Oxygen-activated growth and bandgap tunability of large single-crystal bilayer graphene

Nature Nanotechnology

Volumn 11, Issue 5, 2016, Pages 426-431

  Hao, Yufeng ^a   Wang, Lei ^a   Liu, Yuanyue ^b,c   Chen, Hua ^d   Wang, Xiaohan ^e   Tan, Cheng ^a   Nie, Shu ^f   Won Suk, Ji ^g   Jiang, Tengfei ^h   Liang, Tengfei ⁱ   Xiao, Junfeng ^a   Ye, Wenjing ⁱ   Dean, Cory R ^a   Yakobson, Boris I ^b   McCarty, Kevin F ^f   Kim, Philip ^j   Hone, James ^a   Colombo, Luigi ^k   Ruoff, Rodney S ^e,l  

^a Department of Earth and Environmental Sciences   (United States)

^b Rice University   (United States)

^c NATIONAL RENEWABLE ENERGY LABORATORY   (United States)

^d UNIVERSITY OF TEXAS AT AUSTIN   (United States)

^e The University of Texas at Austin   (United States)

^f SANDIA NATIONAL LABORATORIES   (United States)

^g Sungkyunkwan University   (South Korea)

^h University of Central Florida   (United States)

ⁱ HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Hong Kong)

^j HARVARD UNIVERSITY   (United States)

^k TEXAS INSTRUMENTS   (United States)

^l Ulsan National Institute of Science and Technology   (South Korea)

more..

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL VAPOR DEPOSITION; ELECTRIC FIELDS; ENERGY GAP; MOLECULES; OXYGEN; PHOTONIC DEVICES; SEMICONDUCTOR DEVICES; SINGLE CRYSTALS;

CHEMICAL VAPOUR DEPOSITION; CRYSTALLINE DEFECTS; DIFFUSION OF CARBONS; DISPLACEMENT FIELD; ELECTRICAL QUALITY; GROWTH MECHANISMS; HYDROCARBON MOLECULES; TRANSVERSE ELECTRIC FIELD;

GRAPHENE;

CARBON; COPPER; GRAPHENE; HYDROCARBON; OXYGEN;

ARTICLE; BILAYER MEMBRANE; CONTROLLED STUDY; CRYSTAL; DEHYDROGENATION; DENSITY FUNCTIONAL THEORY; DIFFUSION; ELECTRIC POTENTIAL; ELECTRON DIFFRACTION; INFRARED SPECTROSCOPY; MICROSCOPY; PRIORITY JOURNAL; RAMAN SPECTROMETRY; SURFACE PROPERTY; SYNTHESIS; TRANSMISSION ELECTRON MICROSCOPY;

EID: 84966691899     PISSN: 17483387     EISSN: 17483395     Source Type: Journal    
DOI: 10.1038/nnano.2015.322     Document Type: Article

References (30)

