j.polymer.2005.08.042
17. Massa, M.; Carvalho, J.; Dalnoki-Veress, K. Direct visualisation of homogeneous and heterogeneous crystallisation in an ensemble of confined domains of poly (ethylene oxide) Eur. Phys. J. E: Soft Matter Biol. Phys. 2003, 12 (1) 111-117 10.1140/epje/i2003-10045-3
18. Massa, M. V.; Dalnoki-Veress, K.; Forrest, J. Crystallization kinetics and crystal morphology in thin poly (ethylene oxide) films Eur. Phys. J. E: Soft Matter Biol. Phys. 2003, 11 (2) 191-198 10.1140/epje/i2002-10155-4
19. Schönherr, H.; Frank, C. W. Ultrathin Films of Poly(ethylene oxides) on Oxidized Silicon. 1. Spectroscopic Characterization of Film Structure and Crystallization Kinetics Macromolecules 2003, 36 (4) 1188-1198 10.1021/ma020685i
20. Mellbring, O.; Kihlman Oiseth, S.; Krozer, A.; Lausmaa, J.; Hjertberg, T. Spin coating and characterization of thin high-density polyethylene films Macromolecules 2001, 34 (21) 7496-7503 10.1021/ma000094x
21. Xue, B. F.; Vaughan, B.; Poh, C. H.; Burke, K. B.; Thomsen, L.; Stapleton, A.; Zhou, X. J.; Bryant, G. W.; Belcher, W.; Dastoor, P. C. Vertical Stratification and Interfacial Structure in P3HT:PCBM Organic Solar Cells J. Phys. Chem. C 2010, 114 (37) 15797-15805 10.1021/jp104695j
22. Mokarian-Tabari, P.; Geoghegan, M.; Howse, J. R.; Heriot, S. Y.; Thompson, R. L.; Jones, R. A. L. Quantitative evaluation of evaporation rate during spin-coating of polymer blend films: Control of film structure through defined-atmosphere solvent-casting Eur. Phys. J. E: Soft Matter Biol. Phys. 2010, 33 (4) 283-289 10.1140/epje/i2010-10670-7
23. Dunbar, A. D.; Mokarian-Tabari, P.; Parnell, A. J.; Martin, S. J.; Skoda, M. W.; Jones, R. A. A solution concentration dependent transition from self-stratification to lateral phase separation in spin-cast PS:d-PMMA thin films Eur. Phys. J. E: Soft Matter Biol. Phys. 2010, 31 (4) 369-75 10.1140/epje/i2010-10592-4
24. Heriot, S. Y.; Jones, R. A. L. An interfacial instability in a transient wetting layer leads to lateral phase separation in thin spin-cast polymer-blend films Nat. Mater. 2005, 4 (10) 782-786 10.1038/nmat1476
25. Takahashi, Y.; Tadokoro, H. Structural Studies of Polyethers, (-(CH2)m-O-)n. X. Crystal Structure of Poly(ethylene oxide) Macromolecules 1973, 6 (5) 672-675 10.1021/ma60035a005
26. French, A. C.; Thompson, A. L.; Davis, B. G. High-Purity Discrete PEG-Oligomer Crystals Allow Structural Insight Angew. Chem., Int. Ed. 2009, 48 (7) 1248-1252 10.1002/anie.200804623
27. Hammouda, B.; Ho, D. L.; Kline, S. Insight into clustering in poly(ethylene oxide) solutions Macromolecules 2004, 37 (18) 6932-6937 10.1021/ma049623d
28. He, Y.; Zhu, B.; Inoue, Y. Hydrogen bonds in polymer blends Prog. Polym. Sci. 2004, 29 (10) 1021-1051 10.1016/j.progpolymsci.2004.07.002
29. Ho, D. L.; Hammouda, B.; Kline, S. R.; Chen, W. R. Unusual phase behavior in mixtures of poly (ethylene oxide) and ethyl alcohol J. Polym. Sci., Part B: Polym. Phys. 2006, 44 (3) 557-564 10.1002/polb.20726
30. Hammouda, B. Clustering in polar media J. Chem. Phys. 2010, 133 (8) 084901 10.1063/1.3484235
31. Polverari, M.; van de Ven, T. G. M. Dilute Aqueous Poly(ethylene oxide) Solutions: Clusters and Single Molecules in Thermodynamic Equilibrium J. Phys. Chem. 1996, 100 (32) 13687-13695 10.1021/jp960215o
