Rapid identification of stacking orientation in isotopically labeled chemical-vapor grown bilayer graphene by Raman spectroscopy

Nano Letters

Volumn 13, Issue 4, 2013, Pages 1541-1548

  Fang, Wenjing ^a   Hsu, Allen L ^a   Caudillo, Roman ^b   Song, Yi ^a   Birdwell, A Glen ^c   Zakar, Eugene ^c   Kalbac, Martin ^d   Dubey, Madan ^c   Palacios, Tomás ^a   Dresselhaus, Millie S ^a   Araujo, Paulo T ^a   Kong, Jing ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

^b I Ntel Corporation   (United States)

^c U S ARMY RESEARCH LABORATORY   (United States)

^d J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY   (Czech Republic)

Author keywords

AB stacked bilayer graphene; carbon isotope; fluorination; growth mechanism; Raman spectroscopy

Indexed keywords

BILAYER GRAPHENE; CARBON ISOTOPES; CHARACTERIZATION METHODS; GROWTH MECHANISMS; ISOTOPICALLY LABELED; RAPID DIFFERENTIATION; RAPID IDENTIFICATION; VIBRATIONAL PROPERTIES;

ELECTRONIC PROPERTIES; FLUORINATION; FLUORINE; HALOGENATION; ISOTOPES; RAMAN SPECTROSCOPY; VAPORS;

GRAPHENE;

GAS; GRAPHITE; NANOMATERIAL;

CHEMISTRY; GAS; ISOTOPE LABELING; RAMAN SPECTROMETRY; SURFACE PROPERTY; ARTICLE;

GASES; GRAPHITE; ISOTOPE LABELING; NANOSTRUCTURES; SPECTRUM ANALYSIS, RAMAN; SURFACE PROPERTIES;

EID: 84876034479     PISSN: 15306984     EISSN: 15306992     Source Type: Journal    
DOI: 10.1021/nl304706j     Document Type: Article

References (42)

