Ph(i-PrO)SiH2: An Exceptional Reductant for Metal-Catalyzed Hydrogen Atom Transfers

Journal of the American Chemical Society

Volumn 138, Issue 14, 2016, Pages 4962-4971

  Obradors, Carla ^a   Martinez, Ruben M ^a   Shenvi, Ryan A ^a  

^a SCRIPPS RESEARCH INSTITUTE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMS; CARBON; CATALYSIS; HYDRIDES; HYDROCARBONS; LIGANDS; METALS; REACTION KINETICS; REDOX REACTIONS; SOLVENTS;

ALTERNATIVE HYPOTHESIS; CATALYST LOADINGS; CONJUGATE ADDITION; HYDROGEN-ATOM TRANSFER; ISOTOPE LABELING EXPERIMENTS; LOWER REACTION TEMPERATURE; RADICAL REACTIONS; REACTION CONDITIONS;

FREE RADICAL REACTIONS;

ALKENE DERIVATIVE; HYDROGEN; IRON; MANGANESE; REDUCING AGENT; SILANE; ALKANE; ALKENE; INDOLE DERIVATIVE; ORGANOSILICON DERIVATIVE;

ALTERNATIVE HYPOTHESIS; ARTICLE; CATALYST; CONJUGATE; HYDRATION; HYDROGENATION; ISOTOPE LABELING; RADICAL REACTION; SOLVOLYSIS; STOICHIOMETRY; TEMPERATURE; CATALYSIS; CHEMISTRY; OXIDATION REDUCTION REACTION; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

ALKANES; ALKENES; CATALYSIS; CRYSTALLOGRAPHY, X-RAY; HYDROGEN; INDOLES; ORGANOSILICON COMPOUNDS; OXIDATION-REDUCTION;

EID: 84964733203     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.6b02032     Document Type: Article

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