32. Kinugasa, S.; Nakahara, H.; Fudagawa, N.; Koga, Y. Aggregative Behavior of Poly(ethylene oxide) in Water and Methanol Macromolecules 1994, 27 (23) 6889-6892 10.1021/ma00101a029
33. Faraone, A.; Magazù, S.; Maisano, G.; Migliardo, P.; Tettamanti, E.; Villari, V. The puzzle of poly(ethylene oxide) aggregation in water: Experimental findings J. Chem. Phys. 1999, 110 (3) 1801-1806 10.1063/1.477888
34. Duval, M. Monitoring of Cluster Formation and Elimination in PEO Solutions Macromolecules 2000, 33 (21) 7862-7867 10.1021/ma000423l
35. Polik, W. F.; Burchard, W. Static light scattering from aqueous poly (ethylene oxide) solutions in the temperature range 20-90 C Macromolecules 1983, 16 (6) 978-982 10.1021/ma00240a030
36. Zhou, P.; Brown, W. Static and dynamic properties of poly(ethylene oxide) in methanol Macromolecules 1990, 23 (4) 1131-1139 10.1021/ma00206a035
37. Polik, W. F.; Burchard, W. Static light scattering from aqueous poly(ethylene oxide) solutions in the temperature range 20-90°C Macromolecules 1983, 16 (6) 978-982 10.1021/ma00240a030
38. Halls, J. J. M.; Arias, A. C.; MacKenzie, J. D.; Wu, W.; Inbasekaran, M.; Woo, E. P.; Friend, R. H. Photodiodes based on polyfluorene composites: influence of morphology Adv. Mater. (Weinheim, Ger.) 2000, 12, 498-502 10.1002/(SICI)1521-4095(200004)12:7<498::AID-ADMA498>3.0.CO;2-H
39. Arias, A. C.; MacKenzie, J. D.; Stevenson, R.; Halls, J. J. M.; Inbasekaran, M.; Woo, E. P.; Richards, D.; Friend, R. H. Photovoltaic Performance and Morphology of Polyfluorene Blends: A Combined Microscopic and Photovoltaic Investigation Macromolecules 2001, 34 (17) 6005-6013 10.1021/ma010240e
40. Brabec, C. J.; Durrant, J. R. Solution-processed organic solar cells MRS Bull. 2008, 33 (7) 670-675 10.1557/mrs2008.138
41. Brabec, C. J.; Heeney, M.; McCulloch, I.; Nelson, J. Influence of blend microstructure on bulk heterojunction organic photovoltaic performance Chem. Soc. Rev. 2011, 40 (3) 1185-1199 10.1039/C0CS00045K
42. Schuettfort, T.; Watts, B.; Thomsen, L.; Lee, M.; Sirringhaus, H.; McNeill, C. R. Microstructure of Polycrystalline PBTTT Films: Domain Mapping and Structure Formation ACS Nano 2012, 6 (2) 1849-1864 10.1021/nn2051295
43. Aylott, J. W.; Richardson, D. J.; Russell, D. A. Optical biosensing of gaseous nitric oxide using spin-coated sol-gel thin films Chem. Mater. 1997, 9 (11) 2261-2263 10.1021/cm970324v
44. Chou, K. W.; Yan, B.; Li, R.; Li, E. Q.; Zhao, K.; Anjum, D. H.; Alvarez, S.; Gassaway, R.; Biocca, A.; Thoroddsen, S. T.; Hexemer, A.; Amassian, A. Spin-cast bulk heterojunction solar cells: a dynamical investigation Adv. Mater. 2013, 25 (13) 1923-9 10.1002/adma.201203440
45. Perez, L. A.; Chou, K. W.; Love, J. A.; van der Poll, T. S.; Smilgies, D.-M.; Nguyen, T.-Q.; Kramer, E. J.; Amassian, A.; Bazan, G. C. Solvent Additive Effects on Small Molecule Crystallization in Bulk Heterojunction Solar Cells Probed During Spin Casting Adv. Mater. 2013, 25 (44) 6380-6384 10.1002/adma.201302389
46. Toolan, D. T. W.; Howse, J. R. Development of in situ studies of spin coated polymer films J. Mater. Chem. C 2013, 1 (4) 603-616 10.1039/C2TC00026A
47. Jukes, P. C.; Heriot, S. Y.; Sharp, J. S.; Jones, R. A. L. Time-Resolved Light Scattering Studies of Phase Separation in Thin Film Semiconducting Polymer Blends during Spin-Coating Macromolecules 2005, 38 (6) 2030-2032 10.1021/ma0477145
