Photoinduced One-Electron Oxidation of Benzyl Methyl Sulfides in Acetonitrile: Time-Resolved Spectroscopic Evidence for a Thionium Ion Intermediate

Journal of Organic Chemistry

Volumn 80, Issue 16, 2015, Pages 8001-8008

  Bettoni, Marta ^a   Del Giacco, Tiziana ^a   Stradiotto, Marina ^a   Elisei, Fausto ^a  

^a UNIVERSITY OF PERUGIA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; ELECTRON TRANSPORT PROPERTIES; FREE RADICAL REACTIONS; OXIDATION; PHOTOLYSIS; POSITIVE IONS; REACTION INTERMEDIATES;

ELECTRON TRANSFER PROCESS; HEXAFLUOROPHOSPHATES; LASER FLASH PHOTOLYSIS; ONE-ELECTRON OXIDATION; OXIDATION PRODUCTS; SPECTROSCOPIC EVIDENCE; SPIN DELOCALIZATIONS; STEADY-STATE PHOTOLYSIS;

SULFUR COMPOUNDS;

4 CYANOBENZYL METHYL SULFIDE; 4 METHOXYBENZYL METHYL SULFIDE; ACETONITRILE; BENZALDEHYDE; BENZYL METHYL SULFIDE; CATION; DIMER; DIMETHYL SULFIDE; FLUOROPHOSPHATE; NITROGEN; RADICAL; SULFUR; UNCLASSIFIED DRUG; ACETONITRILE DERIVATIVE; BENZYL DERIVATIVE; ION; QUATERNARY AMMONIUM DERIVATIVE; SULFIDE; THIONIUM;

ABSORPTION; ARTICLE; DENSITY FUNCTIONAL THEORY; ELECTRON; ELECTRON TRANSPORT; HYDROGEN BOND; OXIDATION; PHOTOLYSIS; PHOTOOXIDATION; PROTON TRANSPORT; SPECTROSCOPY; STEADY STATE; CHEMICAL STRUCTURE; CHEMISTRY; LASER; OXIDATION REDUCTION REACTION; PHOTOCHEMISTRY; QUANTUM THEORY; TIME;

ACETONITRILES; BENZYL COMPOUNDS; ELECTRONS; IONS; LASERS; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PHOTOCHEMICAL PROCESSES; QUANTUM THEORY; QUATERNARY AMMONIUM COMPOUNDS; SPECTRUM ANALYSIS; SULFIDES; TIME FACTORS;

EID: 84939840007     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/acs.joc.5b01052     Document Type: Article

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