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Volumn 358, Issue 10, 2016, Pages 1654-1663

Efficient Metal-Free Aerobic Photooxidation of Sulfides to Sulfoxides Mediated by a Vitamin B2Derivative and Visible Light

Author keywords

flavin; green chemistry; light emitting diodes (LED); photocatalysis; photooxidation; sulfoxides

Indexed keywords


EID: 84964252215     PISSN: 16154150     EISSN: 16154169     Source Type: Journal    
DOI: 10.1002/adsc.201501123     Document Type: Article
Times cited : (133)

References (97)
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    • is used for expressing water content throughout the whole paper
    • v/v% is used for expressing water content throughout the whole paper.
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    • Lifetime of singlet oxygen is substantially longer in deuterated solvents than in non-deuterated solvents
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    • Sodium azide, and DABCO, were described as quenchers of flavin excited states. Triplet-triplet energy transfer between flavin (, E, =232) and benzoquinone (, E, =224) cannot be excluded
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    • The equation can be modified for our case Δ, G, =96.4(, E, E,)−e, /εa, where, E, is the oxidation potential of 2,, E, the reduction potential of RFTAin excited state,, e, /εa is the Coulomb term (5.4 kJ mol
    • D. Rehm, A. Weller, Ber. Bunsenges. phys. Chem. 1969, 73, 834–839. The equation can be modified for our case: ΔGET=96.4(Eox1/2−E*red1/2)−e2/εa, where Eox1/2is the oxidation potential of 2, E*red1/2the reduction potential of RFTA (1) in excited state, e2/εa is the Coulomb term (5.4 kJ mol−1).
    • (1969) Ber. Bunsenges. phys. Chem. , vol.73 , Issue.1 , pp. 834-839
    • Rehm, D.1    Weller, A.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.