48. Toolan, D. T. W.; Haq, E. u.; Dunbar, A.; Ebbens, S.; Clarke, N.; Topham, P. D.; Howse, J. R. Direct observation of morphological development during the spin-coating of polystyrene-poly(methyl methacrylate) polymer blends J. Polym. Sci., Part B: Polym. Phys. 2013, 51 (11) 875-881 10.1002/polb.23288
49. Toolan, D. T. W.; Parnell, A. J.; Topham, P. D.; Howse, J. R. Directed phase separation of PFO:PS blends during spin-coating using feedback controlled in situ stroboscopic fluorescence microscopy J. Mater. Chem. A 2013, 1 (11) 3587-3592 10.1039/c3ta01530k
50. Toolan, D. T. W.; Hodgkinson, R.; Howse, J. R. Stroboscopic Microscopy-Direct Imaging of Structure Development and Phase Separation During Spin-Coating J. Polym. Sci., Part B: Polym. Phys. 2014, 52 (1) 17-25 10.1002/polb.23410
51. Toolan, D. T.; Pullan, N.; Harvey, M. J.; Topham, P. D.; Howse, J. R. In situ studies of phase separation and crystallization directed by Marangoni instabilities during spin-coating Adv. Mater. 2013, 25 (48) 7033-7 10.1002/adma.201302657
52. Toolan, D. T. Straightforward technique for in situ imaging of spin-coated thin films Opt. Eng. 2015, 54 (2) 024109-024109 10.1117/1.OE.54.2.024109
53. Brandrup, J.; Immergut, E. H.; Grulke, E. A.; Abe, A.; Bloch, D. R. Polymer handbook; Wiley: New York, 1999; Vol. 89.
54. Özdemir, C.; Güner, A. Solubility profiles of poly(ethylene glycol)/solvent systems, I: Qualitative comparison of solubility parameter approaches Eur. Polym. J. 2007, 43 (7) 3068-3093 10.1016/j.eurpolymj.2007.02.022
55. Van Antwerpen, F.; Van Krevelen, D. Influence of crystallization temperature, molecular weight, and additives on the crystallization kinetics of poly (ethylene terephthalate) J. Polym. Sci., Polym. Phys. Ed. 1972, 10 (12) 2423-2435 10.1002/pol.1972.180101211
56. Machado, J. C.; Silva, G. G.; Oliveira, F. C. d.; Lavall, R. L.; Rieumont, J.; Licinio, P.; Windmöller, D. Free-volume and crystallinity in low molecular weight poly(ethylene oxide) J. Polym. Sci., Part B: Polym. Phys. 2007, 45 (17) 2400-2409 10.1002/polb.21242
57. Wang, T.; Dunbar, A. D. F.; Staniec, P. A.; Pearson, A. J.; Hopkinson, P. E.; MacDonald, J. E.; Lilliu, S.; Pizzey, C.; Terrill, N. J.; Donald, A. M.; Ryan, A. J.; Jones, R. A. L.; Lidzey, D. G. The development of nanoscale morphology in polymer:fullerene photovoltaic blends during solvent casting Soft Matter 2010, 6, 4128-4134 10.1039/c0sm00343c
58. Kolmogorov, A. N. On the statistical theory of the crystallization of metals Bull. Acad. Sci. USSR, Math. Ser. 1937, 1, 355-359
59. Johnson, W. A.; Mehl, R. F. Reaction kinetics in processes of nucleation and growth Trans. Aime 1939, 135 (8) 396-415
60. Avrami, M. Kinetics of phase change. II transformation-time relations for random distribution of nuclei J. Chem. Phys. 1940, 8 (2) 212-224 10.1063/1.1750631
61. Birnie, D. P., III; Zelinski, B. J. J.; Perry, D. L. Infrared Observation of Evaporative Cooling during Spin-Coating Processes Opt. Eng. 1995, 34 (6) 1782-1788 10.1117/12.203114
62. Heeley, E. L.; Maidens, A. V.; Olmsted, P. D.; Bras, W.; Dolbnya, I. P.; Fairclough, J. P. A.; Terrill, N. J.; Ryan, A. J. Early Stages of Crystallization in Isotactic Polypropylene Macromolecules 2003, 36 (10) 3656-3665 10.1021/ma021373i