1. Geim, A. K., & Novoselov, K. S. The rise of graphene. Nature Mater. 6, 183-191 (2007
2. Zhang, Y., et al. Direct observation of a widely tunable bandgap in bilayer graphene. Nature 459, 820-823 (2009
3. Yan, J., et al. Dual-gated bilayer graphene hot-electron bolometer. Nature Nanotechnol. 7, 472-478 (2012
4. Yu, Q., et al. Control and characterization of individual grains and grain boundaries in graphene grown by chemical vapour deposition. Nature Mater. 10, 443-449 (2011
5. Yazyev, O. V., & Louie, S. G. Electronic transport in polycrystalline graphene. Nature Mater. 9, 806-809 (2010
6. Kim, K., et al. Raman spectroscopy study of rotated double-layer graphene: misorientation angle dependence of electronic structure. Phys. Rev. Lett. 108, 246103 (2012
7. Batzill, M. The surface science of graphene: metal interfaces, CVD synthesis, nanoribbons, chemical modifications, and defects. Surf. Sci. Rep. 67, 83-115 (2012
8. Kim, K. S., et al. Large-scale pattern growth of graphene films for stretchable transparent electrodes. Nature 457, 706-710 (2010
9. Weatherup, R. S., et al. Interdependency of subsurface carbon distribution and graphene-catalyst interactions. J. Am. Chem. Soc. 136, 13698-13708 (2014
10. Mattevi, C., Kim, H., & Chhowalla, M. A review of chemical vapour deposition of graphene on copper. J. Mater. Chem. 21, 3324-3334 (2011
11. Lee, S., Lee, K., & Zhong, Z Wafer scale homogeneous bilayer graphene films by chemical vapor deposition. Nano Lett. 10, 4702-4707 (2010
12. Liu, W., et al. Controllable and rapid synthesis of high-quality and large-Area Bernal stacked bilayer graphene using chemical vapor deposition. Chem. Mater. 26, 907-915 (2014
13. Zhou, H., et al. Chemical vapor deposition growth of large single crystals of monolayer and bilayer graphene. Nature Commun. 4, 2096 (2013
14. Yan, K., Peng, H., Zhou, Y., Li, H., & Liu, Z Formation of bilayer Bernal graphene: layer-by-layer epitaxy via chemical vapor deposition. Nano Lett. 11, 1106-1110 (2011
15. Fang, W., et al. Asymmetric growth of bilayer graphene on copper enclosures using low pressure chemical vapor deposition. ACS Nano 8, 6491-6499 (2014
16. Sun, Z., et al. Large-Area Bernal-stacked bi-, tri-, and tetralayer graphene. ACS Nano 6, 9790-9796 (2012
17. Liu, L., et al. High-yield chemical vapor deposition growth of high-quality large-Area AB-stacked bilayer graphene. ACS Nano 6, 8241-8249 (2012
18. Zhao, P., et al. Equilibrium chemical vapor deposition growth of Bernal-stacked bilayer graphene. ACS Nano, 8, 11631-11638 (2014
19. Hao, Y., et al. The role of surface oxygen in the growth of large single-crystal graphene on copper. Science 342, 720-723 (2013
20. Hao, Y., et al. Probing layer number and stacking order of few-layer graphene by Raman spectroscopy. Small 6, 195-200 (2010
21. Vlassiouk, I., et al. Graphene nucleation density on copper: fundamental role of background pressure. J. Phys. Chem. C 117, 18919-18926 (2013
22. Yan, Z., et al. Toward the synthesis of wafer-scale single-crystal graphene on copper foils. ACS Nano 6, 9110-9117 (2012
23. Li, X., Cai, W., Colombo, L., & Ruoff, R S. Evolution of graphene growth on Ni and Cu by carbon isotope labeling. Nano Lett. 9, 4268-4272 (2009
24. Kim, H., et al. Activation energy paths for graphene nucleation and growth on Cu. ACS Nano, 6, 3614-3623 (2012
25. López, G. A., & Mittemeijer, E. J. The solubility of C in solid Cu. Scr. Mater. 51, 1-5 (2004
26. Kidambi, P R., et al. Observing graphene grow: catalyst-graphene interactions during scalable graphene growth on polycrystalline copper. Nano Lett. 13, 4769-4778 (2013
27. Riikonen, S., Krasheninnikov, A. V., Halonen, L., & Nieminen, R. M. The role of stable and mobile carbon adspecies in copper-promoted graphene growth. J. Phys. Chem. C 116, 5802-5809 (2012
28. Zhang, W., Wu, P., Li, Z., & Yang, J. First-principles thermodynamics of graphene growth on Cu surfaces. J. Phys. Chem. C, 115, 17782-17787 (2011
29. Taychatanapat, T., & Jarillo-Herrero, P. Electronic transport in dual-gated bilayer graphene at large displacement fields. Phys. Rev. Lett. 105, 166601 (2010
30. Fang, W., et al. Rapid identification of stacking orientation in isotopically labeled chemical-vapor grown bilayer graphene by Raman spectroscopy. Nano Lett. 13, 1541-1548 (2013