1. Geim, A. K.; Novoselov, K. S. The rise of graphene Nat. Mater. 2007, 6 (3) 183-91 (Pubitemid 46353764)
2. Ohta, T.; Bostwick, A.; Seyller, T.; Horn, K.; Rotenberg, E. Controlling the Electronic Structure of Bilayer Graphene Science 2006, 313 (5789) 951-954 (Pubitemid 44267382)
3. Oostinga, J. B.; Heersche, H. B.; Liu, X.; Morpurgo, A. F.; Vandersypen, L. M. K. Gate-induced insulating state in bilayer graphene devices Nat. Mater. 2007, 7 (2) 151-157 (Pubitemid 351161346)
4. Zhang, Y.; Tang, T.-T.; Girit, C.; Hao, Z.; Martin, M. C.; Zettl, A.; Crommie, M. F.; Shen, Y. R.; Wang, F. Direct observation of a widely tunable bandgap in bilayer graphene Nature 2009, 459 (7248) 820-823
5. Xia, F.; Farmer, D. B.; Lin, Y.-M.; Avouris, P. Graphene Field-Effect Transistors with High on/off Current Ratio and Large Transport Band Gap at Room Temperature Nano Lett. 2010, 10 (2) 715-8
6. Tang, T.-T.; Zhang, Y.; Park, C.-H.; Geng, B.; Girit, C.; Hao, Z.; Martin, M. C.; Zettl, A.; Crommie, M. F.; Louie, S. G.; Shen, Y. R.; Wang, F. A tunable phonon-exciton Fano system in bilayer graphene Nat. Nanotechnol. 2010, 5 (1) 32-36
7. Bae, S.; Kim, H.; Lee, Y.; Xu, X.; Park, J.-S.; Zheng, Y.; Balakrishnan, J.; Lei, T.; Ri Kim, H.; Song, Y. I.; Kim, Y.-J.; Kim, K. S.; Özyilmaz, B.; Ahn, J.-H.; Hong, B. H.; Iijima, S. Roll-to-roll production of 30-in. graphene films for transparent electrodes Nat. Nanotechnol. 2010, 5 (8) 574-578
8. Wang, Y.; Tong, S. W.; Xu, X. F.; Özyilmaz, B.; Loh, K. P. Interface Engineering of Layer-by-Layer Stacked Graphene Anodes for High-Performance Organic Solar Cells Adv. Mater. 2011, 23 (13) 1514-1518
9. Sutter, P. W.; Flege, J.-I.; Sutter, E. A. Epitaxial graphene on ruthenium Nat. Mater. 2008, 7 (5) 406-411 (Pubitemid 351585230)
10. Nie, S.; Walter, A. L.; Bartelt, N. C.; Starodub, E.; Bostwick, A.; Rotenberg, E.; McCarty, K. F. Growth from Below: Graphene Bilayers on Ir(111) ACS Nano 2011, 5 (3) 2298-2306
11. Wu, Y.; Chou, H.; Ji, H.; Wu, Q.; Chen, S.; Jiang, W.; Hao, Y.; Kang, J.; Ren, Y.; Piner, R. D.; Ruoff, R. S. Growth Mechanism and Controlled Synthesis of AB-Stacked Bilayer Graphene on Cu-Ni Alloy Foils ACS Nano 2012, 6 (9) 7731-7738
12. Yan, K.; Peng, H.; Zhou, Y.; Li, H.; Liu, Z. Formation of Bilayer Bernal Graphene: Layer-by-Layer Epitaxy via Chemical Vapor Deposition Nano Lett. 2011, 11 (3) 1106-1110
13. Liu, L.; Zhou, H.; Cheng, R.; Yu, W. J.; Liu, Y.; Chen, Y.; Shaw, J.; Zhong, X.; Huang, Y.; Duan, X. High-Yield Chemical Vapor Deposition Growth of High-Quality Large-Area AB-Stacked Bilayer Graphene ACS Nano 2012, 6 (9) 8241-8249
14. Reina, A.; Jia, X.; Ho, J.; Nezich, D.; Son, H.; Bulovic, V.; Dresselhaus, M. S.; Kong, J. Large Area, Few-Layer Graphene Films on Arbitrary Substrates by Chemical Vapor Deposition Nano Lett. 2009, 9 (1) 30-5
15. Yan, Z.; Peng, Z.; Sun, Z.; Yao, J.; Zhu, Y.; Liu, Z.; Ajayan, P. M.; Tour, J. M. Growth of Bilayer Graphene on Insulating Substrates ACS Nano 2011, 5 (10) 8187-8192
16. Lee, S.; Lee, K.; Zhong, Z. Wafer Scale Homogeneous Bilayer Graphene Films by Chemical Vapor Deposition Nano Lett. 2010, 10 (11) 101008162231093
17. Kim, K.; Coh, S.; Tan, L. Z.; Regan, W.; Yuk, J. M.; Chatterjee, E.; Crommie, M. F.; Cohen, M. L.; Louie, S. G.; Zettl, A. Raman Spectroscopy Study of Rotated Double-Layer Graphene: Misorientation-Angle Dependence of Electronic Structure Phys. Rev. Lett. 2012, 108 (24) 246103
18. Li, X.; Cai, W.; Colombo, L.; Ruoff, R. S. Evolution of Graphene Growth on Ni and Cu by Carbon Isotope Labeling Nano Lett. 2009, 9 (12) 4268-4272
19. Kalbac, M.; Farhat, H.; Kong, J.; Janda, P.; Kavan, L.; Dresselhaus, M. S. Raman Spectroscopy and in Situ Raman Spectroelectrochemistry of Bilayer 12C/13C Graphene Nano Lett. 2011, 11 (5) 1957-1963
20. Li, Q.; Chou, H.; Zhong, J.-H.; Liu, J.-Y.; Dolocan, A.; Zhang, J.; Zhou, Y.; Ruoff, R. S.; Chen, S.; Cai, W. Growth of Adlayer Graphene on Cu Studied by Carbon Isotope Labeling Nano Lett. 2013, 13 (2) 486-490
21. Li, X.; Magnuson, C. W.; Venugopal, A.; Tromp, R. M.; Hannon, J. B.; Vogel, E. M.; Colombo, L.; Ruoff, R. S. Large-area graphene single crystals grown by low-pressure chemical vapor deposition of methane on copper J. Am. Chem. Soc. 2011, 133 (no. 9) 2816-9
22. Fang, W.; Hsu, A.; Birdwell, G.; Zakar, E.; Dubey, M.; Palacios, T.; Dresselhaus, M.;; Kong, J. Growth Mechanism of Bilayer Graphene on Asymmetric Metal Catalysts. Unpublished work, 2012.
23. Li, X.; Cai, W.; An, J.; Kim, S.; Nah, J.; Yang, D.; Piner, R.; Velamakanni, A.; Jung, I.; Tutuc, E.; Banerjee, S. K.; Colombo, L.; Ruoff, R. S. Large-area synthesis of high-quality and uniform graphene films on copper foils Science (New York) 2009, 324 (no. 5932) 1312-4
24. Ago, H.; Ishigami, N.; Yoshihara, N.; Imamoto, K.; Akita, S.; Ikeda, K.; Tsuji, M.; Ikuta, T.; Takahashi, K. Visualization of Horizontally-Aligned Single-Walled Carbon Nanotube Growth with 13C/12C Isotopes J. Phys. Chem. C 2008, 112 (6) 1735-1738 (Pubitemid 351322033)
25. Horiuchi, S.; Gotou, T.; Fujiwara, M.; Sotoaka, R.; Hirata, M.; Kimoto, K.; Asaka, T.; Yokosawa, T.; Matsui, Y.; Watanabe, K.; Sekita, M. Carbon Nanofilm with a New Structure and Property Jpn. J. Appl. Phys. 2003, 42, L1073-L1076
26. Meyer, J. C.; Geim, A. K.; Katsnelson, M. I.; Novoselov, K. S.; Obergfell, D.; Roth, S.; Girit, C.; Zettl, A. On the roughness of single- and bi-layer graphene membranes Solid State Commun. 2007, 143 (1-2) 101-109 (Pubitemid 46874507)
27. Meyer, J. C.; Geim, A. K.; Katsnelson, M. I.; Novoselov, K. S.; Booth, T. J.; Roth, S. The structure of suspended graphene sheets Nature 2007, 446 (7131) 60-63 (Pubitemid 46348040)
28. Malard, L. M.; Guimarães, M. H. D.; Mafra, D. L.; Mazzoni, M. S. C.; Jorio, A. Group-theory analysis of electrons and phonons in N-layer graphene systems Phys. Rev. B 2009, 79 (12) 125426
29. Yan, J.-A.; Ruan, W. Y.; Chou, M. Y. Phonon dispersions and vibrational properties of monolayer, bilayer, and trilayer graphene: Density-functional perturbation theory Phys. Rev. B 2008, 77 (12) 125401
30. Wang, H.; Wang, Y.; Cao, X.; Feng, M.; Lan, G. Vibrational properties of graphene and graphene layers J. Raman Spectrosc. 2009, 40 (12) 1791-1796
31. Malard, L. M.; Nilsson, J.; Elias, D. C.; Brant, J. C.; Plentz, F.; Alves, E. S.; Castro Neto, A. H.; Pimenta, M. A. Probing the electronic structure of bilayer graphene by Raman scattering Phys. Rev. B 2007, 76 (20) 201401
32. Mafra, D. L.; Malard, L. M.; Doorn, S. K.; Htoon, H.; Nilsson, J.; Castro Neto, A. H.; Pimenta, M. A. Observation of the Kohn anomaly near the K point of bilayer graphene Phys. Rev. B 2009, 80 (24) 241414
33. Lui, C. H.; Malard, L. M.; Kim, S.; Lantz, G.; Laverge, F. E.; Saito, R.; Heinz, T. F. Observation of out-of-plane vibrations in few-layer graphene Nano Lett. 2012, 12 (11) 5539
34. Sato, K.; Park, J. S.; Saito, R.; Cong, C.; Yu, T.; Lui, C. H.; Heinz, T. F.; Dresselhaus, G.; Dresselhaus, M. S. Raman spectra of out-of-plane phonons in bilayer graphene Phys. Rev. B 2011, 84 (3) 035419
35. Araujo, P. T.; Mafra, D. L.; Sato, K.; Saito, R.; Kong, J.; Dresselhaus, M. S. Unraveling the interlayer-related phonon self-energy renormalization in bilayer graphene Sci. Rep. 2012, 2 (1017) 1
36. -1 ACS Nano 2011, 5 (3) 1600-1605
37. Cong, C.; Yu, T.; Sato, K.; Shang, J.; Saito, R.; Dresselhaus, G. F.; Dresselhaus, M. S. Raman Characterization of ABA- and ABC-Stacked Trilayer Graphene ACS Nano 2011, 5 (11) 8760-8768
38. Zhang, Y.; Zhang, L.; Kim, P.; Ge, M.; Li, Z.; Zhou, C. Vapor Trapping Growth of Single-Crystalline Graphene Flowers: Synthesis, Morphology, and Electronic Properties Nano Lett. 2012, 12 (6) 2810-2816
39. Robinson, J. T.; Burgess, J. S.; Junkermeier, C. E.; Badescu, S. C.; Reinecke, T. L.; Perkins, F. K.; Zalalutdniov, M. K.; Baldwin, J. W.; Culbertson, J. C.; Sheehan, P. E.; Snow, E. S. Properties of Fluorinated Graphene Films Nano Lett. 2010, 10 (8) 3001-3005
40. Kalbac, M.; Frank, O.; Kavan, L. The control of graphene double-layer formation in copper-catalyzed chemical vapor deposition Carbon 2012, 50 (10) 3682-3687
41. Nie, S.; Wu, W.; Xing, S.; Yu, Q.; Bao, J.; Pei, S.; McCarty, K. F. Growth from below: bilayer graphene on copper by chemical vapor deposition New J. Phys. 2012, 14 (9) 093028
42. Cui, Y.; Fu, Q.; Bao, X. Dynamic observation of layer-by-layer growth and removal of graphene on Ru(0001) Phys. Chem. Chem. Phys. 2010, 12 (19) 5053-5057